Organic–inorganic hybrid sol–gel coatings for metal corrosion protection: a review of recent progress

Journal of Coatings Technology and Research

Volumn 12, Issue 1, 2015, Pages 1-35

  Figueira, R B ^a,b   Silva, C J R ^b   Pereira, E V ^a  

^a NATIONAL LABORATORY FOR CIVIL ENGINEERING   (Portugal)

^b UNIVERSITY OF MINHO   (Portugal)

Author keywords

Coatings; Corrosion; Organic inorganic hybrids; Sol gel method

Indexed keywords

COATINGS; CORROSION; CORROSION RESISTANCE; INORGANIC COATINGS; SILICON COMPOUNDS; SOLS; SUBSTRATES;

ACADEMIC LEVEL; GEL COATINGS; GEL METHOD; INORGANIC HYBRIDS; METALLIC SUBSTRATE; MULTI-LAYER SYSTEM; RECENT PROGRESS; RESEARCH CHALLENGES;

CORROSION RESISTANT COATINGS;

EID: 84922337741     PISSN: 15470091     EISSN: 19353804     Source Type: Journal    
DOI: 10.1007/s11998-014-9595-6     Document Type: Article

References (274)

1. Osborne, JH, “Observations on Chromate Conversion Coatings from a Sol–Gel Perspective.” Prog. Org. Coat., 41 280–286 (2001)
2. Guo, K, “A Review of Magnesium/Magnesium Alloys Corrosion and Its Protection.” Recent Pat. Corros. Sci., 2 13–21 (2010)
3. Guglielmi, M, “Sol–Gel Coatings on Metals.” J. Sol Gel Sci. Technol., 8 443–449 (1997)
4. Twite, RL, Bierwagen, GP, “Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys.” Prog. Org. Coat., 33 91–100 (1998)
5. Metroke, TL, Parkhill, RL, Knobbe, ET, “Passivation of Metal Alloys Using Sol–Gel-Derived Materials—A Review.” Prog. Org. Coat., 41 233–238 (2001)
6. Van Ooij, WJ, et al., “Corrosion Protection Properties of Organofunctional Silanes—An Overview.” Tsinghua Sci. Technol., 10 639–664 (2005)
7. Gray, J, Luan, B, “Protective Coatings on Magnesium and Its Alloys—A Critical Review.” J. Alloys Compd., 336 88–113 (2002)
8. Aegerter, MA, Mennig, M, Sol–Gel Technologies for Glass Producers and Users. Kluwer, Norwell, 2004
9. Dislich, H, “Glassy and Crystalline Systems from Gels: Chemical Basis and Technical Application.” J. Non Cryst. Solids, 57 371–388 (1983)
10. Segal, DL, “Sol–Gel Processing: Routes to Oxide Ceramics Using Colloidal Dispersions of Hydrous Oxides and Alkoxide Intermediates.” J. Non-Cryst. Solids, 63 183–191 (1984)
11. Brinker, CJ, Scherer, GW, Sol–Gel Science: The Physics and Chemistry of Sol–Gel Processing. Academic Press, San Diego, 1990
12. Pierre, AC, In: Pierre, AC (ed.), Introduction to Sol–Gel Processing, p. 4. Kluwer Academic Publishers, Norwell, 1998
13. Brinker, C, Hurd, A, Schunk, P, Frye, G, “Review of Sol–Gel Thin Film Formation.” J. Non Cryst. Solids, 148 424–436 (1992)
14. Hench, LL, West, JK, “The Sol–Gel Process.” Chem. Rev., 90 33–72 (1990)
15. Sanchez, C, Belleville, P, Popall, M, Nicole, L, “Hybrid Materials Themed Issue.” Chem. Soc. Rev., 40 453–1152 (2011)
16. Sanchez, C, et al., “Designed Hybrid Organic–Inorganic Nanocomposites from Functional Nanobuilding Blocks.” Chem. Mater., 13 3061–3083 (2001)
17. Shchukin, DG, Yaremchenko, AA, Ferreira, MGS, Kharton, VV, “Polymer Gel Templating Synthesis of Nanocrystalline Oxide Anodes.” Chem. Mater., 17 5124–5129 (2005)
18. Canto, CF, de A. Prado, LAS, Radovanovic, E, Yoshida, IVP, “Organic–Inorganic Hybrid Materials Derived from Epoxy Resin and Polysiloxanes: Synthesis and Characterization.” Polym. Eng. Sci., 48 141–148 (2008)
19. Sanchez, C, Ribot, F, “Design of Hybrid Organic–Inorganic Materials Synthesized Via Sol–Gel Chemistry.” New J. Chem., 18 1007–1047 (1994)
20. Wojcik, A, Klein, LC, “Transparent Organic/Inorganic Hybrid Gels: A Classification Scheme.” Appl. Organomet. Chem., 11 129–135 (1997)
21. José, NM, de A. Prado, LAS, “Materiais Híbridos Orgânico–Inorgânicos: Preparação e Algumas Aplicações.” Quimica Nova, 28 281–288 (2005)
22. Moreira, SDFC, et al., “Development of New High Transparent Hybrid Organic–Inorganic Monoliths with Surface Engraved Diffraction Pattern.” J. Polym. Sci. B, 50 492–499 (2012)
23. Roberge, P, Handbook of Corrosion Engineering. McGraw-Hill Professional, New York, 1999
24. O’Brien, TF, Bommaraju, TV, Hine, F, Handbook of Chlor-Alkali Technology: Volume I: Fundamentals, Volume II: Brine Treatment and Cell Operation, Volume III: Facility Design and Product Handling, Volume IV: Operations, Volume V: Corrosion, Environmental Issues, and Future Developments. Springer, New York, 2007
25. Kaesche, H, Corrosion of Metals: Physicochemical Principles and Current Problems. Springer, Berlin, 2003
26. Ghali, E, Sastri, VS, Elboujdaini, M, Corrosion Prevention and Protection: Practical Solutions. Wiley, Chichester, 2007
27. Uhlig, HH, Revie, RW, Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering. Wiley, New York, 1991
28. Davis, JR, Surface Engineering for Corrosion and Wear Resistance. ASM International Institute of Materials, Materials Park, 2001
29. Pulker, HK, Coatings on Glass. Elsevier, Amsterdam, 1999
30. Sakka, S, Yoko, T, “Sol–Gel-Derived Coating Films and Applications.” In: Reisfeld, R, Jørgensen, CK (eds.) Chemistry, Spectroscopy and Applications of Sol–Gel Glasses, Vol. 77, pp. 89–118. Springer, Berlin, 1992
31. Magalhães, JM, Silva, JE, Castro, FP, Labrincha, JA, “Physical and Chemical Characterisation of Metal Finishing Industrial Wastes.” J. Environ. Manag., 75 157–166 (2005)
32. Wu, C, Zhang, J, “State-of-Art on Corrosion and Protection of Magnesium Alloys Based on Patent Literatures.” Trans. Nonferrous Met. Soc. China, 21 892–902 (2011)
33. Hu, R-G, Zhang, S, Bu, J-F, Lin, C-J, Song, G-L, “Recent Progress in Corrosion Protection of Magnesium Alloys by Organic Coatings.” Prog. Org. Coat., 73 129–141 (2012)
34. Schmidt, H, Scholze, H, Kaiser, A, “Principles of Hydrolysis and Condensation Reaction of Alkoxysilanes.” J. Non Cryst. Solids, 63 1–11 (1984)
35. Wilkes, GL, Orler, B, Huang, HH, “‘Ceramers’: Hybrid Materials Incorporating Polymeric/Oligomeric Species into Inorganic Glasses Utilizing a Sol–Gel Approach.” Polym. Prep., 26 300–302 (1985)
36. Van Ooij, WJ, Sabata, A, “Characterization of Films of Organofunctional Silanes by TOFSIMS and XPS.” J. Adhes. Sci. Technol., 5 843–863 (1991)
37. Yuan, W, van Ooij, WJ, “Characterization of Organofunctional Silane Films on Zinc Substrates.” J. Colloid Interface Sci., 185 197–209 (1997)
38. Wang, D, Bierwagen, GP, “Sol–Gel Coatings on Metals for Corrosion Protection.” Prog. Org. Coat., 64 327–338 (2009)
39. Mammeri, F, Bourhis, EL, Rozes, L, Sanchez, C, “Mechanical Properties of Hybrid Organic–Inorganic Materials.” J. Mater. Chem., 15 3787 (2005)
40. Castelvetro, V, De Vita, C, “Nanostructured Hybrid Materials from Aqueous Polymer Dispersions.” Adv. Colloid Interface Sci., 108–109 167–185 (2004)
41. Bescher, E, Mackenzie, JD, “Sol–Gel Coatings for the Protection of Brass and Bronze.” J. Sol Gel Sci. Technol., 26 1223–1226 (2003)
42. Attia, SM, Wang, J, Wu, G, Shen, J, Ma, J, “Review on Sol–Gel Derived Coatings: Process, Techniques and Optical Applications.” J. Mater. Sci. Technol., 18 211–218 (2002)
43. Mackenzie, JD, Bescher, EP, “Chemical Routes in the Synthesis of Nanomaterials Using the Sol–Gel Process.” Acc. Chem. Res., 40 810–818 (2007)
44. Niederberger, M, “Nonaqueous Sol–Gel Routes to Metal Oxide Nanoparticles.” Acc. Chem. Res., 40 793–800 (2007)
45. Sakka, S, “Sol–Gel Technology as Representative Processing for Nanomaterials: Case Studies on the Starting Solution.” J. Sol Gel Sci. Technol., 46 241–249 (2007)
46. Dimitriev, Y, Ivanova, Y, Iordanova, R, “History of Sol–Gel Science and Technology.” J. Univ. Chem. Technol. Metall., 43 181–192 (2008)
47. Kozhukharov, S, “Relationship Between the Conditions of Preparation by the Sol–Gel Route and the Properties of the Obtained Products.” J. Univ. Chem. Technol., 44 143–150 (2009)
48. Benvenutti, EV, Moro, CC, Costa, TMH, Gallas, MR, “Materiais híbridos à base de sílica obtidos pelo método Sol–Gel.” Quím. Nova, 32 1926–1933 (2009)
49. Pandey, S, Mishra, SB, “Sol–Gel Derived Organic–Inorganic Hybrid Materials: Synthesis, Characterizations and Applications.” J. Sol Gel Sci. Technol., 59 73–94 (2011)
50. Balgude, D, Sabnis, A, “Sol–Gel Derived Hybrid Coatings as an Environment Friendly Surface Treatment for Corrosion Protection of Metals and Their Alloys.” J. Sol Gel Sci. Technol., 64 124–134 (2012)
51. Abdolah Zadeh, M, van der Zwaag, S, Garcia, SJ, “Routes to Extrinsic and Intrinsic Self-healing Corrosion Protective Sol–Gel Coatings: A Review.” Self Heal. Mater., 1 1–18 (2013)
52. Chaturvedi, S, Dave, PN, “Design Process for Nanomaterials.” J. Mater. Sci., 48 3605–3622 (2013)
53. Wen, J, Wilkes, GL, “Organic/Inorganic Hybrid Network Materials by the Sol–Gel Approach.” Chem. Mater., 8 1667–1681 (1996)
54. Schottner, G, “Hybrid Sol–Gel-Derived Polymers: Applications of Multifunctional Materials.” Chem. Mater., 13 3422–3435 (2001)
55. Walcarius, A, “Electrochemical Applications of Silica-Based Organic–Inorganic Hybrid Materials.” Chem. Mater., 13 3351–3372 (2001)
56. Mitzi, DB, “Thin-Film Deposition of Organic–Inorganic Hybrid Materials.” Chem. Mater., 13 3283–3298 (2001)
57. Hay, JN, Raval, HM, “Synthesis of Organic–Inorganic Hybrids Via the Non-hydrolytic Sol–Gel Process.” Chem. Mater., 13 3396–3403 (2001)
58. Arkhireeva, A, et al., “Synthesis of Organic–Inorganic Hybrid Particles by Sol–Gel Chemistry.” J. Sol Gel Sci. Technol., 31 31–36 (2004)
59. Sanchez, C, Julián, B, Belleville, P, Popall, M, “Applications of Hybrid Organic–Inorganic Nanocomposites.” J. Mater. Chem., 15 3559 (2005)
60. Innocenzi, P, Kidchob, T, Yoko, T, “Hybrid Organic–Inorganic Sol–Gel Materials Based on Epoxy–Amine Systems.” J. Sol Gel Sci. Technol., 35 225–235 (2005)
61. Dash, S, Mishra, S, Patel, S, Mishra, BK, “Organically Modified Silica: Synthesis and Applications Due to its Surface Interaction with Organic Molecules.” Adv. Colloid Interface Sci., 140 77–94 (2008)
62. Lebedev, E, “Hybrid Organo–Inorganic Polymer Systems: Synthesis, Structure and Properties.” Theor. Exp. Chem., 46 391–396 (2011)
63. Sanchez, C, et al., “‘Chimie douce’: A Land of Opportunities for the Designed Construction of Functional Inorganic and Hybrid Organic–Inorganic Nanomaterials.” Comptes Rendus Chim., 13 3–39 (2010)
64. Zheng, S, Li, J, “Inorganic–Organic Sol–Gel Hybrid Coatings for Corrosion Protection of Metals.” J. Sol Gel Sci. Technol., 54 174–187 (2010)
65. Bramfitt, BL. In: Kutz, M (ed.) Handbook of Materials Selection, pp. 25–65. Wiley Inc., New York, 2007. http://onlinelibrary.wiley.com/doi/10.1002/9780470172551.ch2/summary
66. Chou, T, et al., “Organic–Inorganic Hybrid Coatings for Corrosion Protection.” J. Non Cryst. Solids, 290 153–162 (2001)
67. Kumar, S, Alagar, M, Mohan, V, “Studies on Corrosion-Resistant Behavior of Siliconized Epoxy Interpenetrating Coatings Over Mild Steel Surface by Electrochemical Methods.” J. Mater. Eng. Perform., 11 123–129 (2002)
68. Chou, T, Chandrasekaran, C, Cao, GZ, “Sol–Gel-Derived Hybrid Coatings for Corrosion Protection.” J. Sol Gel Sci. Technol., 26 321–327 (2003)
69. Sayilkan, H, Şener, Ş, Şener, E, “The Sol–Gel Synthesis and Application of Some Anticorrosive Coating Materials.” Mater. Sci., 39 106–110 (2003)
70. Gallardo, J, Durán, A, de Damborenea, JJ, “Electrochemical and In Vitro Behaviour of Sol–Gel Coated 316L Stainless Steel.” Corros. Sci., 46 795–806 (2004)
71. Gunji, T, Iizuka, Y, Arimitsu, K, Abe, Y, “Preparation and Properties of Alkoxy(methyl)silsesquioxanes as Coating Agents.” J. Polym. Sci. A, 42 3676–3684 (2004)
72. Castro, Y, Ferrari, B, Moreno, R, Durán, A, “Corrosion Behaviour of Silica Hybrid Coatings Produced from Basic Catalysed Particulate Sols by Dipping and EPD.” Surf. Coat. Technol., 191 228–235 (2005)
73. Pepe, A, Galliano, P, Ceré, S, Aparicio, M, Durán, A, “Hybrid Silica Sol–Gel Coatings on Austempered Ductile Iron (ADI).” Mater. Lett., 59 2219–2222 (2005)
74. Mascia, L, Prezzi, L, Wilcox, GD, Lavorgna, M, “Molybdate Doping of Networks in Epoxy–Silica Hybrids: Domain Structuring and Corrosion Inhibition.” Prog. Org. Coat., 56 13–22 (2006)
75. 2 Sol–Gel.” Surf. Coat. Technol., 200 4967–4975 (2006)
76. Pepe, A, Galliano, P, Aparicio, M, Durán, A, Ceré, S, “Sol–Gel Coatings on Carbon Steel: Electrochemical Evaluation.” Surf. Coat. Technol., 200 3486–3491 (2006)
77. Xing, W, You, B, Wu, L, “Chemical and Anticorrosion Characterization of Polysilsesquioxane Coatings Catalyzed by Different Acids.” J. Coat. Technol. Res., 5 65–72 (2008)
78. Wang, H, Akid, R, “Encapsulated Cerium Nitrate Inhibitors to Provide High-Performance Anti-corrosion Sol–Gel Coatings on Mild Steel.” Corros. Sci., 50 1142–1148 (2008)
79. Phanasgaonkar, A, Raja, VS, “Influence of Curing Temperature, Silica Nanoparticles and Cerium on Surface Morphology and Corrosion Behaviour of Hybrid Silane Coatings on Mild Steel.” Surf. Coat. Technol., 203 2260–2271 (2009)
80. Qian, M, Mcintosh Soutar, A, Tan, XH, Zeng, XT, Wijesinghe, SL, “Two-Part Epoxy-Siloxane Hybrid Corrosion Protection Coatings for Carbon Steel.” Thin Solid Films, 517 5237–5242 (2009)
81. Espinosa-Medina, MA, Carbajal-De la Torre, G, Liu, HB, “Study of Ceramic and Hybrid Coatings Produced by the Sol–Gel Method for Corrosion Protection.” Open Corros. J., 2 197–203 (2009)
82. Sarmento, VHV, et al., “Corrosion Protection of Stainless Steel by Polysiloxane Hybrid Coatings Prepared Using the Sol–Gel Process.” Surf. Coat. Technol., 204 2689–2701 (2010)
83. Hosseinalipour, SM, Ershad-langroudi, A, Hayati, AN, Nabizade-Haghighi, AM, “Characterization of Sol–Gel Coated 316L Stainless Steel for Biomedical Applications.” Prog. Org. Coat., 67 371–374 (2010)
84. Hammer, P, et al., “Improvement of the Corrosion Resistance of Polysiloxane Hybrid Coatings by Cerium Doping.” J. Non Cryst. Solids, 356 2606–2612 (2010)
85. Suegama, PH, et al., “Effect of Cerium(IV) Ions on the Anticorrosion Properties of Siloxane-Poly(methyl methacrylate) Based Film Applied on tin Coated Steel.” Electrochim. Acta, 55 5100–5109 (2010)
86. 2 Coatings on Mild Steel.” Surf. Coat. Technol., 204 1270–1276 (2010)
87. Kannan, AG, Choudhury, NR, Dutta, NK, “Electrochemical Performance of Sol–Gel Derived Phospho-silicate–Methacrylate Hybrid Coatings.” J. Electroanal. Chem., 641 28–34 (2010)
88. Guin, AK, Nayak, SK, Rout, TK, Bandyopadhyay, N, Sengupta, DK, “Corrosion Behavior of Nanohybrid Titania–Silica Composite Coating on Phosphated Steel Sheet.” J. Coat. Technol. Res., 9 97–106 (2011)
89. Hernández-Escolano, M, et al., “The Design and Characterisation of Sol–Gel Coatings for the Controlled-Release of Active Molecules.” J. Sol Gel Sci. Technol., 64 442–451 (2012)
90. Ahmad, S, Zafar, F, Sharmin, E, Garg, N, Kashif, M, “Synthesis and Characterization of Corrosion Protective Polyurethanefattyamide/Silica Hybrid Coating Material.” Prog. Org. Coat., 73 112–117 (2012)
91. Kim, H, Hwang, T, “Corrosion Protection Enhancement Effect by Mixed Silica Nanoparticles of Different Sizes Incorporated in a Sol–Gel Silica Film.” J. Sol Gel Sci. Technol., 63 563–568 (2012)
92. 2 Nanocontainers.” J. Electrochem. Soc., 159 C552–C559 (2012)
93. Hammer, P, dos Santos, FC, Cerrutti, BM, Pulcinelli, SH, Santilli, CV, “Highly Corrosion Resistant Siloxane–Polymethyl Methacrylate Hybrid Coatings.” J. Sol Gel Sci. Technol., 63 266–274 (2012)
94. Cambon, J-B, Ansart, F, Bonino, J-P, Turq, V, “Effect of Cerium Concentration on Corrosion Resistance and Polymerization of Hybrid Sol–Gel Coating on Martensitic Stainless Steel.” Prog. Org. Coat., 75 486–493 (2012)
95. Joncoux-Chabrol, K, Bonino, J-P, Gressier, M, Menu, M-J, Pébère, N, “Improvement of Barrier Properties of a Hybrid Sol–Gel Coating by Incorporation of Synthetic Talc-Like Phyllosilicates for Corrosion Protection of a Carbon Steel.” Surf. Coat. Technol., 206 2884–2891 (2012)
96. Sakai, RT, et al., “Electrochemical Study of TEOS, TEOS/MPTS, MPTS/MMA and TEOS/MPTS/MMA Films on Tin Coated Steel in 3.5% NaCl Solution.” Prog. Org. Coat., 74 288–301 (2012)
97. Subasri, R, Malathi, R, Jyothirmayi, A, Hebalkar, NY, “Synthesis and Characterization of CuO-Hybrid Silica Nanocomposite Coatings on SS 304.” Ceram. Int., 38 5731–5740 (2012)
98. Kumar, N, Jyothirmayi, A, Soma Raju, KRC, Subasri, R, “Effect Of Functional Groups (Methyl, Phenyl) on Organic–Inorganic Hybrid Sol–Gel Silica Coatings on Surface Modified SS 316.” Ceram. Int., 38 6565–6572 (2012)
99. Zandi-zand, R, Verbeken, K, Adriaens, A, “Corrosion Resistance Performance of Cerium Doped Silica Sol–Gel Coatings on 304L Stainless Steel.” Prog. Org. Coat., 75 463–473 (2012)
100. 2 Ceramic Nanostructures into Polyurethane Coatings for the Corrosion Protection of Carbon Steel.” J. Mater. Sci., 48 1067–1084 (2012)
101. Certhoux, E, et al., “New Sol–Gel Formulations to Increase the Barrier Effect of a Protective Coating Against the Corrosion of Steels.” Prog. Org. Coat., 76 165–172 (2013)
102. Hammer, P, dos Santos, FC, Cerrutti, BM, Pulcinelli, SH, Santilli, CV, “Carbon Nanotube-Reinforced Siloxane-PMMA Hybrid Coatings with High Corrosion Resistance.” Prog. Org. Coat., 76 601–608 (2013)
103. Rahoui, S, Turq, V, Bonino, J-P, “Effect of Thermal Treatment on Mechanical and Tribological Properties of hybrid Coatings Deposited by Sol–Gel Route on Stainless Steel.” Surf. Coat. Technol., 235 15–23 (2013)
104. Fedel, M, et al., “Effect of Na-Montmorillonite Sonication on the Protective Properties of Hybrid Silica Coatings.” Electrochim. Acta, (2013). doi:10.1016/j.electacta.2013.11.006
105. Jeeva Jothi, K, Palanivelu, K, “Synergistic Effect of Silane Modified Nanocomposites for Active Corrosion Protection.” Ceram. Int., 39 7619–7625 (2013)
106. 3 As Catalyst.” J. Sol Gel Sci. Technol., 66 133–138 (2013)
107. Balgude, D, Konge, K, Sabnis, A, “Synthesis and Characterization of Sol–Gel Derived CNSL Based Hybrid Anti-corrosive Coatings.” J. Sol Gel Sci. Technol., (2013). doi:10.1007/s10971-013-3198-z
108. Santana, I, Pepe, A, Jimenez-Pique, E, Pellice, S, Ceré, S, “Silica-Based Hybrid Coatings for Corrosion Protection of Carbon Steel. Part I: Effect of Pretreatment with Phosphoric Acid.” Surf. Coat. Technol., 236 476–484 (2013)
109. Hernandez, M, et al., “Characterization of Hybrid Sol–Gel Coatings Doped with Hydrotalcite-Like. Compounds on Steel and Stainless Steel Alloys.” ECS Trans., 47 195–206 (2013)
110. Chawada, G, Dholakiya, BZ, “Organic–Inorganic Hybrid Sol–Gel Pretreatments for Corrosion Protection of Mild Steel in Neutral and Acidic Solutions.” Res. Chem. Intermed., (2013). doi:10.1007/s11164-013-1479-3
111. Karmakar, B, De, G, Ganguli, D, “Dense Silica Microspheres from Organic and Inorganic Acid Hydrolysis.” J. Non Cryst. Solids, 272 119–126 (2000)
112. Wagh, PB, Rao, AV, Haranath, D, “Influence of Molar Ratios of Precursor, Solvent and Water on Physical Properties of Citric Acid Catalyzed TEOS Silica Aerogels.” Mater. Chem. Phys., 53 41–47 (1998)
113. Kunst, SR, et al., “Corrosion Resistance of Siloxane–Poly(methyl methacrylate) Hybrid Films Modified with Acetic Acid on Tin Plate Substrates: Influence of Tetraethoxysilane Addition.” Appl. Surf. Sci., (2013). doi:10.1016/j.apsusc.2013.09.182
114. Wojcik, AB, Klein, LC, “Transparent Inorganic/organic Copolymers by the Sol–Gel Process: Copolymers of Tetraethyl Orthosilicate (TEOS), Vinyl Triethoxysilane (VTES) and (Meth)acrylate Monomers.” J. Sol Gel Sci. Technol., 4 57–66 (1995)
115. Álvarez, D, Collazo, A, Hernández, M, Nóvoa, XR, Pérez, C, “Characterization of Hybrid Sol–Gel Coatings Doped with Hydrotalcite-Like Compounds to Improve Corrosion Resistance of AA2024-T3 Alloys.” Prog. Org. Coat., 67 152–160 (2010)
116. Parkhill, R, Knobbe, E, Donley, M, “Application and Evaluation of Environmentally Compliant Spray-Coated Ormosil Films as Corrosion Resistant Treatments for Aluminum 2024-T3.” Prog. Org. Coat., 41 261–265 (2001)
117. Kasten, LS, et al., “An XPS Study of Cerium Dopants In Sol–Gel Coatings for Aluminum 2024-T3.” Surf. Coat. Technol., 140 11–15 (2001)
118. Metroke, T, Kachurina, O, Knobbe, ET, “Spectroscopic and Corrosion Resistance Characterization of GLYMO–TEOS Ormosil Coatings for Aluminum Alloy Corrosion Inhibition.” Prog. Org. Coat., 44 295–305 (2002)
119. Metroke, T, Kachurina, O, “Spectroscopic and Corrosion Resistance Characterization of Amine and Super Acid-Cured Hybrid Organic–Inorganic Thin Films on 2024-T3 Aluminum Alloy.” Prog. Org. Coat., 44 185–199 (2002)
120. Voevodin, N, Balbyshev, V, Khobaib, M, Donley, M, “Nanostructured Coatings Approach for Corrosion Protection.” Prog. Org. Coat., 47 416–423 (2003)
121. Conde, A, Durán, A, de Damborenea, J, “Polymeric Sol–Gel Coatings as Protective Layers of Aluminium Alloys.” Prog. Org. Coat., 46 288–296 (2003)
122. Donley, MS, et al., “The Self-assembled Nanophase Particle (SNAP) Process: A Nanoscience Approach to Coatings.” Prog. Org. Coat., 47 401–415 (2003)
123. Metroke, TL, Gandhi, JS, Apblett, A, “Corrosion Resistance Properties of Ormosil Coatings on 2024-T3 Aluminum Alloy.” Prog. Org. Coat., 50 231–246 (2004)
124. Metroke, TL, Apblett, A, “Effect of Solvent Dilution on Corrosion Protective Properties of Ormosil Coatings on 2024-T3 Aluminum Alloy.” Prog. Org. Coat., 51 36–46 (2004)
125. Zandi-zand, R, Ershad-langroudi, A, Rahimi, A, “Silica Based Organic–Inorganic Hybrid Nanocomposite Coatings for Corrosion Protection.” Prog. Org. Coat., 53 286–291 (2005)
126. Zandi-zand, R, Ershad-langroudi, A, Rahimi, A, “Organic–Inorganic Hybrid Coatings for Corrosion Protection of 1050 Aluminum Alloy.” J. Non Cryst. Solids, 351 1307–1311 (2005)
127. Donley, MS, Balbyshev, VN, Voevodin, NN, “Self-assembled NAnophase Particle (SNAP) Surface Treatments for Corrosion Protection of AA2024-T3.” Prog. Org. Coat., 52 34–38 (2005)
128. Liu, Y, Sun, D, You, H, Chung, JS, “Corrosion Resistance Properties of Organic–Inorganic Hybrid Coatings on 2024 Aluminum Alloy.” Appl. Surf. Sci., 246 82–89 (2005)
129. Khramov, AN, Voevodin, NN, Balbyshev, VN, Mantz, RA, “Sol–Gel-Derived Corrosion-Protective Coatings with Controllable Release of Incorporated Organic Corrosion Inhibitors.” Thin Solid Films, 483 191–196 (2005)
130. Zheludkevich, M, et al., “Nanostructured Sol–Gel Coatings Doped with Cerium Nitrate as Pre-treatments for AA2024-T3. Corrosion Protection Performance.” Electrochim. Acta, 51 208–217 (2005)
131. Voevodin, NN, Balbyshev, VN, Donley, MS, “Investigation of Corrosion Protection Performance of Sol–Gel Coatings on AA2024-T3.” Prog. Org. Coat., 52 28–33 (2005)
132. Zheludkevich, ML, Serra, R, Montemor, MF, Salvado, IMM, Ferreira, MGS, “Corrosion Protective Properties of Nanostructured Sol–Gel Hybrid Coatings to AA2024-T3.” Surf. Coat. Technol., 200 3084–3094 (2006)
133. Voevodin, NN, Kurdziel, JW, Mantz, R, “Corrosion Protection for Aerospace Aluminum Alloys by Modified Self-assembled NAnophase Particle (MSNAP) Sol–Gel.” Surf. Coat. Technol., 201 1080–1084 (2006)
134. Wu, KH, Chang, TC, Yang, CC, Wang, GP, “Dynamics and Corrosion Resistance of Amine-cured Organically Modified Silicate Coatings on Aluminum Alloys.” Thin Solid Films, 513 84–89 (2006)
135. Vezir Kahraman, M, Kuğu, M, Menceloğlu, Y, Kayaman-Apohan, N, Güngör, A, “The Novel Use of Organo Alkoxy Silane for the Synthesis of Organic–Inorganic Hybrid Coatings.” J. Non Cryst. Solids, 352 2143–2151 (2006)
136. Wu, KH, Li, MC, Yang, CC, Wang, GP, “Domain Size and Thermal Stability of Amine-cured Hybrid Films as Corrosion Resistance Treatments for Aluminum Alloy.” J. Non Cryst. Solids, 352 2897–2904 (2006)
137. Han, Y-H, Taylor, A, Mantle, MD, Knowles, KM, “UV Curing of Organic–Inorganic Hybrid Coating Materials.” J. Sol Gel Sci. Technol., 43 111–123 (2007)
138. Wang, H, Akid, R, “A Room Temperature Cured Sol–Gel Anticorrosion Pre-treatment for Al 2024-T3 Alloys.” Corros. Sci., 49 4491–4503 (2007)
139. Wu, KH, Chao, CM, Yeh, TF, Chang, TC, “Thermal Stability and Corrosion Resistance of Polysiloxane Coatings on 2024-T3 and 6061-T6 Aluminum Alloy.” Surf. Coat. Technol., 201 5782–5788 (2007)
140. Pathak, SS, Khanna, AS, Sinha, TJM, “HMMM Cured Corrosion Resistance Waterborne Ormosil Coating for Aluminum Alloy.” Prog. Org. Coat., 60 211–218 (2007)
141. Barkhudarov, PM, et al., “Corrosion Inhibition Using Superhydrophobic Films.” Corros. Sci., 50 897–902 (2008)
142. Lampke, T, Darwich, S, Nickel, D, Wielage, B, “Development and Characterization of Sol–Gel Composite Coatings on Aluminum Alloys for Corrosion Protection.” Mater. Werkst., 39 914–919 (2008)
143. Tiwari, A, Zhu, J, Hihara, LH, “The Development of Low-Temperature Hardening Silicone Ceramer Coatings for the Corrosion Protection of Metals.” Surf. Coat. Technol., 202 4620–4635 (2008)
144. Poznyak, SK, et al., “Preparation and Corrosion Protective Properties of Nanostructured Titania-Containing Hybrid Sol–Gel Coatings on AA2024.” Prog. Org. Coat., 62 226–235 (2008)
145. Yasakau, KA, Zheludkevich, ML, Karavai, OV, Ferreira, MGS, “Influence of Inhibitor Addition on the Corrosion Protection Performance of Sol–Gel Coatings on AA2024.” Prog. Org. Coat., 63 352–361 (2008)
146. 2 Nanoparticles on the Protection of AA2024.” Corros. Sci., 50 1283–1291 (2008)
147. Vreugdenhil, AJ, Gelling, VJ, Woods, ME, Schmelz, JR, Enderson, BP, “The Role of Crosslinkers in Epoxy–Amine Crosslinked Silicon Sol–Gel Barrier Protection Coatings.” Thin Solid Films, 517 538–543 (2008)
148. Pathak, SS, Khanna, AS, “Synthesis and Performance Evaluation of Environmentally Compliant Epoxysilane Coatings for Aluminum Alloy.” Prog. Org. Coat., 62 409–416 (2008)
149. Wang, D, Chen, X, Zhang, X, Liu, Y, Hu, L, “Enhancement Corrosion Resistance of (3-Methacryloxypropyl)silsesquioxane Hybrid Films and Its Validation by Gas-Molecule Diffusion Coefficients Using MD Simulation.” J. Sol Gel Sci. Technol., 49 293–300 (2008)
150. Rosero-Navarro, NC, Pellice, SA, Castro, Y, Aparicio, M, Durán, A, “Improved Corrosion Resistance of AA2024 Alloys Through Hybrid Organic–Inorganic Sol–Gel Coatings Produced from Sols with Controlled Polymerisation.” Surf. Coat. Technol., 203 1897–1903 (2009)
151. Pathak, SS, Khanna, AS, “Investigation of Anti-corrosion Behavior of Waterborne Organosilane–Polyester Coatings for AA6011 Aluminum Alloy.” Prog. Org. Coat., 65 288–294 (2009)
152. Rosero-Navarro, NC, Pellice, SA, Durán, A, Ceré, S, Aparicio, M, “Corrosion Protection of Aluminium Alloy AA2024 with Cerium Doped Methacrylate-Silica Coatings.” J. Sol Gel Sci. Technol., 52 31–40 (2009)
153. Pirhady Tavandashti, N, Sanjabi, S, Shahrabi, T, “Corrosion Protection Evaluation of Silica/Epoxy Hybrid Nanocomposite Coatings to AA2024.” Prog. Org. Coat., 65 182–186 (2009)
154. 2-Filled Sol–Gel Coatings for Corrosion Protection of AA2024-T3 Aluminium Alloy.” Corros. Sci., 51 2304–2315 (2009)
155. Raps, D, et al., “Electrochemical Study of Inhibitor-Containing Organic–Inorganic Hybrid Coatings on AA2024.” Corros. Sci., 51 1012–1021 (2009)
156. Li, Y-S, Lu, W, Wang, Y, Tran, T, “Studies of (3-Mercaptopropyl)trimethoxylsilane and Bis(trimethoxysilyl)ethane Sol–Gel Coating on Copper and Aluminum.” Spectrochim. Acta A, 73 922–928 (2009)
157. Kakde, V, Mannari, V, “Advanced Chrome-Free Organic–Inorganic Hybrid Pretreatments for Aerospace Aluminum Alloy 2024-T3—Application of Novel Bis-ureasil Sol–Gel Precursors.” J. Coat. Technol. Res., 6 201–211 (2009)
158. Rosero-Navarro, NC, et al., “Optimization of Hybrid Sol–Gel Coatings by Combination of Layers with Complementary Properties for Corrosion Protection of AA2024.” Prog. Org. Coat., 69 167–174 (2010)
159. Álvarez, P, Collazo, A, Covelo, A, Nóvoa, XR, Pérez, C, “The Electrochemical Behaviour of Sol–Gel Hybrid Coatings Applied on AA2024-T3 Alloy: Effect of the Metallic Surface Treatment.” Prog. Org. Coat., 69 175–183 (2010)
160. Varma, PCR, et al., “Corrosion Protection of AA 2024-T3 Aluminium Alloys Using 3,4-Diaminobenzoic Acid Chelated Zirconium–Silane Hybrid Sol–Gels.” Thin Solid Films, 518 5753–5761 (2010)
161. Shi, H, Liu, F, Han, E, “Corrosion Behaviour of Sol–Gel Coatings Doped with Cerium Salts on 2024-T3 Aluminum Alloy.” Mater. Chem. Phys., 124 291–297 (2010)
162. Shi, H, Liu, F, Han, E, “Characterization of Self-assembled Nano-phase Silane-Based Particle Coating.” Trans. Nonferrous Met. Soc. China, 20 1928–1935 (2010)
163. Becchi, DM, Luca, MA, Martinelli, M, Mitidieri, S, “Organic–Inorganic Coatings Based on Epoxidised Castor Oil/APTES/TEOS.” J. Am. Oil Chem. Soc., 88 101–109 (2010)
164. Feng, Z, Liu, Y, Thompson, GE, Skeldon, P, “Sol–Gel Coatings for Corrosion Protection of 1050 Aluminium Alloy.” Electrochim. Acta, 55 3518–3527 (2010)
165. Tiwari, A, Hihara, LH, “High Performance Reaction-Induced Quasi-ceramic Silicone Conversion Coating for Corrosion Protection of Aluminium Alloys.” Prog. Org. Coat., 69 16–25 (2010)
166. Kumar, A, Kanta, A, Birbilis, N, Williams, T, Muddle, BCA, “Pseudoboehmite–Silane Hybrid Coating for Enhanced Corrosion Protection of AA2024-T3.” J. Electrochem. Soc., 157 C346 (2010)
167. Collazo, A, Hernández, M, Nóvoa, XR, Pérez, C, “Effect of the Addition of Thermally Activated Hydrotalcite on the Protective Features of Sol–Gel Coatings Applied on AA2024 Aluminium Alloys.” Electrochim. Acta, 56 7805–7814 (2011)
168. Wittmar, A, Wittmar, M, Caparrotti, H, Veith, M, “The Influence of the Inhibitor Particle Sizes to the Corrosion Properties of Hybrid Sol–Gel Coatings.” J. Sol Gel Sci. Technol., 59 621–628 (2011)
169. Croes, KJ, et al., “An Electrochemical Study of Corrosion Protection by In Situ Oxidative Polymerization in Phenylenediamine Crosslinked Sol–Gel Hybrid Coatings.” Electrochim. Acta, 56 7796–7804 (2011)
170. Roussi, E, Tsetsekou, A, Tsiourvas, D, Karantonis, A, “Novel Hybrid Organo-Silicate Corrosion Resistant Coatings Based on Hyperbranched Polymers.” Surf. Coat. Technol., 205 3235–3244 (2011)
171. Varma, PCR, Periyat, P, Oubaha, M, McDonagh, C, Duffy, B, “Application of Niobium Enriched Ormosils as Thermally Stable Coatings for Aerospace Aluminium Alloys.” Surf. Coat. Technol., 205 3992–3998 (2011)
172. Cambon, J-B, et al., “Effect of Cerium on Structure Modifications of a Hybrid Sol–Gel Coating, Its Mechanical Properties and Anti-corrosion Behavior.” Mater. Res. Bull., 47 3170–3176 (2012)
173. Iroh, JO, Rajamani, D, “Synthesis and Structure of Environmentally Friendly Hybrid Clay/Organosilane Nanocomposite Coatings.” J. Inorg. Organomet. Polym. Mater., 22 595–603 (2012)
174. Wittmar, A, Wittmar, M, Ulrich, A, Caparrotti, H, Veith, M, “Hybrid Sol–Gel Coatings Doped with Transition Metal Ions for the Protection of AA 2024-T3.” J. Sol Gel Sci. Technol., 61 600–612 (2012)
175. Kozhukharov, S, et al., “Protective Ability of Hybrid Nano-composite Coatings with Cerium Sulphate as Inhibitor Against Corrosion of AA2024 Aluminium Alloy.” Prog. Org. Coat., 73 95–103 (2012)
176. Dias, SAS, Lamaka, SV, Nogueira, CA, Diamantino, TC, Ferreira, MGS, “Sol–Gel Coatings Modified with Zeolite Fillers for Active Corrosion Protection of AA2024.” Corros. Sci., 62 153–162 (2012)
177. Dias, SAS, et al., “The Role of Ce(III)-Enriched Zeolites on the Corrosion Protection of AA2024-T3.” Electrochim. Acta, 112 549–556 (2013)
178. Collazo, A, Covelo, A, Nóvoa, XR, Pérez, C, “Corrosion Protection Performance of Sol–Gel Coatings Doped with Red Mud Applied on AA2024-T3.” Prog. Org. Coat., 74 334–342 (2012)
179. Gupta, G, Pathak, SS, Khanna, AS, “Anticorrosion Performance of Eco-friendly Silane Primer for Coil Coating Applications.” Prog. Org. Coat., 74 106–114 (2012)
180. Abuín, M, Serrano, A, Llopis, J, García, MA, Carmona, N, “Silica Doped with Lanthanum Sol–Gel Thin Films for Corrosion Protection.” Thin Solid Films, 520 5267–5271 (2012)
181. 2 Nanocontainers Loaded with Inhibitors for Corrosion Protection of AA2024-T3.” Prog. Org. Coat., 73 142–148 (2012)
182. Hojjati Najafabadi, A, Mozaffarinia, R, Rahimi, H, Shoja Razavi, R, Paimozd, E, “Sol–Gel Processing of Hybrid Nanocomposite Protective Coatings Using Experimental Design.” Prog. Org. Coat., 76 293–301 (2013)
183. May, M, Wang, H, Akid, R, “Bond Strength of Hybrid Sol–Gel Coatings with Different Additives.” J. Coat. Technol. Res., 10 407–413 (2012)
184. Yasakau, KA, Kallip, S, Zheludkevich, ML, Ferreira, MGS, “Active Corrosion Protection of AA2024 by Sol–Gel Coatings with Cerium Molybdate Nanowires.” Electrochim. Acta, 112 236–246 (2013)
185. Roussi, E, Tsetsekou, A, Skarmoutsou, A, Charitidis, CA, Karantonis, A, “Anticorrosion and Nanomechanical Performance of Hybrid Organo-silicate Coatings Integrating Corrosion Inhibitors.” Surf. Coat. Technol., 232 131–141 (2013)
186. Wankhede, RG, Morey, S, Khanna, AS, Birbilis, N, “Development of Water-Repellent Organic–Inorganic Hybrid Sol–Gel Coatings on Aluminum Using Short Chain Perfluoro Polymer Emulsion.” Appl. Surf. Sci., 283 1051–1059 (2013)
187. Naderi, R, Fedel, M, Deflorian, F, Poelman, M, Olivier, M, “Synergistic Effect of Clay Nanoparticles and Cerium Component on the Corrosion Behavior of Eco-friendly Silane Sol–Gel Layer Applied on Pure Aluminum.” Surf. Coat. Technol., 224 93–100 (2013)
188. Capelossi, VR, et al., “Corrosion Protection of CLAD 2024 Aluminum Alloy Anodized in Tartaric-Sulfuric Acid Bath and Protected with Hybrid Sol–Gel Coating.” Electrochim. Acta, (2013). doi:10.1016/j.electacta.2013.09.004
189. Rahimi, H, Mozaffarinia, R, Hojjatinajafabadi, A, “Corrosion and Wear Resistance Characterization of Environmentally Friendly Sol–Gel Hybrid Nanocomposite Coating on AA5083.” J. Mater. Sci. Technol., 29 603–608 (2013)
190. 3+ Doped Sol–Gel Nanocomposite Coating on Aluminum Alloy.” Prog. Org. Coat., 76 367–374 (2013)
191. Rahimi, H, Mozaffarinia, R, Hojjati Najafabadi, A, Shoja Razavi, R, Paimozd, E, “Optimization of Process Factors for the Synthesis of Advanced Chrome-Free Nanocomposite Sol–Gel Coatings for Corrosion Protection of Marine Aluminum Alloy AA5083 by Design of Experiment.” Prog. Org. Coat., 76 307–317 (2013)
192. Bechi, DM, Luca, MAD, Martinelli, M, Mitidieri, S, “Organic–Inorganic Coatings Based on Epoxidized Castor Oil with APTES/TIP and TEOS/TIP.” Prog. Org. Coat., 76 736–742 (2013)
193. Zheludkevich, ML, et al., “Active Protection Coatings with Layered Double Hydroxide Nanocontainers of Corrosion Inhibitor.” Corros. Sci., 52 602–611 (2010)
194. Shchukin, DG, et al., “Active Anticorrosion Coatings with Halloysite Nanocontainers.” J. Phys. Chem. C, 112 958–964 (2008)
195. Zheludkevich, ML, Shchukin, DG, Yasakau, KA, Möhwald, H, Ferreira, MGS, “Anticorrosion Coatings with Self-healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor.” Chem. Mater., 19 402–411 (2007)
196. Tan, ALK, Soutar, AM, “Hybrid Sol–Gel Coatings for Corrosion Protection of Copper.” Thin Solid Films, 516 5706–5709 (2008)
197. Peng, S, et al., “The Enhancement of Benzotriazole on Epoxy Functionalized Silica Sol–Gel Coating for Copper Protection.” Appl. Surf. Sci., 276 284–290 (2013)
198. Kiele, E, et al., “Methyl-Modified Hybrid Organic–Inorganic Coatings for the Conservation of Copper.” J. Cult. Herit., (2013). doi:10.1016/j.culher.2013.06.002
199. Gusakov, AG, Voropayev, AG, Zheludkevich, ML, Vecher, AA, Raspopov, SA, “Studies of the Interaction of Copper with Atomic and Molecular Oxygen.” Phys. Chem. Chem. Phys., 1 5311–5314 (1999)
200. Honkanen, M, Hoikkanen, M, Vippola, M, Vuorinen, J, Lepistö, T, “Aminofunctional Silane Layers for Improved Copper–Polymer Interface Adhesion.” J. Mater. Sci., 46 6618–6626 (2011)
201. Yang, JC, Kolasa, B, Gibson, JM, Yeadon, M, “Self-limiting Oxidation of Copper.” Appl. Phys. Lett., 73 2841–2843 (1998)
202. Deflorian, F, Rossi, S, Fedrizzi, L, Fedel, M, “Integrated Electrochemical Approach for the Investigation of Silane Pre-treatments for Painting Copper.” Prog. Org. Coat., 63 338–344 (2008)
203. Finšgar, M, Milošev, I, “Inhibition of Copper Corrosion by 1,2,3-Benzotriazole: A Review.” Corros. Sci., 52 2737–2749 (2010)
204. González, S, Gil, M, Hernández, J, Fox, V, Souto, R, “Resistance to Corrosion of Galvanized Steel Covered with an Epoxy–Polyamide Primer Coating.” Prog. Org. Coat., 41 167–170 (2001)
205. Garcia-Heras, M, et al., “Preparation and Electrochemical Study of Cerium–Silica Sol–Gel Thin Films.” J. Alloys Compd., 380 219–224 (2004)
206. Eliziane, M, et al., “Characterization of Organic–Inorganic Hybrid Coatings for Corrosion Protection of Galvanized Steel and Electroplated ZnFe Steel 2. Experimental Procedure.” Mater. Res., 9 59–64 (2006)
207. Conde, A, Damborenea, J, Durán, A, Menning, M, “Protective Properties of a Sol–Gel Coating on Zinc Coated Steel.” J. Sol Gel Sci. Technol., 37 79–85 (2006)
208. Fedel, M, et al., “Corrosion Protection Properties of Silane Pre-treated Powder Coated Galvanized Steel.” Prog. Org. Coat., 66 118–128 (2009)
209. Deflorian, F, Rossi, S, Fedel, M, Motte, C, “Electrochemical Investigation of High-Performance Silane Sol–Gel Films Containing Clay Nanoparticles.” Prog. Org. Coat., 69 158–166 (2010)
210. Fedel, M, et al., “Compatibility Between Cataphoretic Electro-coating and Silane Surface Layer for the Corrosion Protection of Galvanized Steel.” Prog. Org. Coat., 69 118–125 (2010)
211. Motte, C, et al., “Improvement of Corrosion Protection Offered to Galvanized Steel by Incorporation of Lanthanide Modified Nanoclays in Silane Layer.” Prog. Org. Coat., 74 326–333 (2012)
212. Kartsonakis, IA, Balaskas, AC, Koumoulos, EP, Charitidis, CA, Kordas, GC, “Incorporation of Ceramic Nanocontainers into Epoxy Coatings for the Corrosion Protection of Hot Dip Galvanized Steel.” Corros. Sci., 57 30–41 (2012)
213. Zand, RZ, Verbeken, K, Adriaens, A, “Influence of the Cerium Concentration on the Corrosion Performance of Ce-Doped Silica Hybrid Coatings on Hot Dip Galvanized Steel Substrates.” Int. J. Electrochem. Sci., 8 549 (2013)
214. Xue, D, Van Ooij, WJ, “Corrosion Performance Improvement of Hot-Dipped Galvanized (HDG) Steels by Electro-deposition of Epoxy-Resin–Ester Modified Bis-[tri-ethoxy-silyl]ethane (BTSE) Coatings.” Prog. Org. Coat., 76 1095–1102 (2013)
215. Figueira, RB, Silva, CJ, Pereira, EV, Salta, MM, “Ureasilicate Hybrid Coatings for Corrosion Protection of Galvanized Steel in Cementitious Media.” J. Electrochem. Soc., 160 C467–C479 (2013)
216. Magalhães, AAO, Margarit, ICP, Mattos, OR, “Molybdate Conversion Coatings on Zinc Surfaces.” J. Electroanal. Chem., 572 433–440 (2004)
217. Lin, B-L, Lu, J-T, Kong, G, “Effect of Molybdate Post-sealing on the Corrosion Resistance of Zinc Phosphate Coatings on Hot-Dip Galvanized Steel.” Corros. Sci., 50 962–967 (2008)
218. Da Silva, CG, et al., “The Molybdate–Zinc Conversion Process.” Corros. Sci., 51 151–158 (2009)
219. Moutarlier, V, Gigandet, MP, Ricq, L, Pagetti, J, “Electrochemical Characterisation of Anodic Oxidation Films Formed in Presence of Corrosion Inhibitors.” Appl. Surf. Sci., 183 1–9 (2001)
220. Bibber, JW, “Non-chrome-Containing Conversion Coatings for Zinc and Zinc Alloys: Environmentally Friendly Alternatives Provide Equal or Better Adhesion and Corrosion Resistance as Conventional Methods.” Met. Finish., 106 41–46 (2008)
221. Hara, M, Ichino, R, Okido, M, Wada, N, “Corrosion Protection Property of Colloidal Silicate Film on Galvanized Steel.” Surf. Coat. Technol., 169–170 679–681 (2003)
222. Dalbin, S, Maurin, G, Nogueira, RP, Persello, J, Pommier, N, “Silica-Based Coating for Corrosion Protection of Electrogalvanized Steel.” Surf. Coat. Technol., 194 363–371 (2005)
223. Socha, RP, Fransaer, J, “Mechanism of Formation of Silica–Silicate Thin Films on Zinc.” Thin Solid Films, 488 45–55 (2005)
224. Socha, RP, Pommier, N, Fransaer, J, “Effect of Deposition Conditions on the Formation of Silica–Silicate Thin Films.” Surf. Coat. Technol., 201 5960–5966 (2007)
225. Klimow, G, Fink, N, Grundmeier, G, “Electrochemical Studies of the Inhibition of the Cathodic Delamination of Organically Coated Galvanised Steel by Thin Conversion Films.” Electrochim. Acta, 53 1290–1299 (2007)
226. Zhu, L, Yang, F, Ding, N, “Corrosion Resistance of the Electro-galvanized Steel Treated in a Titanium Conversion Solution.” Surf. Coat. Technol., 201 7829–7834 (2007)
227. Hosseini, M, Ashassi-Sorkhabi, H, Ghiasvand, HAY, “Corrosion Protection of Electro-Galvanized Steel by Green Conversion Coatings.” J. Rare Earths, 25 537–543 (2007)
228. Bernal, S, et al., “Lanthanide Salts as Alternative Corrosion Inhibitors.” J. Alloys Compd., 225 638–641 (1995)
229. Arenas, MA, Casado, C, Damborenea, JD, “Influence of the Conversion Coating on the Corrosion of Galvanized Reinforcing Steel.” Cem. Concr. Compos., 28 267–275 (2007)
230. Hinton, BRW, “Corrosion Inhibition with Rare Earth Metal Salts.” J. Alloys Compd., 180 15–25 (1992)
231. Van de Leest, RE, Krijl, G, “A Tungstate Conversion Coating on Tin.” Thin Solid Films, 72 237–246 (1980)
232. Da Silva, CG, Correia, AN, de Lima-Neto, P, Margarit, ICP, Mattos, OR, “Study of Conversion Coatings Obtained from Tungstate–Phosphoric Acid Solutions.” Corros. Sci., 47 709–722 (2005)
233. Zou, Z, Li, N, Li, D, Liu, H, Mu, S, “A Vanadium-Based Conversion Coating as Chromate Replacement for Electrogalvanized Steel Substrates.” J. Alloys Compd., 509 503–507 (2011)
234. Tan, ALK, Soutar, AM, Annergren, IF, Liu, YN, “Multilayer Sol–Gel Coatings for Corrosion Protection of Magnesium.” Surf. Coat. Technol., 198 478–482 (2005)
235. Khramov, AN, Balbyshev, VN, Kasten, LS, Mantz, RA, “Sol–Gel Coatings with Phosphonate Functionalities for Surface Modification of Magnesium Alloys.” Thin Solid Films, 514 174–181 (2006)
236. Lamaka, SV, et al., “Novel Hybrid Sol–Gel Coatings for Corrosion Protection of AZ31B Magnesium Alloy.” Electrochim. Acta, 53 4773–4783 (2008)
237. Khramov, AN, Johnson, JA, “Phosphonate-Functionalized ORMOSIL Coatings for Magnesium Alloys.” Prog. Org. Coat., 65 381–385 (2009)
238. Guo, X, An, M, Yang, P, Su, C, Zhou, Y, “Property Characterization and Formation Mechanism of Anticorrosion Film Coated on AZ31B Mg Alloy by SNAP Technology.” J. Sol Gel Sci. Technol., 52 335–347 (2009)
239. Shi, H, Liu, F, Han, E, “Corrosion Protection of AZ91D Magnesium Alloy with Sol–Gel Coating Containing 2-Methyl Piperidine.” Prog. Org. Coat., 66 183–191 (2009)
240. Hu, J, Li, Q, Zhong, X, Zhang, L, Chen, B, “Composite Anticorrosion Coatings for AZ91D Magnesium Alloy with Molybdate Conversion Coating and Silicon Sol–Gel Coatings.” Prog. Org. Coat., 66 199–205 (2009)
241. Galio, AF, et al., “Inhibitor-Doped Sol–Gel Coatings for Corrosion Protection of Magnesium Alloy AZ31.” Surf. Coat. Technol., 204 1479–1486 (2010)
242. Barranco, V, et al., “Electrochemical Study of Tailored Sol–Gel Thin Films as Pre-treatment Prior to Organic Coating for AZ91 Magnesium Alloy.” Prog. Org. Coat., 68 347–355 (2010)
243. Zhong, X, et al., “Effect of Cerium Concentration on Microstructure, Morphology and Corrosion Resistance of Cerium–Silica Hybrid Coatings on Magnesium Alloy AZ91D.” Prog. Org. Coat., 69 52–56 (2010)
244. Nikrooz, B, Zandrahimi, M, “Optimization of Process Variables and Corrosion Properties of a Multi-layer Silica Sol–Gel Coating on AZ91D Using the Box–Behnken Design.” J. Sol Gel Sci. Technol., 59 640–649 (2011)
245. Zomorodian, A, et al., “Anti-corrosion Performance of a New Silane Coating for Corrosion Protection of AZ31 Magnesium Alloy in Hank’s Solution.” Surf. Coat. Technol., 206 4368–4375 (2012)
246. Murillo-Gutiérrez, NV, Ansart, F, Bonino, J-P, Menu, M-J, Gressier, M, “Protection Against Corrosion of Magnesium Alloys with Both Conversion Layer and Sol–Gel Coating.” Surf. Coat. Technol., 232 606–615 (2013)
247. Brusciotti, F, et al., “Hybrid Epoxy–Silane Coatings for Improved Corrosion Protection of Mg Alloy.” Corros. Sci., 67 82–90 (2013)
248. Molnár, P, Ostapovets, A, Jäger, A, “Reversible Motion of Twin Boundaries in AZ31 Alloy and New Design of Magnesium Alloys as Smart Materials.” Mater. Des., 56 509–516 (2014)
249. 3 Particulates and Ca.” J. Alloys Compd., 574 565–572 (2013)
250. Li, ZM, et al., “Improved High Cycle Fatigue Properties of a New Magnesium Alloy.” Mater. Sci. Eng. A, 582 170–177 (2013)
251. Jiang, J, et al., “Microstructure and Mechanical Properties of AZ61 Magnesium Alloy Parts Achieved by Thixo-extruding Semisolid Billets Prepared by New SIMA.” Trans. Nonferrous Met. Soc. China, 23 576–585 (2013)
252. Pan, F, et al., “Key R&D Activities for Development of New Types of Wrought Magnesium Alloys in China.” Trans. Nonferrous Met. Soc. China, 20 1249–1258 (2010)
253. Alam, ME, Han, S, Nguyen, QB, Salem Hamouda, AM, Gupta, M, “Development of New Magnesium Based Alloys and Their Nanocomposites.” J. Alloys Compd., 509 8522–8529 (2011)
254. Chen, TJ, Wang, W, Zhang, DH, Ma, Y, Hao, Y, “Development of a New Magnesium Alloy ZW21.” Mater. Des., 44 555–565 (2013)
255. Sendova, M, Willis, K, “Spiral and Curved Periodic Crack Patterns in Sol–Gel Films.” Appl. Phys. Mater. Sci. Process., 76 957–959 (2003)
256. Latellaa, BA, Barbéa, CJ, Cassidya, DJ, Lia, H, Ignatb, M, “Mechanical Stability and Decohesion of Sol–Gel Hybrid Coatings on Metallic Substrates.” Rev. Matér., 10 199–204 (2005)
257. Castro, Y, Ferrari, B, Moreno, R, “Silica Sol–Gel Coatings on Metals Produced by EPD.” J. Sol Gel Sci. Technol., 26 735–739 (2003)
258. Arkles, B, “Commercial Application of Sol–Gel-Derived Hybrid Materials.” MRS Bull., 26 402–408 (2001)
259. Ghosh, SK. In: Ghosh, SK (ed.) Self-healing Materials, pp. 1–28. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008. http://onlinelibrary.wiley.com/doi/10.1002/9783527625376.ch1/summary
260. Trabelsi, W, Cecilio, P, Ferreira, MGS, Montemor, MF, “Electrochemical Assessment of the Self-healing Properties of Ce-Doped Silane Solutions for the Pre-treatment of Galvanised Steel Substrates.” Prog. Org. Coat., 54 276–284 (2005)
261. Shchukin, DG, Zheludkevich, M, Möhwald, H, “Feedback Active Coatings Based on Incorporated Nanocontainers.” J. Mater. Chem., 16 4561–4566 (2006)
262. Lamaka, SV, et al., “TiOx Self-assembled Networks Prepared by Templating Approach as Nanostructured Reservoirs for Self-healing Anticorrosion Pre-treatments.” Electrochem. Commun., 8 421–428 (2006)
263. Lamaka, SV, et al., “Nanoporous Titania Interlayer as Reservoir of Corrosion Inhibitors for Coatings with Self-healing Ability.” Prog. Org. Coat., 58 127–135 (2007)
264. Yabuki, A, Yamagami, H, Noishiki, K, “Barrier and Self-healing Abilities of Corrosion Protective Polymer Coatings and Metal Powders for Aluminum Alloys.” Mater. Corros., 58 497–501 (2007)
265. 2 Nanoparticles on the Electrochemical Behaviour of Galvanised Steel in NaCl Solutions.” Electrochim. Acta, 53 5913–5922 (2008)
266. 2 Nanoparticles.” Electrochim. Acta, 54 5179–5189 (2009)
267. Cho, SH, White, SR, Braun, PV, “Self-healing Polymer Coatings.” Adv. Mater., 21 645–649 (2009)
268. Zheludkevich, ML, et al., “Self-healing Protective Coatings with ‘Green’ Chitosan Based Pre-layer Reservoir of Corrosion Inhibitor.” J. Mater. Chem., 21 4805–4812 (2011)
269. García, SJ, et al., “Self-healing Anticorrosive Organic Coating Based on an Encapsulated Water Reactive Silyl Ester: Synthesis and Proof of Concept.” Prog. Org. Coat., 70 142–149 (2011)
270. Odom, SA, Esser-Kahn, AP, Sottos, NR, White, SR, Moore, JS, “Triggered Release from Polymer Capsules.” Macromolecules, 44 5539–5553 (2011)
271. Carneiro, J, et al., “Chitosan-Based Self-Healing Protective Coatings Doped with Cerium Nitrate for Corrosion Protection of Aluminum Alloy 2024.” Prog. Org. Coat., 75 8–13 (2012)
272. Zheludkevich, ML, Tedim, J, Ferreira, MGS, “‘Smart’ Coatings for Active Corrosion Protection Based on Multi-functional Micro and Nanocontainers.” Electrochim. Acta, 82 314–323 (2012)
273. Hughes, AE, Cole, IS, Muster, TH, Varley, RJ, “Designing Green, Self-healing Coatings for Metal Protection.” NPG Asia Mater., 2 143–151 (2010)
274. White, SR, et al., “Autonomic Healing of Polymer Composites.” Nature, 409 794–797 (2001)