Selective formation of a trisubstituted alkene motif by trans-Hydrostannation/Stille coupling: Application to the total synthesis and late-Stage modification of 5,6-Dihydrocineromycin B

Angewandte Chemie - International Edition

Volumn 54, Issue 21, 2015, Pages 6241-6245

  Rummelt, Stephan M ^a   Preindl, Johannes ^a   Sommer, Heiko ^a   Fürstner, Alois ^a  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

alkyne metathesis; cross coupling; hydrostannation; natural products; ruthenium

Indexed keywords

ANTIBIOTICS; CATALYSIS; CHEMICAL REACTIONS; HYDROCARBONS; KETONES; RUTHENIUM;

ALKYNE METATHESIS; CROSS-COUPLINGS; DIVERSITY-ORIENTED SYNTHESIS; HYDROSTANNATION; NATURAL PRODUCTS; RING-CLOSING METATHESIS REACTIONS; SELECTIVE FORMATION; TRISUBSTITUTED ALKENES;

SYNTHESIS (CHEMICAL);

ALKENE; BIOLOGICAL PRODUCT; CINEROMYCIN B; LACTONE;

CHEMICAL STRUCTURE; CHEMISTRY; STREPTOMYCES; SYNTHESIS;

ALKENES; BIOLOGICAL PRODUCTS; CHEMISTRY TECHNIQUES, SYNTHETIC; LACTONES; MODELS, MOLECULAR; STREPTOMYCES;

EID: 84928999151     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201501608     Document Type: Article

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