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16944363996
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The lifetime of the 500-nm transient showed some variation from one experiment to the next, most likely as a result of varying water content in the acetonitrile. On the basis of measured rate constant for reaction with water, even 0.02% water is sufficient to change the observed rate constant for decay by ∼50%, and it is difficult with our experimental setup for flow experiments to adequately control the water content below this level. There is also some indication that the lifetime decreases slightly with increasing concentration of 1.
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