Trifluoromethylchlorosulfonylation of alkenes: Evidence for an inner-sphere mechanism by a copper phenanthroline photoredox catalyst

Angewandte Chemie - International Edition

Volumn 54, Issue 24, 2015, Pages 6999-7002

  Bagal, Dattatraya B ^a,b   Kachkovskyi, Georgiy ^a,c   Knorn, Matthias ^a   Rawner, Thomas ^a   Bhanage, Bhalchandra M ^b   Reiser, Oliver ^a  

^a UNIVERSITY OF REGENSBURG   (Germany)

^b INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

^c INSTITUTE OF BIOORGANIC CHEMISTRY AND PETROCHEMISTRY   (Ukraine)

Author keywords

atom transfer radical additions (ATRA); chlorosulfonylation; copper; photocatalysis; trifluoromethylation

Indexed keywords

CATALYSTS; COPPER; ELECTRON TRANSITIONS; FREE RADICAL REACTIONS; IRIDIUM; PHOTOCATALYSIS;

ATOM TRANSFER RADICAL ADDITION; BOND FORMING; CHLOROSULFONYLATION; COPPER PHENANTHROLINE; ELECTRON TRANSFER; INNERSPHERE MECHANISM; TRIFLUOROMETHYLATION; VISIBLE LIGHT;

HYDROCARBONS;

1,10-PHENANTHROLINE; ALKENE; COORDINATION COMPOUND; COPPER; PHENANTHROLINE DERIVATIVE; RUTHENIUM;

CATALYSIS; CHEMISTRY; LIGHT; OXIDATION REDUCTION REACTION;

ALKENES; CATALYSIS; COORDINATION COMPLEXES; COPPER; LIGHT; OXIDATION-REDUCTION; PHENANTHROLINES; RUTHENIUM;

EID: 84930623389     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201501880     Document Type: Article

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