Axially chiral spirosilanes via catalytic asymmetric intramolecular hydrosilation

Journal of the American Chemical Society

Volumn 118, Issue 49, 1996, Pages 12469-12470

  Tamao, Kohei ^a   Nakamura, Kazunori ^a   Ishii, Hiroyuki ^a   Yamaguchi, Shigehiro ^a   Shiro, Motoo ^b  

^a KYOTO UNIVERSITY   (Japan)

^b RIGAKU CORPORATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

SILANE DERIVATIVE; SPIRO COMPOUND; THIOPHENE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030457105     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962754c     Document Type: Article

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38. 2, 2 mol %; Rh/DIOP = 1:1), the reaction did not go to completion at -20 °C even after 7 days.