Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control

Journal of the American Chemical Society

Volumn 137, Issue 27, 2015, Pages 8838-8850

  Grayson, Matthew N ^a   Krische, Michael J ^b   Houk, K N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; BUTADIENE; CATALYSTS; CHEMICAL BONDS; ENANTIOSELECTIVITY; HYDROGEN BONDS; PHOSPHORUS COMPOUNDS;

CARBON-CARBON BOND FORMATION; DIASTEREO- AND ENANTIOSELECTIVITY; HOMOALLYLIC ALCOHOL; PHOSPHATE LIGANDS; PHOSPHORYL OXYGEN; PRODUCT DISTRIBUTIONS; STEREOCHEMICAL CONTROL; TRANSITION STRUCTURES;

DENSITY FUNCTIONAL THEORY;

1,3 BUTADIENE; ALDEHYDE; CARBONYL DERIVATIVE; OXYGEN; PHOSPHORIC ACID; RUTHENIUM; 1,3 BUTADIENE DERIVATIVE; 1,3-BUTADIENE;

ALDOL REACTION; ALKYLATION; ARTICLE; ASYMMETRIC CATALYSIS; ASYMMETRIC HYDROHYDROXYALKYLATION; CHIRALITY; COVALENT BOND; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; HYDROGEN BOND; ISOMERIZATION; KINETICS; NUCLEOPHILICITY; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY; CATALYSIS; CHEMISTRY; MOLECULAR MODEL; STEREOISOMERISM;

ALKYLATION; BUTADIENES; CATALYSIS; HYDROGEN BONDING; MODELS, MOLECULAR; RUTHENIUM; STEREOISOMERISM;

EID: 84937151857     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b04844     Document Type: Article

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