A heteroleptic push-pull substituted iron(II) bis(tridentate) complex with low-energy charge-transfer states

Chemistry - A European Journal

Volumn 21, Issue 2, 2015, Pages 704-714

  Mengel, Andreas K C ^a   Förster, Christoph ^a   Breivogel, Aaron ^a   Mack, Katharina ^a   Ochsmann, Julian R ^b   Laquai, Frédéric ^b   Ksenofontov, Vadim ^a   Heinze, Katja ^a  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

Charge transfer; Excited states; Iron; Ligand field splitting; Tridentate ligands

Indexed keywords

CHARGE TRANSFER; ELECTRON SPIN RESONANCE SPECTROSCOPY; EXCITED STATES; GROUND STATE; IRON; LIGANDS; PYRIDINE; SPIN DYNAMICS;

CHARGE TRANSFER STATE; ELECTRON-DONATING; ELECTRON-WITHDRAWING LIGANDS; EPR SPECTROSCOPY; LIGAND FIELD SPLITTING; PUSH-PULL SUBSTITUTION; SPIN GROUND STATE; TRIDENTATE LIGANDS;

IRON COMPOUNDS;

EID: 84920172047     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201404955     Document Type: Article

References (65)

1. a) C. Balzani, S. Campagna, Top. Curr. Chem., Vol. 280: Photochemistry and Photophysics of Coordination Compounds I, Springer, Berlin, 2007;
2. b) C. Balzani, S. Campagna, Top. Curr. Chem., Vol. 281: Photochemistry and Photophysics of Coordination Compounds II, Springer, Berlin, 2007.
3. Y. Tanabe, S. Sugano, J. Phys. Soc. Jpn. 1954, 9, 766-779.
4. General SCO: a) P. Gütlich, H. A. Goodwin, Top. Curr. Chem., Vol. 233: Spin Crossover in Transition Metal Compounds I, Springer, Berlin, 2004;
5. b) P. Gütlich, H. A. Goodwin, Top. Curr. Chem., Vol. 234: Spin Crossover in Transition Metal Compounds II, Springer, Berlin, 2004;
6. c) P. Gütlich, H. A. Goodwin, Top. Curr. Chem., Vol. 235: Spin Crossover in Transition Metal Compounds III, Springer, Berlin, 2004;
7. d) O. Kahn, C. Jay Martinez, Science 1998, 279, 44-48;
8. e) P. Gütlich, Y. Garcia, T. Woike, Coord. Chem. Rev. 2001, 219-221, 839- 879;
9. f) J.-F. Létard, P. Guionneau, L. Goux-Capes, Top. Curr. Chem. 2004, 235, 221-249;
10. g) A. Bousseksou, G. Molnar, L. Salmon, W. Nicolazzi, Chem. Soc. Rev. 2011, 40, 3313-3335;
11. Special issue: Spin-Crossover Complexes, Eur. J. Inorg. Chem. 2013, 574-1067.
12. A. Marino, P. Chakraborty, M. Servol, M. Lorenc, E. Collet, A. Hauser, Angew. Chem. Int. Ed. 2014, 53, 3863 - 3867;
13. Angew. Chem. 2014, 126, 3944-3948.
14. S. Campagna, F. Puntoriero, F. Nastasi, G. Bergamini, V. Balzani, Top. Curr. Chem. 2007, 280, 117-214.
15. a) L. Hammarström, O. Johansson, Coord. Chem. Rev. 2010, 254, 2546-2559;
16. b) M. Abrahamsson, M. Jäger, T. Österman, L. Eriksson, P. Persson, H.-C. Becker, O. Johansson, L. Hammarström, J. Am. Chem. Soc. 2006, 128, 12616-12617;
17. c) M. Abrahamsson, M. Jäger, R. J. Kumar, T. Österman, P. Persson, H.-C. Becker, O. Johansson, L. Hammarström, J. Am. Chem. Soc. 2008, 130, 15533-15542;
18. d) R. J. Kumar, S. Karlsson, D. Streich, A. R. Jensen, M. Jäger, H.-C. Becker, J. Bergquist, O. Johansson, L. Hammarström, Chem. Eur. J. 2010, 16, 2830-2842.
19. F. Schramm, V. Meded, H. Fliegl, K. Fink, O. Fuhr, Z. Qu, W. Klopper, S. Finn, T. E. Keyes, M. Ruben, Inorg. Chem. 2009, 48, 5677-5684.
20. a) A. Breivogel, C. Förster, K. Heinze, Inorg. Chem. 2010, 49, 7052-7056;
21. b) A. Breivogel, M. Meister, C. Förster, F. Laquai, K. Heinze, Chem. Eur. J. 2013, 19, 13745-13760;
22. c) A. Breivogel, C. Kreitner, K. Heinze, Eur. J. Inorg. Chem. 2014, DOI: 10.1002/ejic.201402466.
23. A. Breivogel, S. Wooh, J. Dietrich, T. Y. Kim, Y. S. Kang, K. Char, K. Heinze, Eur. J. Inorg. Chem. 2014, 2720-2734.
24. A. Breivogel, M. Park, D. Lee, S. Klassen, A. Kühnle, C. Lee, K. Char, K. Heinze, Eur. J. Inorg. Chem. 2014, 288-295.
25. C. Sousa, C. de Graaf, A. Rudavskyi, R. Broer, J. Tatchen, M. Etinski, C. M. Marian, Chem. Eur. J. 2013, 19, 17541-17551.
26. W. Gawelda, A. Cannizzo, V.-T. Pham, F. van Mourik, C. Bressler, M. Chergui, J. Am. Chem. Soc. 2007, 129, 8199-8206.
27. Y. Liu, T. Harlang, S. E. Canton, P. Chábera, K. Suárez-Alcántara, A. Fleckhaus, D. A. Vithanage, E. Göransson, A. Corani, R. Lomoth, V. Sundström, K. Wärnmark, Chem. Commun. 2013, 49, 6412-6414.
28. I. M. Dixon, F. Alary, M. Boggio-Pasqua, J.-L. Heully, Inorg. Chem. 2013, 52, 13369-13374.
29. L. L. Jamula, A. M. Brown, D. Guo, J. K. McCusker, Inorg. Chem. 2014, 53, 15-17.
30. S. Ferrere, B. A. Gregg, J. Am. Chem. Soc. 1998, 120, 843-844.
31. W. Macyk, Gr. Stochel, K. Szaciłowski, Chem. Eur. J. 2007, 13, 5676-5687.
32. M. Yang, D. W. Thompson, G. J. Meyer, Inorg. Chem. 2002, 41, 1254-1262.
33. H. Li Chum, D. Koran, R. A. Osteryoung, J. Am. Chem. Soc. 1978, 100, 310-312.
34. R.-A. Fallahpour, M. Neuburger, M. Zehnder, New J. Chem. 1999, 23, 53-61.
35. I. M. Henderson, R. C. Hayward, J. Mater. Chem. 2012, 22, 21366-21369.
36. K. Mack, A. Wünsche von Leupoldt, C. Förster, M. Ezhevskaya, D. Hinderberger, K. W. Klinkhammer, K. Heinze, Inorg. Chem. 2012, 51, 7851-7858.
37. C. Förster, K. Mack, L. M. Carrella, V. Ksenofontov, E. Rentschler, K. Heinze, Polyhedron 2013, 52, 576-581.
38. C. R. Goldsmith, T. D. P. Stack, Inorg. Chem. 2006, 45, 6048-6055.
39. U. S. Schubert, H. Hofmeier, G. R. Newkome, Modern Terpyridine Chemistry, Wiley-VCH, Weinheim, 2006.
40. S. K. Hain, F. W. Heinemann, K. Gieb, P. Müller, G. Hörner, A. Grohmann, Eur. J. Inorg. Chem. 2010, 221-232.
41. W. Koch, M. C. Holthausen, A Chemist's Guide to Density Functional Theory, Wiley-VCH, Weinheim, 2001.
42. N. G. Connelly, W. E. Geiger, Chem. Rev. 1996, 96, 877-910.
43. R. Aasa, J. Chem. Phys. 1970, 52, 3919-3930.
44. R. E. DeSimone, R. S. Drago, J. Am. Chem. Soc. 1970, 92, 2343-2352.
45. L. Duelund, H. Toftlund, Spectrochim. Acta Part A 2000, 56, 331-340.
46. C. Olea-Azar, B. Abarca, E. Norambuena, L. Opazo, C. Rigol, R. Ballesteros, M. Chadlaoui, Spectrochim. Acta Part A 2005, 61, 2261-2266.
47. S. Schenker, P. C. Stein, J. A. Wolny, C. Brady, J. J. McGarvey, H. Toftlund, A. Hauser, Inorg. Chem. 2001, 40, 134-139.
48. J. K. McCusker, H. Toftlund, A. L. Rheingold, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 115, 1797-1804.
49. J. J. McGarvey, I. Lawthers, K. Heremans, H. Toftlund, J. Chem. Soc. Chem. Commun. 1984, 1575-1576.
50. J. J. McGravey, I. Lawthers, J. Chem. Soc. Chem. Commun. 1982, 906-907.
51. K. A. Reeder, E. V. Dose, L. J. Wilson, Inorg. Chem. 1978, 17, 1071-1075.
52. E. V. Dose, M. A. Hoselton, N. Sutin, M. F. Tweedle, L. J. Wilson, J. Am. Chem. Soc. 1978, 100, 1141-1147.
53. J. K. Beattie, R. A. Binstead, R. J. West, J. Am. Chem. Soc. 1978, 100, 3044-3050.
54. F. Neese, Coord. Chem. Rev. 2009, 253, 526-563.
55. S. Ye, F. Neese, Inorg. Chem. 2010, 49, 772-774.
56. C. R. Jacob, M. Reiher, Int. J. Quantum Chem. 2012, 112, 3661-3684.
57. K. P. Kepp, Coord. Chem. Rev. 2013, 257, 196-209.
58. Q. Sun, S. Mosquera-Vazquez, L. M. Lawson Daku, L. Gu-n-e, H. A. Goodwin, E. Vauthey, A. Hauser, J. Am. Chem. Soc. 2013, 135, 13660-13663.
59. S. Stoll, A. Schweiger, J. Magn. Reson. 2006, 178, 42-55.
60. K. Lagarec, D. G. Rancourt, Nucl. Instrum. Methods Phys. Res. Sect. B 1997, 129, 266-280.
61. SMART Data Collection and SAINT-Plus Data Processing Software for the SMART System, various versions, Bruker Analytical X-ray Instruments, Madison, WI, 2000.
62. R. H. Blessing, Acta Crystallogr. A 1995, 51, 33-38.
63. G. M. Sheldrick, SHELXTL, version 5.1, Bruker AXS, Madison, WI, 1998.
64. G. M. Sheldrick, SHELXL-97; University of Göttingen: Göttingen, Germany, 1997.
65. Gaussian 09, Revision A.02, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, Ö. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski, D. J. Fox, Gaussian, Inc., Wallingford CT, 2009.