Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis

Thermochimica Acta

Volumn 552, Issue , 2013, Pages 54-59

  Sánchez Jiménez, Pedro E ^a   Pérez Maqueda, Luis A ^a   Perejón, Antonio ^a   Criado, José M ^a  

^a INSTITUTO DE CIENCIA DE MATERIALES DE SEVILLA   (Spain)

Author keywords

Cellulose; Kinetics; Master plots; Pyrolysis; Random scission; Thermal degradation

Indexed keywords

COMPLEX REACTIONS; CONSTANT RATE THERMAL ANALYSIS; EXPERIMENTAL CURVES; KINETIC MODELS; LINEAR HEATING RATES; MASTER PLOTS; RANDOM SCISSION; THERMAL DECOMPOSITION KINETICS;

CELLULOSE; ENZYME KINETICS; KINETIC THEORY; PYROLYSIS; THERMOANALYSIS;

KINETICS;

EID: 84870660817     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2012.11.003     Document Type: Article

References (36)

1. A. Khawam, and D.R. Flanagan Solid-state kinetic models: basics and mathematical fundamentals J. Phys. Chem. B 110 2006 17315 17328
2. F.J. Gotor, J.M. Criado, J. Malek, and N. Koga Kinetic analysis of solid-state reactions: the universality of master plots for analyzing isothermal and nonisothermal experiments J. Phys. Chem. A 104 2000 10777 10782
3. P.E. Sanchez-Jimenez, L.A. Perez-Maqueda, A. Perejon, and J.M. Criado Generalized kinetic master plots for the thermal degradation of polymers following a random scission mechanism J. Phys. Chem. A 114 2010 7868 7876
4. J.M. Criado, L.A. Perez-Maqueda, F.J. Gotor, J. Malek, and N. Koga A unified theory for the kinetic analysis of solid state reactions under any thermal pathway J. Therm. Anal. Calorim. 72 2003 901 906
5. J. Malek Kinetic analysis of crystallization processes in amorphous materials Thermochim. Acta 355 2000 239 253
6. J.M. Criado, P.E. Sanchez-Jimenez, and L.A. Perez-Maqueda Critical study of the isoconversional methods of kinetic analysis J. Therm. Anal. Calorim. 92 2008 199 203
7. P. Simon Isoconversional methods-fundamentals, meaning and application J. Therm. Anal. Calorim. 76 2004 123 132
8. S. Vyazovkin, and N. Sbirrazzuoli Isoconversional kinetic analysis of thermally stimulated processes in polymers Macromol. Rapid Commun. 27 2006 1515 1532
9. S. Volker, and T. Rieckmann Thermokinetic investigation of cellulose pyrolysis-impact of initial and final mass on kinetic results J. Anal. Appl. Pyrolysis 62 2002 165 177
10. V. Mamleev, S. Bourbigot, M. Le Bras, J. Yvon, and J. Lefebvre Model-free method for evaluation of activation energies in modulated thermogravimetry and analysis of cellulose decomposition Chem. Eng. Sci. 61 2006 1276 1292
11. R. Capart, L. Khezami, and A.K. Burnham Assessment of various kinetic models for the pyrolysis of a microgranular cellulose Thermochim. Acta 417 2004 79 89
12. D.K. Shen, and S. Gu The mechanism for thermal decomposition of cellulose and its main products Bioresour. Technol. 100 2009 6496 6504
13. V. Mamleev, S. Bourbigot, and J. Yvon Kinetic analysis of the thermal decomposition of cellulose: the change of the rate limitation J. Anal. Appl. Pyrolysis 80 2007 141 150
14. V. Mamleev, S. Bourbigot, and J. Yvon Kinetic analysis of the thermal decomposition of cellulose: the main step of mass loss J. Anal. Appl. Pyrolysis 80 2007 151 165
15. Y.C. Lin, J. Cho, G.A. Tompsett, P.R. Westmoreland, and G.W. Huber Kinetics and mechanism of cellulose pyrolysis J. Phys. Chem. C 113 2009 20097 20107
16. Y. Eom, S. Kim, S.S. Kim, and S.H. Chung Application of peak property method for estimating apparent kinetic parameters of cellulose pyrolysis reaction J. Ind. Eng. Chem. 12 2006 846 852
17. P. Kaushal, and J. Abedi A simplified model for biomass pyrolysis in a fluidized bed reactor J. Ind. Eng. Chem. 16 2010 748 755
18. A.G.W. Bradbury, Y. Sakai, and F. Shafizadeh Kinetic model for pyrolysis of cellulose J. Appl. Polym. Sci. 23 1979 3271 3280
19. R.K. Agrawal Kinetics of reactions involved in pyrolysis of cellulose.1. The 3-reaction model Can. J. Chem. Eng. 66 1988 403 412
20. R.K. Agrawal Kinetics of reactions involved in pyrolysis of cellulose.2. The modified Kilzer-Broido model Can. J. Chem. Eng. 66 1988 413 418
21. G. Varhegyi, E. Jakab, and M.J. Antal Is the Broido-Shafizadeh model for cellulose true? Energy Fuels 8 1994 1345 1352
22. M.J. Antal, G. Varhegyi, and E. Jakab Cellulose pyrolysis kinetics: revisited Ind. Eng. Chem. Res. 37 1998 1267 1275
23. A. Barneto, J. Carmona, J.E. Alfonso, and L. Alcaide Use of autocatalytic kinetics to obtain composition of lignocellulosic materials Bioresour. Technol. 100 2009 3963 3973
24. D. Dollimor, and B. Holt Thermal degradation of cellulose in nitrogen J. Polym. Sci. Part B-Polym. Phys. 11 1973 1703 1711
25. J.G. Reynolds, and A.K. Burnham Pyrolysis decomposition kinetics of cellulose-based materials by constant heating rate micropyrolysis Energy Fuels 11 1997 88 97
26. P.E. Sanchez-Jimenez, L.A. Perez-Maqueda, A. Perejon, J. Pascual-Cosp, M. Benitez-Guerrero, and J.M. Criado An improved model for the kinetic description of the thermal degradation of cellulose Cellulose 18 2011 1487 1498
27. N. Koga, and J.M. Criado The influence of mass transfer phenomena on the kinetic analysis for the thermal decomposition of calcium carbonate by constant rate thermal analysis (CRTA) under vacuum Int. J. Chem. Kinet. 30 1998 737 744
28. J. Rouquerol A general introduction to SCTA and to rate-controlled SCTA J. Therm. Anal. Calorim. 72 2003 1081 1086
29. L.A. PerezMaqueda, A. Ortega, and J.M. Criado The use of master plots for discriminating the kinetic model of solid state reactions from a single constant-rate thermal analysis (CRTA) experiment Thermochim. Acta 277 1996 165 173
30. T. Ozawa Nonisothermal kinetics and the generalized time Thermochim. Acta 100 1986 109 118
31. P.E. Sanchez-Jimenez, L.A. Perez-Maqueda, A. Perejon, and J.M. Criado A new model for the kinetic analysis of thermal degradation of polymers driven by random scission Polym. Degrad. Stab. 95 2010 733 739
32. R. Simha, and L.A. Wall Kinetics of chain depolymerization J. Phys. Chem. 56 1952 707 715
33. P.E. Sánchez-Jiménez, L.A. Pérez-Maqueda, A. Perejón, and J.M. Criado Constant rate thermal analysis fot thermal stability studies of polymers Polym. Degrad. Stab. 96 2011 974 981
34. L.A. Perez-Maqueda, J.M. Criado, and F.J. Gotor Controlled rate thermal analysis commanded by mass spectrometry for studying the kinetics of thermal decomposition of very stable solids Int. J. Chem. Kinet. 34 2002 184 192
35. V. Mamleev, S. Bourbigot, M. Le Bras, and J. Yvon The facts and hypotheses relating to the phenomenological model of cellulose pyrolysis interdependence of the steps J. Anal. Appl. Pyrolysis 84 2009 1 17
36. N. Koga, and J.M. Criado Kinetic analyses of solid-state reactions with a particle-size distribution J. Am. Ceram. Soc. 81 1998 2901 2909