Mechanistic insights into a BINOL-derived phosphoric acid-catalyzed asymmetric Pictet-Spengler reaction

Journal of Organic Chemistry

Volumn 80, Issue 5, 2015, Pages 2634-2640

  Overvoorde, Lois M ^a   Grayson, Matthew N ^a   Luo, Yi ^b   Goodman, Jonathan M ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CATALYSIS; CATALYSTS; DENSITY FUNCTIONAL THEORY; HYDROGEN BONDS; MOLECULAR MODELING; PHOSPHORIC ACID; QUANTUM THEORY; RIGID STRUCTURES;

ACYLIMINIUM ION; DIASTEREO- AND ENANTIOSELECTIVITY; HIGH STEREOSELECTIVITIES; HYDROGEN ATOMS; PHOSPHATE GROUP; PICTET-SPENGLER REACTIONS; QUANTUM MECHANICS/MOLECULAR MECHANICS; TRANSITION STRUCTURES;

ENANTIOSELECTIVITY;

2,2' DIHYDROXY 1,1' BINAPHTHYL; ACETIC ACID DERIVATIVE; BETA CARBOLINE; CARBON; HYDROGEN; ION; N ACYLIMINIUM; NITROGEN; OXYGEN; PHOSPHATE; PHOSPHORIC ACID; TRIMETHYLSILYL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CATALYSIS; CATALYST; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; HYDROGEN BOND; MOLECULAR MECHANICS; PICTET SPENGLER REACTION; QUANTUM MECHANICS; STEREOCHEMISTRY;

EID: 84924297482     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo5028134     Document Type: Article

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