Reliability of the ΔeCN42 limit and global method for extra virgin olive oil purity assessment using different analytical approaches

Food Chemistry

Volumn 190, Issue , 2016, Pages 216-225

  Beccaria, Marco ^a   Moret, Erica ^b   Purcaro, Giorgia ^b   Pizzale, Lorena ^b   Cotroneo, Antonella ^a   Dugo, Paola ^a,c   Mondello, Luigi ^a,c   Conte, Lanfranco S ^b  

^a UNIVERSITY OF MESSINA   (Italy)

^b UNIVERSITY OF UDINE   (Italy)

^c UNIVERSITY CAMPUS BIO MEDICO   (Italy)

Author keywords

Authenticity; Delta ECN42; Global method; High performance liquid chromatography (HPLC); Mass spectrometry (MS); Olive oil; Refractive index detector (RID); Triacyglycerol (TAG)

Indexed keywords

CHROMATOGRAPHY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; OILS AND FATS; REFRACTIVE INDEX;

ANALYTICAL APPROACH; AUTHENTICITY; DELTA-ECN42; EXTRA VIRGIN OLIVE OIL; GLOBAL METHODS; INSTRUMENTAL APPROACH; PARTITION NUMBERS; TRIACYGLYCEROL (TAG);

OLIVE OIL;

EXTRA VIRGIN OLIVE OIL; OLIVE OIL; TRIACYLGLYCEROL; UNCLASSIFIED DRUG; VEGETABLE OIL;

ALGORITHM; ARTICLE; CONTROLLED STUDY; FALSE POSITIVE RESULT; FOOD ANALYSIS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; INTERMETHOD COMPARISON; LIPID ANALYSIS; MASS SPECTROMETRY; NON AQUEOUS REVERSE PHASE HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; REFRACTION INDEX; RELIABILITY; CHEMISTRY; PROCEDURES;

CHROMATOGRAPHY, HIGH PRESSURE LIQUID; MASS SPECTROMETRY; OLIVE OIL; PLANT OILS;

EID: 84930225759     PISSN: 03088146     EISSN: 18737072     Source Type: Journal    
DOI: 10.1016/j.foodchem.2015.05.075     Document Type: Article

References (36)

1. A. Acheampong, N. Leveque, A. Tchapla, and S. Heron Simple complementary liquid chromatography and mass spectrometry approaches for the characterization of triacylglycerols in Pinus koraiensis seed oil Journal of Chromatography A 1218 2011 5087 5100
2. A. Bach-Faig, E.M. Berry, D. Lairon, J. Reguant, A. Trichopoulou, and S. Dernini Mediterranean diet foundation expert group mediterranean diet pyramid today. Science and cultural updates Public Health Nutrition 14 12A 2011 2274 2284
3. R. Bernerth, and M. Frentzen Utilization of erucoyl-CoA by acyltransferases from developing seeds of Brassica napus (L.) involved in triacylglycerol biosynthesis Plant Science 67 1990 21 28
4. M. Buchgraber, F. Ulberth, and E. Anklam Capillary GLC: A robust method to characterize the triglyceride profile of cocoa butter - Results of an intercomparison study European Journal of Lipid Science and Technology 105 2003 754 760
5. A. Cert, and W. Moreda Algorithms for the detection of hazelnut oil in olive oil Grasas y Aceites 51 2000 143 149
6. W.W. Christie A stable silver-loaded column for the separation of lipids by high performance liquid chromatography Journal of High Resolution Chromatography 10 1987 148 150
7. W.W. Christie Separation of molecular species of triacylglycerols by high-performance liquid chromatography with a silver ion column Journal of Chromatography 454 1988 273 284
8. E. Christopoulou, M. Lazaraki, M. Komaitis, and K. Kaselimis Effectiveness of determinations of fatty acids and triglycerides for the detection of adulteration of olive oils with vegetable oils Food Chemistry 84 2004 463 474
9. J.M. Cunliffe, and T.D. Maloney Fused-core particle technology as an alternative to sub-2-μm particles to achieve high separation efficiency with low backpressure Journal of Separation Science 30 2007 3104 3109
10. G. Dobson, W.W. Christie, and B. Nikolova-Damyanova Silver ion chromatography of lipids and fatty acids Journal of Chromatography B 671 1995 197 222
11. P. Dugo, M. Beccaria, N. Fawzi, P. Donato, F. Cacciola, and L. Mondello Mass spectrometric elucidation of triacylglycerol content of Brevoortia tyrannus (menhaden) oil using non-aqueous reversed-phase liquid chromatography under ultra-high pressure conditions Journal of Chromatography A 1259 2012 227 236
12. P. Dugo, O. Favoino, P.Q. Tranchida, G. Dugo, and L. Mondello Off-line coupling of non-aqueous reversed-phase and silver ion high-performance liquid chromatography-mass spectrometry for the characterization of rice oil triacylglycerol positional isomers Journal of Chromatography A 1041 2004 135 142
13. European Commission Regulation (EC) No. 2472 Amending regulation (EEC) No. 2568/91 on the characteristics of olive oil and olive-residue oil and on the relevant methods of analysis and council regulation (EEC) No. 2658/87 on the tariff and statistical nomenclature and on the common customs tariff The Official Journal of the European Union L341 1997 25 39
14. European Commission Regulation (EEC) No. 2568 On the characteristics of olive oil and olive-residue oil and on the relevant methods of analysis The Official Journal of the European Union L248 1991 1 83
15. European Union Implementing Regulation (EU) No.1348/2013 Amending regulation (EEC) No. 2568/91 on the characteristics of olive oil and olive-residue oil and on the relevant methods of analysis The Official Journal of the European Union L338 2013 31 67
16. C. Fanali, L. Dugo, F. Cacciola, M. Beccaria, S. Grasso, and M. Dachà Chemical characterization of sacha inchi (Plukenetia volubilis L.) oil Journal of Agriculture and Food Chemistry 59 2011 13043 13049
17. M. Fasciotti, and A.D. Pereira Netto Optimization and application of methods of triacylglycerol evaluation for characterization of olive oil adulteration by soybean oil with HPLC-APCI-MS-MS Talanta 81 2010 1116 1125
18. D. García-Gonzles, M. Viera-Macía, R. Aparicio-Ruiz, M.T. Morales, and R. Aparicio Validation of a method based on triglycerides for the detection of low percentages of hazelnut oil in olive oil by column liquid chromatography Journal of AOAC International 90 2007 1346 1353
19. M. Holčapek, M. Lísa, P. Jandera, and N. Kabátová Quantitation of triacylglycerols in plant oils using HPLC with APCI-MS, evaporative light-scattering, and UV detection Journal of Separation Science 28 2005 1315 1333
20. International Olive Council. (2001). Determination of the difference between actual and theoretical content of triacylglycerols with ECN 42. COI/T.20/Doc. No. 20 Rev. 3. Madrid, Spain.
21. International Olive Council. (2013). Global method for the detection of extraneous oils in olive oils. COI/T.20/Doc. No. 25 Rev. 1. Madrid, Spain.
22. G.N. Jham, B. Nikolova-Damyavova, M. Viera, R. Natalino, and A.C. Rodriques Determination of the triacylglycerol composition of coffee beans by reverse-phase high-performance liquid chromatography Phytochemical Analysis 14 2003 310 314
23. P. Laakso, W.W. Christie, and J. Pettersen Analysis of north atlantic and baltic fish oil triacylglycerols by high-performance liquid chromatography with a silver ion column Lipids 25 1990 284 291
24. M.J. Lerma-García, R. Lusardi, E. Chiavaro, L. Cerratani, A. Bendini, and G. Ramis-Ramos Use of triacylglycerol profiles established by high performance liquid chromatography with ultraviolet-visible detection to predict the botanical origin of vegetable oils Journal of Chromatography A 1218 2011 7521 7527
25. J.T. Lin, L.R. Snyder, and T.A. McKeon Prediction of relative retention times of triacylglycerols in nonaqueous reversed-phase high-performance liquid chromatography Journal of Chromatography A 808 1998 43 49
26. M. Lísa, and M. Holčapek Triacylglycerols profiling in plant oils important in food industry, dietetics and cosmetics using high-performance liquid chromatography-atmospheric pressure chemical ionization mass spectrometry Journal of Chromatography A 1198-1199 2008 115 130
27. M. Lísa, E. Cífková, and M. Holčapek Lipidomic profiling of biological tissues using off-line two-dimensional high-performance liquid chromatography-mass spectrometry Journal of Chromatography A 1218 2011 5146 5156
28. M. Lísa, K. Netušilová, L. Franěk, H. Dvoráková, V. Vrkoslav, and M. Holčapek Characterization of fatty acid and triacylglycerol composition in animal fats using silver-ion and non-aqueous reversed-phase high-performance liquid chromatography/mass spectrometry and gas chromatography/flame ionization detection Journal of Chromatography A 1218 2011 7499 7510
29. J. López-Miranda, F. Pérez-Jiménez, E. Ros, R. De Caterina, L. Badimón, and M.I. Covas Olive oil and health: summary of the II international conference on olive oil and health consensus report, Jaén and Córdoba (Spain) 2008 Nutrition, Metabolism and Cardiovascular Diseases 20 4 2010 284 294
30. L. Mondello, M. Beccaria, P. Donato, F. Cacciola, G. Dugo, and P. Dugo Comprehensive two-dimensional liquid chromatography with evaporative lightscattering detection for the analysis of triacylglycerols in Borago officinalis Journal of Separation Science 34 2011 688 692
31. W. Moreda, M.C. Pérez-Camino, and A. Cert Improved method for the determination of triacylglycerols in olive oils by high performance liquid chromatography Grasas y Aceites 54 2003 175 179
32. D. Ollivier, J. Artaud, C. Pinatel, J.P. Durbec, and M. Guérère Differentiation of French virgin olive oil RDOs by sensory characteristics, fatty acid and triacylglycerol compositions and chemometrics Food Chemistry 97 2006 382 393
33. C. Ragonese, L. Tedone, M. Beccaria, G. Torre, F. Cichello, and F. Cacciola Characterization of lipid fraction of marine macroalgae by means of chromatography techniques coupled to mass spectrometry Food Chemistry 145 2014 932 940
34. T.G. Sotiroudis, and S.A. Kyrtopoulos Anticarcinogenic compounds of olive oil and related biomarkers European Journal of Nutrition 47 2008 69 72
35. E.J.C. van der Klift, G. Vivó-Truyols, F.W. Claassen, F.L. van Holthoon, and T.A. van Beek Comprehensive two-dimensional liquid chromatography with ultraviolet, evaporative light scattering and mass spectrometric detection of triacylglycerols in corn oil Journal of Chromatography A 1178 2008 43 55
36. F. Visioli, and C. Galli Antiatherogenic components of olive oil Current Atherosclerosis Reports 3 1 2001 64 67