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1HNMR and MALDI-TOF mass spectrometry. This observation reveals that under these conditions 1f results in a less effective, heterogeneous catalyst. Similar observations have been reported by North and co-workers, see reference[5a].
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Catalytic reactions under similar conditions using either acetone (16%) or propylene carbonate (2%) as solvent showed no improvement in yield. Styrene oxide is generally a more sluggish substrate in cyclic carbonate synthesis.
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