Highly enantioselective, intermolecular hydroamination of allenyl esters catalyzed by bifunctional phosphinothioureas

Journal of the American Chemical Society

Volumn 136, Issue 52, 2014, Pages 17966-17968

  Fang, Yuan Qing ^a   Tadross, Pamela M ^a   Jacobsen, Eric N ^a  

^a HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINATION; AMINO ACIDS; CATALYSIS; CHEMICAL COMPOUNDS; ENANTIOSELECTIVITY; ESTERS; SUBSTRATES;

AMINO ACID ESTERS; BI-FUNCTIONAL; CONJUGATE ADDITION; ENANTIOSELECTIVE; HIGH ENANTIOSELECTIVITY; HYDROAMINATIONS; PHOSPHONIUM IONS; PROPARGYL ESTERS;

ESTERIFICATION;

ALLENE DERIVATIVE; AMINO ACID; CARBAMIC ACID DERIVATIVE; ESTER; NUCLEOPHILE; PHOSPHINOTHIOUREA DERIVATIVE; THIOUREA; THIOUREA DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE; ALKENE;

AMINATION; ARTICLE; CATALYST; ENANTIOSELECTIVITY; HYDROGEN BOND; ISOMERIZATION; PROTON TRANSPORT; STEREOCHEMISTRY; CATALYSIS; CHEMISTRY; ENZYME SPECIFICITY; STEREOISOMERISM;

ALKENES; AMINATION; CATALYSIS; ESTERS; STEREOISOMERISM; SUBSTRATE SPECIFICITY; THIOUREA;

EID: 84920149246     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5117638     Document Type: Article

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