Cellulose Pyrolysis Kinetics: Revisited

Industrial and Engineering Chemistry Research

Volumn 37, Issue 4, 1998, Pages 1267-1275

  Antal Jr , Michael Jerry ^a   Várhegyi, Gábor ^b   Jakab, Emma ^b  

^a University of Hawaii at Manoa   (United States)

^b INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; MEASUREMENT ERRORS; PYROLYSIS; REACTION KINETICS; TEMPERATURE MEASUREMENT; THERMOGRAVIMETRIC ANALYSIS;

THERMAL LAG;

CELLULOSE;

EID: 0032048503     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie970144v     Document Type: Article

References (40)

1. Antal, M. J. Thermogravimetric Signatures of Complex Solid- Phase Pyrolysis Mechanisms and Kinetics. In Thermal Analysis; Miller, B., Ed.; J. Wiley Heyden Ltd.: Chichester, U.K., 1982.
2. Anted, M. J. Effects of Reactor Severity on the Gas-Phase Pyrolysis of Cellulose- and Kraft Lignin-Derived Volatile Matter. Ind. Eng. Chem. Prod. Res. Dev. 1983, 22, 366-375.
3. Antal, M. J. Biomass Pyrolysis: A Review of the Literature. Part II. Lignocellulose Pyrolysis. In Advances in Solar Energy; Boer, K. W., Duffie, J. A., Eds.; American Solar Energy Society: Boulder, CO, 1985.
4. Antal, M. J.; Várhegyi, G. Cellulose Pyrolysis Kinetics: The Current State of Knowledge. Ind. Eng. Chem. Res. 1995, 34, 703-717.
5. Antal, M. J.; Várhegyi, G. Impact of Systematic Errors on the Determination of Cellulose Pyrolysis Kinetics. Energy Fuels 1997, 11, 1309-1310.
6. Antal, M. J.; Friedman, H. L.; Rogers, F. E. Kinetics of Cellulose Pyrolysis in Nitrogen and Steam. Combust. Sci. Technol. 1980, 21, 141-152.
7. Antal, M. J.; Mok, W.; Roy, J. C.; Tabatabaie-Raissi, A.; Anderson, D. G. M. A. Pyrolytic Sources of Hydrocarbons from Biomass. J. Anal. Appl. Pyrolysis 1985, 8, 291-303.
8. Arseneau, D. F. Competitive Reactions in the Thermal Decomposition of Cellulose. Can. J. Chem. 1971, 49, 632-638.
9. Bradbury, A. G. W.; Sakai, Y.; Shafizadeh, F. A Kinetic Model for Pyrolysis of Cellulose. J. Appl. Polym. Sci. 1979, 23, 3271-3280.
10. Broido, A. Kinetics of Solid-Phase Cellulose Pyrolysis. In Thermal Uses and Properties of Carbohydraes and Lignins; Shafizadeh, F., Sarkanen, K. V., Tillman, D. A., Eds.; Academic Press: New York, 1976; pp 19-35.
11. Chornet, E.; Roy, C. Compensation Effect in the Thermal Decomposition of Cellulosic Materials. Thermochim. Acta 1980, 35, 389-393.
12. Cooley, S.; Antal, M. J. Kinetics of Cellulose Pyrolysis in the Presence of Nitric Oxide. J. Anal. Appl. Pyrolysis 1988, 14, 149-161.
13. Cozzani, V.; Nicolella, C.; Rovatti, M.; Tognotti, L. Modeling and Experimental Verification of Physical and Chemical Processes during Pyrolysis of a Refuse-Derived Fuel. Ind. Eng. Chem. Res. 1996, 35, 90-98.
14. Di Blasi, C. Kinetic and Heat Transfer Control in the Slow and Flash Pyrolysis of Solids. Ind. Eng. Chem. Res. 1996a, 35, 37-46.
15. Di Blasi, C. Heat, Momentum and Mass Transport Through a Shrinking Biomass Particle Exposed to Thermal Radiation. Chem. Eng. Sci. 1996b, 51, 1121-1132.
16. Di Blasi, C. Influences of Model Assumptions on the Predictions of Cellulose Pyrolysis in the Heat Transfer Controlled Regime. Fuel 1996c, 75, 58-66.
17. Di Blasi, C. Heat Transfer Mechanisms and Multi-Step Kinetics in the Ablative Pyrolysis of Cellulose. Chem. Eng. Sci. 1996d, 57, 2211-2220.
18. Di Blasi, C.; Lanzetta, M. Intrinsic Kinetics of Isothermal Xylan Degradation in Inert Atmosphere. J. Anal. Appl. Pyrolysis 1997, 40-41, 287-303.
19. Drummond, A.-R. F.; Drummond, I. W. Pyrolysis of Sugar Cane Bagasse in a Wire-Mesh Reactor. Ind. Eng. Chem. Res. 1996, 35, 1263-1268.
20. 2. J. Anal. Appl. Pyrolysis 1991, 21, 249-264.
21. Friedman, H. L. Kinetics of Thermal Degradation of Char-forming Plastics from Thermogravimetry. J. Polym. Sci. 1964, C6, 183-195.
22. Gaur, S.; Reed, T. B. Prediction of Cellulose Decomposition Rates from Thermogravimetric Data. Biomass Bioenergy 1994, 7, 61-67.
23. Grønli, M. A Theoretical and Experimental Study of the Thermal Degradation of Biomass. Ph.D. Thesis, The Norwegian University of Science and Technology, Trondheim, Norway, 1996.
24. Julien, S.; Chornet, E.; Tiwari, P. K.; Overend, R. P. Vacuum Pyrolysis of Cellulose: Fourier Transform Infrared Characterization of Solid Residues, Product Distribution and Correlations. J. Anal. Appl. Pyrolysis 1991, 19, 81-104.
25. Lanzetta, M.; Di Blasi, C.; Buonanno, F. An Experimental Investigation of Heat Transfer Limitations in the Flash Pyrolysis of Cellulose. Ind. Eng. Chem. Res. 1997, 36, 542-552.
26. Milosavljevic, I.; Suuberg, E. M. Cellulose Thermal Decomposition Kinetics: Global Mass Loss Kinetics. Ind. Eng. Chem. Res. 1995, 34, 1081-1091.
27. Milosavljevic, I.; Oja, V.; Suuberg, E. M. Thermal Effects in Cellulose Pyrolysis: Relationship to Char Formation Processes. Ind. Eng. Chem. Res. 1996, 35, 653-662.
28. Mok, W. S. L.; Antal, M. J. Effects of Pressure on Biomass Pyrolysis. II. Heats of Reaction of Cellulose Pyrolysis. Thermochim. Acta 1983, 68, 165-186.
29. Mok, W. S. L.; Antal, M. J.; Szabó, P.; Várhegyi, G.; Zelei, B. Formation of Charcoal from Biomass in a Sealed Reactor. Ind. Eng. Chem. Res. 1992, 31, 1162-1166.
30. Myers, R. H. Classical and Modern Regression with Applications; PWS-KENT Publishing Co.: Boston, 1990.
31. Narayan, R.; Antal, M. J. Thermal Lag, Fusion, and the Compensation Effect during Biomass Pyrolysis. Ind. Eng. Chem. Res. 1996, 35, 1711-1721.
32. Pastorova, I.; Arisz, P. W.; Boon, J. J. Preservation of D-glucose- oligosaccharides in Cellulose Chars. Carbohydr. Res. 1993, 248, 151-165.
33. Shafizadeh, F. Pyrolytic Reactions and Products of Biomass. In Fundamentals of Thermochemical Biomass Conversion; Overend, R. P., Milne, T. A., Mudge, L. K., Eds.; Elsevier: London, 1985; pp 183-218.
34. th Symposium (Int.) on Combustion; The Combustion Institute: Pittsburgh, 1996; pp 1515-1521.
35. Tabatabaie-Raissi, A.; Mok, W.; Antal, M. J. Cellulose Pyrolysis Kinetics in a Simulated Solar Environment. Ind. Eng. Chem. Res. 1989, 28, 856-865.
36. Várhegyi, G.; Antal, M. J.; Székely, T.; Till, F.; Jakab, E. Simultaneous Thermogravimetric-Mass Spectrometric Studies of the Thermal Decomposition of Biopolymers. 1. Avicel Cellulose in the Presence and Absence of Catalysts. Energy Fuels 1988, 2, 267-272.
37. Várhegyi, G.; Antal, M. J.; Székely, T.; Szabó, P. Kinetics of the Thermal Decomposition of Cellulose, Hemicellulose, and Sugar Cane Bagasse. Energy Fuels 1989, 3, 329-335.
38. Várhegyi, G,; Jakab, E.; Antal, M. J. Is the Broido-Shafizadeh Model for Cellulose Pyrolysis True? Energy Fuels 1994, 8, 1345-1352.
39. 2 Mixtures. Energy Fuels 1996, 10, 1208-1214.
40. Williams, P. T.; Besler, S. Thermogravimetric Analysis of the Components of Biomass. In Advances in Thermochemical Biomass Conversion; Bridgwater, A. V., Ed.; Blackie Academic & Professional: London, 1994; pp 771-783.