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Volumn 21, Issue 30, 2015, Pages 10754-10762

Highly Chemoselective Catalytic Coupling of Substituted Oxetanes and Carbon Dioxide

Author keywords

aluminium; carbon dioxide; chemoselectivity; heterocycles; homogeneous catalysis

Indexed keywords

ALUMINUM; BIODEGRADABLE POLYMERS; CARBONATES; CATALYSIS; ORGANIC COMPOUNDS; ORGANIC LIGHT EMITTING DIODES (OLED); ORGANIC POLYMERS;

EID: 84936999728     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201501576     Document Type: Article
Times cited : (81)

References (79)
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    • Please note that other methods towards 6MCCs have been reported, but these methods often suffer from the use of toxic reagents (such as phosgene/chloroformates), produce stoichiometric amounts of halide waste, or require harsh reaction conditions. See, for example
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    • Note that also the use of dialkylcarbonates with respect to 6MCC formation has been reported; the industrial preparation of dialkylcarbonates typically requires toxic reagents such as phosgene and/or harsh reaction conditions. For a recent review, see
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    • Please also note that column purification of the crude 6MCCs in some cases resulted in significant 1,3-diol formation (noted for instance in the purification of 2), thereby compromising the yield of the isolated product. Therefore, it is recommended to carry out the column separation of the 6MCCs without too much delay.
    • K. M. Tomczyk, P. A. Guńka, P. G. Parzuchowski, J. Zachara, G. Rokicki, Green Chem. 2012, 14, 1749-1758. Please also note that column purification of the crude 6MCCs in some cases resulted in significant 1,3-diol formation (noted for instance in the purification of 2), thereby compromising the yield of the isolated product. Therefore, it is recommended to carry out the column separation of the 6MCCs without too much delay.
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    • CCDC-1056843 (6), CCDC-1056844 (15a), CCDC-1056845 (9), CCDC-1056846 (11), and CCDC-1056847 (21), contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.