Rhodium-catalyzed enantioselective intramolecular C-H silylation for the syntheses of planar-chiral metallocene siloles

Angewandte Chemie - International Edition

Volumn 54, Issue 23, 2015, Pages 6918-6921

  Zhang, Qing Wei ^a   An, Kun ^a   Liu, Li Chuan ^a   Yue, Yuan ^a   He, Wei ^a  

^a Tsinghua University   (China)

Author keywords

chirality; ligand effects; metallocenes; rhodium; silicon

Indexed keywords

CATALYSIS; CHIRALITY; LIGANDS; METALS; ORGANOMETALLICS; RHODIUM; RUTHENIUM; SILICON;

C-H BOND; CHIRAL LIGAND; CYCLOPENTADIENE RING; ENANTIOSELECTIVE; LIGAND EFFECT; RHODIUM-CATALYZED; SILYLATIONS; STERIC HINDRANCES;

ENANTIOSELECTIVITY;

FERRIC ION; ORGANOMETALLIC COMPOUND; RHODIUM; SILANE DERIVATIVE; SILOLE;

CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

CATALYSIS; FERRIC COMPOUNDS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; RHODIUM; SILANES; STEREOISOMERISM;

EID: 84930507701     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201502548     Document Type: Article

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