Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution

Synthesis (Germany)

Volumn 47, Issue 7, 2015, Pages 924-933

  Delvos, Lukas B ^a   Oestreich, Martin ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

allylic substitution; copper; enantioselectivity; N heterocyclic carbenes; silicon

Indexed keywords

ALLYLATION; CATALYSIS; ENANTIOMERS; ENANTIOSELECTIVITY; ORGANIC COMPOUNDS; SILICON; SUBSTITUTION REACTIONS;

ALLYLIC PHOSPHATES; ALLYLIC SUBSTITUTION; COPPER (I) COMPLEXES; EXPERIMENTAL ANALYSIS; N-HETEROCYCLIC CARBENES; QUANTITATIVE TRANSFORMATION; SILYLATIONS; TEMPERATURE DEPENDENT;

COPPER;

ALLYL COMPOUND; COPPER; NUCLEOPHILE; PHOSPHATE; SILANE DERIVATIVE; SILICON;

ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; CHIRALITY; ENANTIOCONVERGENT SILYLATION; QUANTITATIVE ANALYSIS; RACEMIC MIXTURE; SILYLATION; SUBSTITUTION REACTION; TEMPERATURE;

EID: 84925533257     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0034-1380157     Document Type: Article

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