Asymmetric synthesis of planar chiral ferrocenes by enantioselective intramolecular C-H arylation of N-(2-haloaryl)ferrocenecarboxamides

Organic Letters

Volumn 16, Issue 20, 2014, Pages 5336-5338

  Liu, Lantao ^a   Zhang, An An ^a   Zhao, Rui Juan ^a   Li, Feng ^a   Meng, Tuan Jie ^a   Ishida, Naoki ^b   Murakami, Masahiro ^b   Zhao, Wen Xian ^a  

^a SHANGQIU NORMAL UNIVERSITY   (China)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84907980066     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol502520b     Document Type: Article

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53. It is reported that an N-unsubstituted quinolinone-fused ferrocene racemizes in solution (ref 12). However, the erosion of the enantiomeric excess of N-butyl derivative 2e was not observed in toluene even at re fluxing temperature.
54. Low enantioselectivities were observed when pyridinecontaining substrates were subjected to the optimized reaction conditions. See the Supporting Information for details.
55. CCDC1002966 (2j) contains the supplementary crystallographic data for this paper.