Kinetics and mechanism of chromium electrodeposition from methanesulfonate solutions of Cr(III) salts

Surface Engineering and Applied Electrochemistry

Volumn 50, Issue 5, 2014, Pages 384-389

  Protsenko, V S ^a   Kityk, A A ^a   Danilov, F I ^a  

^a UKRAINIAN STATE UNIVERSITY OF CHEMICAL TECHNOLOGY   (Ukraine)

Author keywords

electroplating; kinetics; methanesulfonic acid; trivalent chromium

Indexed keywords

CHROMIUM; ELECTRODEPOSITION; ELECTROLYTIC REDUCTION; ELECTROPLATING; ENZYME KINETICS; IONS; KINETICS;

BUFFERING CAPACITIES; CHROMIUM ELECTRODEPOSITION; ELECTRO REDUCTION; ELECTRO-DEPOSITION BEHAVIORS; ELECTROCHEMICAL SYSTEMS; KINETICS AND MECHANISM; METHANE SULFONIC ACID; TRIVALENT CHROMIUM;

CHROMIUM COMPOUNDS;

EID: 84924954634     PISSN: 10683755     EISSN: 19348002     Source Type: Journal    
DOI: 10.3103/S106837551405007X     Document Type: Article

References (23)

1. Kwon, S.C., Kim, M., Park, S.U., Kim, D.Y., Kim, D., Nam, K.S., and Choi Y., Characterization of intermediate Cr-C layer fabricated by electrodeposition in hexavalent and trivalent chromium baths, Surf. Coat. Technol., 2004, vol. 183, pp. 151–156.
2. Baral, A. and Engelken, R. Modeling, optimization, and comparative analysis of trivalent chromium electrodeposition from aqueous glycine and formic acid baths, J. Electrochem. Soc., 2005, vol. 152, pp. C504–C512.
3. Surviliene, S., Nivinskiene, O., Cesuniene, A., and Selskis, A., Effect of Cr(III) solution chemistry on electrodeposition of chromium, J. Appl. Electrochem., 2006, vol. 36, pp. 649–654.
4. Zeng, Z., Zhang, Y., Zhao, W., and Zhang, J., Role of complexing ligands in trivalent chromium electrodeposition, Surf. Coat. Technol., 2011, vol. 205, pp. 4771–4775.
5. Danilov, F.I., Protsenko, V.S., Gordiienko, V.O., Kwon, S.C., Lee, J.Y., and Kim, M., Nanocrystalline hard chromium electrodeposition from trivalent chromium bath containing carbamide and formic acid: structure, composition, electrochemical corrosion behavior, hardness and wear characteristics of deposits, Appl. Surf. Sci., 2011, vol. 257, pp. 8048–8053.
6. 3H on thickness, current efficiency and corrosion properties of brusn plated Cr(III) formate urea baths, Surf. Eng., 2008, vol. 24, pp. 458–463.
7. 3 in direct and pulse current electrodeposition of trivalent chromium, Surf. Eng., 2009, vol. 25, pp. 570–576.
8. Gernon, M.D., Wu, M., Buszta, T., and Janney, P., Environmental benefits of methanesulfonic acid: comparative properties and advantages, Green Chem., 1999, vol. 1, no. 6, pp. 127–140.
9. Danilov, F.I., Sknar, I.V., and Sknar, Yu.E., Kinetics of nickel electroplating from methanesulfonate electrolyte, Russ. J. Electrochem., 2011, vol. 47, no. 9, pp. 1035–1042.
10. Martyak, N.M. and Seefeldt, R., Additive-effects during plating in acid tin ethanesulfonate electrolytes, Electrochim. Acta, 2004, vol. 49, pp. 4303–4311.
11. Low, C.T.J. and Walsh, F.C., The stability of an acidic tin methanesulfonate electrolyte in the presence of a hydroquinone antioxidant, Electrochim. Acta, 2008, vol. 53, pp. 5280–5286.
12. 2+ on Sn electrodeposition in methyl sulphonic acid solutions, Electrochim. Acta, 2008, vol. 53, pp. 2430–2440.
13. Balaji, R. and Pushpavanam, M., Methanesulphonic acid in electroplating related metal finishing industries, Trans. Inst. Met. Finish., 2003, vol. 81, no. 5, pp. 154–158.
14. Danilov, F.I., Vasil’eva, E.A., Butyrina, T.E., and Protsenko, V.S., Electrodeposition of leadtin alloy from methanesulphonate bath containing organic surfactants, Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 6, pp. 697–703.
15. Danilov, F.I., Protsenko, V.S., Vasil’eva, E.A., and Kabat, O.S., Antifriction coatings of Pb-Sn-Cu alloy electrodeposited from methanesulphonate bath, Trans. Inst. Met. Finish., 2011, vol. 89, no. 3, pp. 151–154.
16. Pleshka, E.D., Adhesion of iron coatings with steel and cast iron, Surf. Eng. Appl. Electrochem., 2008, vol. 44, no. 2, pp. 92–97.
17. Pleshka, E.D., Iron coatings from multicomponent methyl sulfate chloride electrolyte, Surf. Eng. Appl. Electrochem., 2008, vol. 44, no. 4, pp. 264–270.
18. Protsenko, V.S., Kityk, A.A., and Danilov, F.I., Voltammetry study of Cr(III)/Cr(II) system in aqueous methanesulfonate solutions, J. Electroanal. Chem., 2011, vol. 661, pp. 213–218.
19. Kityk, A.A., Protsenko, V.S., and Danilov, F.I., Voltammetry study of Cr(III)/Cr(II) system in methane-sulfonate and sulfate solutions: temperature dependences, J. Electroanal. Chem., 2013, vol. 689, pp. 269–275.
20. Protsenko, V. and Danilov, F., Kinetics and mechanism of chromium electrodeposition from formate and oxalate solutions of Cr(III) compounds, Electrochim. Acta, 2009, vol. 54, pp. 5666–5672.
21. Danilov, F.I., Protsenko, V.S., and Gordiienko, V.O., Electrode processes occurring during the electrode-position of chromium-carbon coatings from solutions of Cr(III) salts with carbamide and formic acid additions, Russ. J. Electrochem., 2013, vol. 49, no. 5, pp. 475–482.
22. Kuznetsov, V.V., Vinokurov, E.G., and Kudryavtsev, V.N., Effect of hydrodynamic electrolysis conditions on the kinetics of cathodic processes in chromium(III) sulfate electrolytes, Russ. J. Electrochem., 2000, vol. 36, no. 7, pp. 756–760.
23. Protsenko, V.S., Butyrina, T.E., and Danilov, F.I., Applying a theory of generalized variables to electro-chemical kinetics: interpreting the results of studying chromium deposition from Cr(III) baths, Prot. Met., 2007, vol. 43, no. 4, pp. 398–406.