Iterative linear integral isoconversional method: Theory and application

Bioresource Technology

Volumn 103, Issue 1, 2012, Pages 309-312

  Cai, Junmeng ^a   Chen, Yong ^a  

^a SHANGHAI JIAO TONG UNIVERSITY   (China)

Author keywords

Combustion kinetics; Isoconversional methods; Pyrolysis char; Thermogravimetric analysis

Indexed keywords

COMBUSTION KINETICS; EXPERIMENTAL DATA; FAST PYROLYSIS; FREQUENCY FACTORS; ISO-CONVERSIONAL METHOD; REACTION MODEL;

ACTIVATION ENERGY; COMBUSTION; KINETICS; PYROLYSIS; THERMOGRAVIMETRIC ANALYSIS;

DATA HANDLING;

CHARCOAL;

ACTIVATION ENERGY; COMBUSTION; PYROLYSIS; REACTION KINETICS; THERMOGRAVIMETRY;

ARTICLE; BIOMASS CONVERSION; BIOMASS ENERGY; COMBUSTION; PRIORITY JOURNAL; PYROLYSIS; REACTION TIME;

BIOTECHNOLOGY; COMPUTER SIMULATION; HOT TEMPERATURE; KINETICS; LINEAR MODELS; MODELS, THEORETICAL;

EID: 82955195666     PISSN: 09608524     EISSN: 18732976     Source Type: Journal    
DOI: 10.1016/j.biortech.2011.10.008     Document Type: Article

References (19)

1. Barbadillo F., Fuentes A., Naya S., Cao R., Mier J.L., Artiaga R. Evaluating the logistic mixture model on real and simulated TG curves. J. Therm. Anal. Calorim. 2007, 87:223-227.
2. Barneto A.G., Carmona J.A., Alfonso J.E.M., Serrano R.S. Simulation of the thermogravimetry analysis of three non-wood pulps. Bioresour. Technol. 2011, 101(9):3220-3229.
3. Budrugeac P. An iterative model-free method to determine the activation energy of non-isothermal heterogeneous processes. Thermochim. Acta 2010, 511:8-16.
4. Burnham A.K., Dinh L.N. A comparison of isoconversional and model-fitting approaches to kinetic parameter estimation and application predictions. J. Therm. Anal. Calorim. 2007, 89(2):479-490.
5. Cai J., Chen S. A new iterative linear integral isoconversional method for the determination of the activation energy varying with the conversion degree. J. Comput. Chem. 2009, 30:1986-1991.
6. Cai J., Liu R. Weibull mixture model for modeling nonisothermal kinetics of thermally stimulated solid-state reactions: application to simulated and real kinetic conversion data. J. Phys. Chem. B 2007, 111:10681-10686.
7. Cheng G., Zhang L., He P., Yan F., Xiao B., Xu T., Jiang C., Zhang Y., Guo D. Pyrolysis of ramie residue: kinetic study and fuel gas produced in a cyclone furnace. Bioresour. Technol. 2011, 102(3):3451-3456.
8. Criado J.M., Sánchez-Jiménez P.E., Pérez-Maqueda L.A. Critical study of the isoconversional methods of kinetic analysis. J. Therm. Anal. Calorim. 2008, 92(1):199-203.
9. Otero M., Sánchez M.E., Gómez X. Co-firing of coal and manure biomass: a TG-MS approach. Bioresour. Technol. 2011, 102(17):8304-8309.
10. Sbirrazzuoli N. Is the Friedman method applicable to transformations with temperature dependent reaction heat?. Macromol. Chem. Phys. 2007, 208:1592-1597.
11. Sbirrazzuoli N., Vincent L., Mija A., Guigo N. Integral, differential and advanced isoconversional methods: complex mechanisms and isothermal predicted conversion-time curves. Chemom. Intell. Lab. Syst. 2009, 96:219-226.
12. Segal E., Budrugeac P. Is there any convergence between the differential and integral procedures used in chemical kinetics, particularly in nonisothermal kinetics?. Int. J. Chem. Kinet. 2006, 38:339-344.
13. Simon P. Isoconversional methods: fundamentals, meaning and application. J. Therm. Anal. Calorim. 2004, 76:123-132.
14. Tiwari, P., Deo, M., 2011. Detailed kinetic analysis of oil shale pyrolysis TGA data. AIChE J. doi:10.1002/aic.12589.
15. Vyazovkin S. A unified approach to kinetic processing of nonisothermal data. Int. J. Chem. Kinet. 1996, 28:95-101.
16. Vyazovkin S. On the phenomenon of variable activation energy for condensed phase reactions. New J. Chem. 2000, 24:913-917.
17. Vyazovkin S. Modification of the integral isoconversional method to account for variation in the activation energy. J. Comput. Chem. 2001, 22:178-183.
18. Vyazovkin S. Model-free kinetics: staying free of multiplying entities without necessity. J. Therm. Anal. Calorim. 2006, 83(1):45-51.
19. Vyazovkin S., Vincent L., Sbirrazzuoli N. Thermal denaturation of collagen analyzed by isoconversional method. Macromol. Biosci. 2007, 7:1181-1186.