Environmental benefits of methanesulfonic acid: Comparative properties and advantages

Green Chemistry

Volumn 1, Issue 3, 1999, Pages 127-140

  Gernon, Michael D ^a   Wu, Min ^a,b   Buszta, Thomas ^a   Janney, Patrick ^a  

^a Organic Chemicals   (United States)

^b JOHNSON AND JOHNSON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 22844454644     PISSN: 14639262     EISSN: None     Source Type: Journal    
DOI: 10.1039/a900157c     Document Type: Article

References (51)

1. F. Lowenheim, Electroplating, Technical Reference Publications, Isle of Man, UK, 1995.
2. M. Jordan, The Electrodeposition of Tin and its Alloys, Leuze Verlag, Saulgau, Germany, 1995.
3. Ferrostan is a phenolsulfonic acid based tin plating process, USS Corp., Pittsburg, PA, USA; Ronastan is a MSA based tin plating process, Shipley Ronal, Freeport, NY, USA; Techni Solder is a MSA based Sn/Pb solder plating process, Technic, Inc., Cranston, RI, USA; Solderon is a MSA based Sn/Pb solder plating process, Shipley Ronal, Freeport, NY, USA.
4. S. Patai, Z. Rappoport, The Chemistry of Sulphonic Acids, Esters and their Derivatives, John Wiley and Sons, New York, 1991, p. 251.
5. S. Meibuhr and P. R. Carter, Electrochem. Technol. (J. Electrochem. Soc.), 1964, 2, 267;
6. J. A. McCarthy, Plating (Plating Surf. Finishing), 1960, 805. These references measure the oxidizing characteristics of numerous aqueous electrolytes other than MSA(aq) toward Sn(II). The data for MSA(aq) were generated at Elf Atochem's King of Prussia R&D Center by employing experiments similar to those described in the references.
7. Springborn Laboratories, Inc., An Acute Oral Toxicity Study in Rats with 70% Methane Sitlfonic Acid, SLI Study No. 3255.11, 07/11/97.
8. Fluoroboric acid, MSDS available from Aldrich Chemical Company, Milwaukee, WI, USA; fluorosilicic acid, MSDS available from Riedel-de-Haen, St. Louis, MO, USA.
9. Internal study conducted at Elf Atochem NA, King of Prussia, PA, USA.
10. S. C. Baker, D. P. Kelly and J. C. Murrell, Nature, 1991, 350, 627.
11. M. Gernon, US Pat., 5520794; assigned to Elf Atochem NA, Inc., 1996 (filed in 5/95);
12. F. Vork, Tijdschr. Oppervlaktetech. Corrosiebestrijd., 1995, 39, 242 (published in 6/95).
13. Noller and Gordon, J. Am. Chem. Soc., 1933, 55, 1090;
14. McBain and Williams, J. Am. Chem. Soc., 1933, 55, 2250.
15. M. D. Gernon, M. Nosowitz and N. Martyak, US Pat. Pending, USSN 08/798985 filed; 2/11/97.
16. Kirk-Othmer Encyclopedia of Chemical Technology, 4th edn., John Wiley and Sons, New York, 1994, vol. 11, pp. 309-323.
17. Ullman's Encyclopedia of Industrial Chemistry, 5th edn., VCH, New York, 1988, A11, pp. 334-347.
18. x catalyzed air oxidation of RSH);
19. W. Proell, US Pat. 2489316; assigned to Standard Oil of Indiana, 1949 (sulfonic anhydride preparation);
20. W. Proell, U.S. Patent 2,505,910; assigned to Standard Oil of Indiana, 1950 (sulfonic acid manufacture);
21. W. Proell, US Pat. 2502619; assigned to Standard Oil of Indiana, 1950 (purifying salts of sulfonic acids);
22. W. Proell, US Pat. 2567399; assigned to Standard Oil of Indiana, 1951 (purifying sulfonic acids).
23. W. Proell, US Pat. 2564077; assigned to Standard Oil of Indiana, 1951;
24. W. Proell, J. Org. Chem., 1955, 16, 178.
25. W. Proell, US Pat. 2576535; assigned to Standard Oil of Indiana, 1951;
26. W. Proell and C. Adams, Ind. Eng. Chem., 1949, 41, 2217.
27. W. Proell, US Pat. 2525942; assigned to Standard Oil of Indiana, 1950;
28. W. Proell, C. Adams and B. Shoemaker, Ind. Eng. Chem., 1948, 40, 1129.
29. W. Proell, US Pat. 2525943; assigned to Standard Oil of Indiana, 1950.
30. R. Guertin, US Pat. 3626004; assigned to Pennwalt Corporation, 1967.
31. G. Wheaton, US Pat. 4680095; assigned to Pennwalt Corporation, 1987.
32. This methodology was first described by D. Pletcher and C. J. Myall, J. Chem. Soc., Perkin Trans. 1, 1975, 590.
33. C. Rosenstein, Met. Finish., 1990, January, 17.
34. J. A. Gonzalez, PhD Thesis, University of British Columbia, Electrochemical Processes Within the Slimes Layer of Lead Anodes During Betts Electrorefining, 1991, p. 6.
35. Abstract available from: Diss. Abstr. Int. B, 1993, 53, 4885.
36. Work in progress at Elf Atochem.
37. M. Capelato, J. Nobrega and E. Neves, J. Appl. Electrochem., 1995, 25, 408;
38. A. M. Bond, S. R. Ellis and A. F. Hollenkamp, J. Am. Chem. Soc., 1988, 110, 5293.
39. Internal study conducted at Elf Atochem NA, KoP Technical Center, King of Prussia, PA, USA; SolderOn Process TechSpec #47400, Shipley Ronal Corporation, Freeport, NY, USA, reprinted 2/11/85.
40. J. A. Gonzalez, PhD Thesis, University of British Columbia, Electrochemical Processes Within the Slimes Layer of Lead Anodes During Betts Electrorefining, 1991, pp. 193-196, 312-314;
41. abstract available from: Diss. Abstr. Int. B, 1993, 53, 4885.
42. Note that this market is largely dominated by patents issued to Shipley Ronal Corporation of Freeport, NY, USA; see, for example, US Pat. 5174887, 1992, assigned to LeaRonal Corporation, Freeport, NY, USA.
43. T. Kondo, S. Masaki, H. Inoue and K. Yamakawa, Met. Finish., 1991, October, 32;
44. S. Masaki, H. Inoue and K. Yamakawa, Hyomen Gijutsu Kyokai, 1997, 48, 643.
45. N. Martyak, WO 99/02765; assigned to Atotech Gmbh, 1999.
46. W. A. Proell, C. L. Faust, B. Agruss and E. L. Combs, Monthly Rev. Am. Electroplaters Soc., 1947, 34, 541.
47. N. M. Martyak, A. Jones and R. Wormuth, Proceedings of the International Symposium, Zinc-Based Steel Coating Systems: Production and Performance, held at the TMS Annual Meeting, San Antonio, Texas, 1998, pp. 293-303.
48. Note that this process is covered by international patents. M. D. Gernon, US Pat. 5491247; assigned to Elf Atochem, 1996;
49. M. D. Gernon, Eur. Pat. EP 0711753A1; assigned to Elf Atochem, 1996.
50. M. D. Gernon, G. Smith and J. Elkins, Proceedings of the I2th Annual International Forum on Electrolysis in the Chemical Industry, Clearwater Beach, FL, 1998.
51. R. C. Paul V. P. Kapila and S. K. Sharma, Indian J. Chem., 1974, 12, 651.