Generation of arynes using trimethylsilylmethyl Grignard reagent for activation of ortho-Iodoaryl or ortho-sulfinylaryl triflates

Chemistry Letters

Volumn 44, Issue 5, 2015, Pages 691-693

  Yoshida, Suguru ^a   Uchida, Keisuke ^a   Hosoya, Takamitsu ^a  

^a TOKYO MEDICAL AND DENTAL UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84929179251     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.150060     Document Type: Article

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51. Soft electrophilic nature of iodo group would be favored by the soft nucleophilic trimethylsilylmethyl Grignard reagent, although the reason for the selectivity is yet to be investigated.