Model-free rate expression for thermal decomposition processes: The case of microcrystalline cellulose pyrolysis

Fuel

Volumn 143, Issue , 2015, Pages 438-447

  Samuelsson, Lina N ^a   Moriana, Rosana ^a   Babler, Matthaus U ^a   Ek, Monica ^a   Engvall, Klas ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

Cellulose; Isoconversional; Kinetics; Model free; Pyrolysis; Thermogravimetric analysis

Indexed keywords

ACTIVATION ENERGY; CELLULOSE; CRYSTALLINE MATERIALS; ENZYME KINETICS; HEATING RATE; ISOTHERMS; KINETICS; PYROLYSIS; REACTION KINETICS;

APPARENT ACTIVATION ENERGY; DESIGN AND OPTIMIZATION; ISO-CONVERSIONAL METHOD; ISOCONVERSIONAL; MICRO-CRYSTALLINE CELLULOSE; MODEL FREE; PYROLYTIC DECOMPOSITION; THERMAL DECOMPOSITION PROCESS;

THERMOGRAVIMETRIC ANALYSIS;

EID: 84918767293     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2014.11.079     Document Type: Article

References (37)

1. C. Şerbənescu Kinetic analysis of cellulose pyrolysis: a short review Chem Pap 68 2014 847 860
2. S. Vyazovkin, A.K. Burnham, J.M. Criado, L.A. Pérez-Maqueda, C. Popescu, and N. Sbirrazzuoli ICTAC kinetics committee recommendations for performing kinetic computations on thermal analysis data Thermochim Acta 520 2011 1 19
3. J. Lédé Cellulose pyrolysis kinetics: an historical review on the existence and role of intermediate active cellulose J Anal Appl Pyrol 94 2012 17 32
4. C.D. Blasi Modeling chemical and physical processes of wood and biomass pyrolysis Prog Energy Combust Sci 34 2008 47 90
5. T. Fisher, M. Hajaligol, B. Waymack, and D. Kellogg Pyrolysis behavior and kinetics of biomass derived materials J Anal Appl Pyrol 62 2002 331 349
6. M. Grønli, M.J. Antal, and G. Várhegyi A round-robin study of cellulose pyrolysis kinetics by thermogravimetry Ind Eng Chem Res 38 1999 2238 2244
7. Y.C. Lin, J. Cho, G.A. Tompsett, P.R. Westmoreland, and G.W. Huber Kinetics and mechanism of cellulose pyrolysis J Phys Chem C 113 2009 20097 20107
8. S.M. Shaik, C. Koh, P.N. Sharratt, and R.B. Tan Influence of acids and alkalis on transglycosylation and beta-elimination pathway kinetics during cellulose pyrolysis Thermochim Acta 566 2013 19
9. M.J. Antal, G. Várhegyi, and E. Jakab Cellulose pyrolysis kinetics: revisited Ind Eng Chem Res 37 1998 1267 1275
10. J.A. Conesa, J. Caballero, A. Marcilla, and R. Font Analysis of different kinetic models in the dynamic pyrolysis of cellulose Thermochim Acta 254 1995 175 192
11. J.G. Reynolds, and A.K. Burnham Pyrolysis decomposition kinetics of cellulose-based materials by constant heating rate micropyrolysis Energy Fuels 11 1997 88 97
12. S. Völker, and T. Rieckmann Thermokinetic investigation of cellulose pyrolysis-impact of initial and final mass on kinetic results J Anal Appl Pyrol 62 2002 165 177
13. R. Capart, L. Khezami, and A.K. Burnham Assessment of various kinetic models for the pyrolysis of a microgranular cellulose Thermochim Acta 417 2004 79 89
14. V. Mamleev, S. Bourbigot, and J. Yvon Kinetic analysis of the thermal decomposition of cellulose: the main step of mass loss J Anal Appl Pyrol 80 2007 151 165
15. P.E. Sánchez-Jiménez, L.A. Pérez-Maqueda, A. Perejón, and J.M. Criado Generalized master plots as a straightforward approach for determining the kinetic model: the case of cellulose pyrolysis Thermochim Acta 552 2013 54 59
16. J.L. Banyasz, S. Li, J.L. Lyons-Hart, and K.H. Shafer Cellulose pyrolysis: the kinetics of hydroxyacetaldehyde evolution J Anal Appl Pyrol 57 2001 223 248
17. I. Milosavljevic, and E.M. Suuberg Cellulose thermal decomposition kinetics: global mass loss kinetics Ind Eng Chem Res 34 1995 1081 1091
18. V. Mamleev, S. Bourbigot, M.L. Bras, J. Yvon, and J. Lefebvre Model-free method for evaluation of activation energies in modulated thermogravimetry and analysis of cellulose decomposition Chem Eng Sci 61 2006 1276 1292
19. L. Cabrales, and N. Abidi On the thermal degradation of cellulose in cotton fibers J Therm Anal Calorim 102 2010 485 491
20. R. Moriana, F. Vilaplana, S. Karlsson, and A. Ribes Correlation of chemical, structural and thermal properties of natural fibres for their sustainable exploitation Carbohydr Polym 112 2014 422 431
21. H.L. Friedman Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic J Polym Sci Pol Sym 6 1964 183 195
22. S. Vyazovkin Modification of the integral isoconversional method to account for variation in the activation energy J Comput Chem 22 2001 178 183
23. A.K. Burnham, and L.N. Dinh A comparison of isoconversional and model-fitting approaches to kinetic parameter estimation and application predictions J Therm Anal Calorim 89 2007 479 490
24. J. Cai, and Y. Chen Iterative linear integral isoconversional method: theory and application Bioresour Technol 103 2012 309 312
25. P. Šimon, P.S. Thomas, J. Okuliar, and A.S. Ray An incremental integral isoconversional method J Therm Anal Calorim 72 2003 867 874
26. P. Budrugeac An iterative model-free method to determine the activation energy of non-isothermal heterogeneous processes Thermochim Acta 511 2010 8 16
27. F.J. Gotor, J.M. Criado, J. Malek, and N. Koga Kinetic analysis of solid-state reactions: the universality of master plots for analyzing isothermal and nonisothermal experiments J Phys Chem A 104 2000 10777 10782
28. P. Šimon Considerations on the single-step kinetics approximation J Therm Anal Calorim 82 2005 651 657
29. S. Vyazovkin, and C.A. Wight Estimating realistic confidence intervals for the activation energy determined from thermoanalytical measurements Anal Chem 72 2000 3171 3175
30. J.R. Taylor An introduction to error analysis 2 ed. 1997 University Science Books Sausalito California
31. D. Montgomery, and G. Runger Applied statistics and probability for engineers 5 ed. 2010 John Wiley & Sons
32. T.E. Oliphant Python for scientific computing Comput Sci Eng 9 2007 10 20
33. E.M. Suuberg, I. Milosavljevic, and V. Oja Two-regime global kinetics of cellulose pyrolysis: the role of tar evaporation Symp (Int) Combust 26 1996 1515 1521
34. G. Várhegyi, E. Jakab, and M.J. Antal Jr. Is the Broido-Shafizadeh model for cellulose pyrolysis true? Energy Fuels 8 1994 1345 1352
35. J. Opfermann, E. Kaisersberger, and H. Flammersheim Model-free analysis of thermoanalytical data-advantages and limitations Thermochim Acta 391 2002 119 127
36. M. Miranda, C. Bica, S. Nachtigall, N. Rehman, and S. Rosa Kinetical thermal degradation study of maize straw and soybean hull celluloses by simultaneous DSc-tga and mdsc techniques Thermochim Acta 565 2013 65 71
37. S. Matsuoka, H. Kawamoto, and S. Saka What is active cellulose in pyrolysis? An approach based on reactivity of cellulose reducing end J Anal Appl Pyrol 106 2014 138 146