Mechanistic insight into the photoredox catalysis of anti-markovnikov alkene hydrofunctionalization reactions

Journal of the American Chemical Society

Volumn 136, Issue 49, 2014, Pages 17024-17035

  Romero, Nathan A ^a   Nicewicz, David A ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; ATOMS; COVALENT BONDS; FREE RADICAL REACTIONS; HYDROCARBONS;

ACTIVATION BARRIERS; ADDUCT FORMATION; DIPHENYL DISULFIDE; HYDROGEN ATOM TRANSFERS (HAT); MECHANISTIC ASPECTS; PHOTOREDOX CATALYSIS; STRUCTURAL REORGANIZATION; TRANSITION STRUCTURES;

CATALYST ACTIVITY;

2 PHENYLMALONONITRILE; ALKENE; DIPHENYL DISULFIDE; DISULFIDE; HYDROGEN; MALONONITRILE; THIOPHENOL; UNCLASSIFIED DRUG; 9-MESITYL-10-METHYLACRIDINIUM; ACRIDINE DERIVATIVE; ALKANE; PHENOL DERIVATIVE; THIOL DERIVATIVE;

ADDUCTION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; DISULFIDE BOND; OXIDATION REDUCTION REACTION; PHOTOLYSIS; PROTON TRANSPORT; RADICAL REACTION; STRUCTURE ANALYSIS; CHEMISTRY; KINETICS; PHOTOCHEMISTRY; QUANTUM THEORY; SYNTHESIS;

ACRIDINES; ALKANES; ALKENES; CATALYSIS; DISULFIDES; KINETICS; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PHENOLS; PHOTOCHEMICAL PROCESSES; QUANTUM THEORY; SULFHYDRYL COMPOUNDS;

EID: 84918585727     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja506228u     Document Type: Article

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