Vectorial electron transfer in donor-photosensitizer-acceptor triads based on novel bis-tridentate ruthenium polypyridyl complexes

Chemistry - A European Journal

Volumn 16, Issue 9, 2010, Pages 2830-2842

  Kumar, Rohan J ^a   Karlsson, Susanne ^a   Streich, Daniel ^a   Jensen, Alice Rolandini ^a   Jäger, Michael ^a   Becker, Hans Christian ^a   Bergquist, Jonas ^a   Johansson, Olof ^a   Hammarström, Leif ^a  

^a UPPSALA UNIVERSITY   (Sweden)

Author keywords

Donor acceptor systems; Electron transfer; Photochemistry; Ruthenium; Tridentate ligands

Indexed keywords

CHARGE SEPARATIONS; COMPLEX 1; DONOR AND ACCEPTOR; DONOR MOIETY; DONOR-ACCEPTOR SYSTEM; ELECTRON TRANSFER; FAST ELECTRON TRANSFER; PHOTO-INDUCED CHARGE; PHOTO-INDUCED ELECTRON TRANSFER; RUTHENIUM POLYPYRIDYL COMPLEXES; SINGLE-ISOMER; TIME-RESOLVED ABSORPTION; TRIDENTATE LIGANDS; VECTORIAL ELECTRON TRANSFER;

ABSORPTION SPECTROSCOPY; ELECTRON TRANSITIONS; ENERGY HARVESTING; ISOMERS; LIGANDS; PHOTOSENSITIZERS; RUTHENIUM; SEPARATION; SOLAR ENERGY;

RUTHENIUM COMPOUNDS;

EID: 77149136051     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902716     Document Type: Article

References (58)

1. E. Schrödinger, What is Life? The Physical Aspects of the Living Cell, Cambridge University Press, New York, 1944.
2. J. Barber, B. Anderson, Nature 1994, 370, 31-34.
3. B. A. Diner, F. Rappaport, Annu. Rev. Plant Biol. 2002, 53, 551-580.
4. G. Renger in Comprehensive Series in Photochemistry and Photobiology, Vol. 8 (Eds.: D.-P. Häder, G. Jori), RSC, Cambridge, 2008.
5. J. H. Alstrum-Acevedo, M. K. Brennaman, T. J. Meyer, Inorg. Chem. 2005, 44, 6802-6827.
6. S. Campagna, F. Puntoriero, F. Nastasi, G. Bergamini, V. Balzani, Top. Curr. Chem. 2007, 280, 117-214.
7. J. P. Sauvage, J. P. Collin, J. C. Chambron, S. Guillerez, C. Coudret, V. Balzani, F. Barigelletti, L. De Cola, L. Flamigni, Chem. Rev. 1994, 94, 993-1019.
8. O. S. Wenger, Coord. Chem. Rev. 2009, 253, 1439-1457.
9. M. Falkenström, O. Johansson, L. Hammarström, Inorg. Chim. Acta 2007, 360, 741-750.
10. J.-M. Lehn, M. Kirch, J.-P. Sauvage, Helv. Chim. Acta 1979, 62, 1345-1384.
11. S. Campagna, C. Di Pietro, F. Loiseau, B. Maubert, N. McClenaghan, R. Passalacqua, F. Puntoriero, V. Ricevuto, S. Serroni, Coord. Chem. Rev. 2002, 229, 67-74.
12. F. R. Keene, Coord. Chem. Rev. 1997, 166, 121-159.
13. F. R. Keene, Chem. Soc. Rev. 1998, 27, 185-193.
14. K. A. Opperman, S. L. Mecklenburg, T. J. Meyer, Inorg. Chem. 1994, 33, 5295-5301.
15. M. Borgström, N. Shaikh, O. Johansson, M. F. Anderlund, S. Styring, B. Åkermark, A. Magnuson, L. Hammarström, J. Am. Chem. Soc. 2005, 127, 17504-17515.
16. J. A. Treadway, P. Chen, T. J. Rutherford, F. R. Keene, T. J. Meyer, J. Phys. Chem. A 1997, 101, 6824-6826.
17. T. J. Rutherford, F. R. Keene, Inorg. Chem. 1997, 36, 2872-2878.
18. J.-P. Collin, S. Guillerez, J.-P. Sauvage, F. Barigelletti, L. De Cola, L. Flamigni, V. Balzani, Inorg. Chem. 1991, 30, 4230-4238.
19. P. Lainé, F. Bedioui, E. Amouyal, V. Albin, F. Berruyer-Penaud, Chem. Eur. J. 2002, 8, 3162-3176.
20. O. Johansson, M. Borgström, R. Lomoth, M. Palmblad, J. Bergquist, L. Hammarström, L. Sun, B. Åkermark, Inorg. Chem. 2003, 42, 2908-2918.
21. J. M. Calvert, J. V. Caspar, R. A. Binstead, T. D. Westmoreland, T. J. Meyer, J. Am. Chem. Soc. 1982, 104, 6620-6627.
22. B. J. Coe, D. A. Friesen, D. W. Thompson, T. J. Meyer, Inorg. Chem. 1996, 35, 4575-4584.
23. M. Abrahamsson, M. Jäger, T. Österman, L. Eriksson, P. Persson, H.-C. Becker, O. Johansson, L. Hammarström, J. Am. Chem. Soc. 2006, 128, 12616-12617.
24. M. Abrahamsson, M. Jäger, R. J. Kumar, T. Österman, P. Persson, H.-C. Becker, O. Johansson, L. Hammarström, J. Am. Chem. Soc. 2008, 130, 15533-15542.
25. M. Jäger, L. Eriksson, J. Bergquist, O. Johansson, J. Org. Chem. 2007, 72, 10227-10230.
26. M. Jäger, R. J. Kumar, H. Görls, J. Bergquist, O. Johansson, Inorg. Chem. 2009, 48, 3228-3238.
27. D. Gust, T. A. Moore, A. L. Moore, in Electron Transfer in Chemistry, Vol. 3 (Ed.: V. Balzani), Wiley-VCH, Weinheim, 2001, pp. 272-336.
28. M. R. Wasielewski, Chem. Rev. 1992, 92, 435-461.
29. A. C. Benniston, G. M. Chapman, A. Harriman, S. A. Roston, Inorg. Chem. 2005, 44, 4029-4036.
30. M. Borgström, O. Johansson, R. Lomoth, H. B. Baudin, S. Wallin, L. Sun, B. Åkermark, L. Hammarström, Inorg. Chem. 2003, 42, 5173-5184.
31. R. A. Berthon, S. B. Colbran, G. M. Moran, Inorg. Chim. Acta 1993, 204, 3-7.
32. K. S. Schanze, K. Sauer, J. Am. Chem. Soc. 1988, 110, 1180-1186.
33. V. Goulle, A. Harriman, J.-M. Lehn, J. Chem. Soc. Chem. Commun. 1993, 1034-1036.
34. E. A. Alemán, C. D. Shreiner, C. S. Rajesh, T. Smith, S. A. Garrison, D. A. Modarelli, Dalton Trans. 2009, 6562-6577.
35. B. I. Greene, R. M. Hochstrasser, R. B. Weisman, J. Chem. Phys. 1979, 70, 1247-1259.
36. E. Laviron, J. Electroanal. Chem. 1986, 208, 357-372.
37. P. Wardman, J. Phys. Chem. Ref. Data 1989, 18, 1637-1657.
38. J. A. Schmidt, A. Siemiarczuk, A. C. Weedon, J. R. Bolton, J. Am. Chem. Soc. 1985, 107, 6112-6114.
39. J. A. Schmidt, A. R. McIntosh, A. C. Weedon, J. R. Bolton, J. S. Connolly, J. K. Hurley, M. R. Wasielewski, J. Am. Chem. Soc. 1988, 110, 1733-1740.
40. The amount of excited state subtracted from the product spectrum (at 5 ns) was scaled by the amplitude (DO.D.) at 427 and 430 nm for 1a and 3a, respectively. The reference dyads 2a and 4a show isosbestic points at these wavelengths, and thus the only contribution to the spectrum at these wavelengths should be that of the product state. The percentage of subtracted excited-state spectrum is 5% in 1a and 40% in 3a, in good agreement with the fraction of hydroquinone found in steady-state emission quantum yield measurements and NMR data.
41. S. A. Alkaitis, G. Beck, M. Grätzel, J. Am. Chem. Soc. 1975, 97, 5723-5729.
42. J. R. Darwent, K. Kalyanasundaram, J. Chem. Soc. Faraday Trans. 2 1981, 77, 373-382.
43. P. S. Rao, E. Hayon, J. Phys. Chem. 1973, 77, 2274-2276.
44. K. B. Patel, R. L. Willson, J. Chem. Soc. Faraday Trans. 1 1973, 69, 814-825.
45. +/0)], respectively. The Coulombic work term is assumed to be negligible.
46. +/0)].
47. E. Danielson, C. M. Elliott, J. W. Merkert, T. J. Meyer, J. Am. Chem. Soc. 1987, 109, 2519-2520.
48. D. R. Striplin, S. Y. Reece, D. G. McCafferty, C. G. Wall, D. A. Friesen, B. W. Erickson, T. J. Meyer, J. Am. Chem. Soc. 2004, 126, 5282-5291.
49. J. M. Weber, M. T. Rawls, V. J. MacKenzie, B. R. Limoges, C. M. Elliott, J. Am. Chem. Soc. 2007, 129, 313-320.
50. K. A. Maxwell, M. Sykora, J. M. DeSimone, T. J. Meyer, Inorg. Chem. 2000, 39, 71-75.
51. S. L. Mecklenburg, D. G. McCafferty, J. R. Schoonover, B. M. Peek, B. W. Erickson, T. J. Meyer, Inorg. Chem. 1994, 33, 2974-2983.
52. L. F. Cooley, S. L. Larson, C. M. Elliott, D. F. Kelley, J. Phys. Chem. 1991, 95, 10694-10700.
53. E. Baranoff, J.-P. Collin, L. Flamigni, J.-P. Sauvage, Chem. Soc. Rev. 2004, 33, 147-155.
54. -1 (from A. Yoshimura, M. Z. Hoffman, H. Sun, J. Photochem. Photobiol. A 1993, 70, 29-33).
55. G. E. Adams, B. D. Michael, J. Chem. Soc. Faraday Trans. 1967, 1171-1180.
56. The non-active hydroquinone fraction of 5% in 1a and 40% in 3a has been taken into account when evaluating the maximum groundstate bleach.
57. J. Elhaik, C. M. Pask, C. A. Kilner, M. A. Halcrow, Tetrahedron 2006, 62, 291-298.
58. S. Karlsson, J. Modin, H.-C. Becker, L. Hammarström, H. Grennberg, Inorg. Chem. 2008, 47, 7286-7294.