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Volumn 119, Issue 43, 1997, Pages 10325-10334

Calibration of intramolecular radical cation probes based on arylalkene cycloadditions

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; CYCLOBUTANE DERIVATIVE; CYCLOHEXENE DERIVATIVE; RADICAL;

EID: 0030714093     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971307+     Document Type: Article
Times cited : (29)

References (58)
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    • The lifetime of the 500-nm transient showed some variation from one experiment to the next, most likely as a result of varying water content in the acetonitrile. On the basis of measured rate constant for reaction with water, even 0.02% water is sufficient to change the observed rate constant for decay by ∼50%, and it is difficult with our experimental setup for flow experiments to adequately control the water content below this level. There is also some indication that the lifetime decreases slightly with increasing concentration of 1.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.