Cyclopentanethiolato-protected Au36(SC5H9)24 nanocluster: Crystal structure and implications for the steric and electronic effects of ligand

Journal of Physical Chemistry A

Volumn 118, Issue 37, 2014, Pages 8264-8269

  Das, Anindita ^a   Liu, Chong ^b   Zeng, Chenjie ^a   Li, Gao ^a   Li, Tao ^b   Rosi, Nathaniel L ^b   Jin, Rongchao ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; AROMATIZATION; LIGANDS; NANOCLUSTERS;

AROMATIC LIGANDS; CLUSTER SIZES; CONJUGATION EFFECTS; ELECTRONIC EFFECTS; FACE-CENTERED CUBIC; PROTECTED GOLD NANOCLUSTERS; TETRAHEDRAL STRUCTURES;

CRYSTAL STRUCTURE;

EID: 84917683522     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp501073a     Document Type: Article

References (60)

1. Jena, P.; Castleman, A. W. Clusters: A Bridge across the Disciplines of Physics and Chemistry Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 10560-10569
2. Jin, R. Quantum-Sized, Thiolate-Protected Gold Nanoclusters Nanoscale 2010, 2, 343-362
3. Qian, H.; Zhu, M.; Wu, Z.; Jin, R. Quantum Sized Gold Nanoclusters with Atomic Precision Acc. Chem. Res. 2012, 45, 1470
4. 4 Motif J. Am. Chem. Soc. 2013, 135, 18264-18267
5. Nishigaki, J.; Tsunoyama, R.; Tsunoyama, H.; Ichikuni, N.; Yamazoe, S.; Negishi, Y.; Ito, M.; Matsuo, T.; Tamao, K.; Tsukuda, T. A New Binding Motif of Sterically Demanding Thiolates on a Gold Cluster J. Am. Chem. Soc. 2012, 134, 14295-14297
6. 18 Molecules J. Phys. Chem. C 2013, 117, 22094-22097
7. 25 Nanoclusters via pH Controlled CO Reduction Chem. Mater. 2013, 25, 946-952
8. 15 in Cyclodextrins Chem. Mater. 2011, 23, 989-999
9. Zeng, C.; Li, T.; Das, A.; Rosi, N. L.; Jin, R. Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography J. Am. Chem. Soc. 2013, 135, 10011-10013
10. Niihori, Y.; Matsuzaki, M.; Pradeep, T.; Negishi, Y. Separation of Precise Compositions of Noble Metal Clusters Protected with Mixed Ligands J. Am. Chem. Soc. 2013, 135, 4946-4949
11. 40 Clusters: A Combined Circular Dichroism and Mass Spectrometry Study J. Am. Chem. Soc. 2010, 132, 16783-16789
12. 25 Clusters J. Phys. Chem. C 2013, 117, 23155-23161
13. 18 Small 2012, 8, 2028-2035
14. 144 Clusters by Electron Cryomicroscopy J. Phys. Chem. C 2010, 114, 16037-16042
15. Li, G.; Jin, R. Atomically Precise Gold Nanoclusters as New Model Catalysts Acc. Chem. Res. 2013, 46, 1749-1758
16. Yamazoe, S.; Koyasu, K.; Tsukuda, T. Nonscalable Oxidation Catalysis of Gold Clusters Acc. Chem. Res. 2014, 10.1021/ar400209a
17. Li, G.; Jiang, D.-e.; Liu, C.; Yu, C.; Jin, R. Oxide-supported atomically precise gold nanocluster for catalyzing Sonogashira cross-coupling J. Catal. 2013, 306, 177-183
18. de Heer, W. A. The Physics of Simple Metal Clusters: Experimental Aspects and Simple Models Rev. Mod. Phys. 1993, 65, 611-676
19. Martin, T. P. Shells of Atoms Phys. Rep. 1996, 273, 199-241
20. Castleman, A. W.; Khanna, S. N. Clusters, Superatoms, and Building Blocks of New Materials J. Phys. Chem. C 2009, 113, 2664-2675
21. Wyrwas, R. B.; Alvarez, M. M.; Khoury, J. T.; Price, R. C.; Schaaff, T. G.; Whetten, R. L. The colours of nanometric gold-Optical response functions of selected gold-cluster thiolates Eur. Phys. J. D. 2007, 43, 91-95
22. Lin, Z.; Kanters, R. P. F.; Mingos, D. M. P. Closed-shell electronic requirements for condensed clusters of the group 11 elements Inorg. Chem. 1991, 30, 91-95
23. 25 J. Am. Chem. Soc. 2008, 130, 3756-3757
24. Qian, H.; Zhu, Y.; Jin, R. Atomically Precise Gold Nanocrystal Molecules with Surface Plasmon Resonance Proc. Natl. Acad. Sci. U.S.A. 2012, 109, 696
25. 25 Superatoms J. Am. Chem. Soc. 2009, 131, 2490-2492
26. q Core-Shell Clusters Inorg. Chem. 2009, 48, 2720-2722
27. 20: Implication to Structural Evolution of Thiolated Gold Clusters from Homoleptic Gold(I) Thiolates to Core-Stacked Nanoparticles J. Am. Chem. Soc. 2012, 134, 3015-3024
28. Aikens, C. M. Electronic Structure of Ligand-Passivated Gold and Silver Nanoclusters J. Phys. Chem. Lett. 2011, 2, 99-104
29. 18 J. Am. Chem. Soc. 2007, 129, 11322-11323
30. 14 cluster Phys. Chem. Chem. Phys. 2012, 14, 3737-3740
31. Han, Y.-K.; Jung, J. Does the "Superatom" Exist in Halogenated Aluminum Clusters? J. Am. Chem. Soc. 2008, 130, 2-3
32. Reimers, J. R.; Wang, Y.; Cankurtaran, B. O.; Ford, M. J. Chemical Analysis of the Superatom Model for Sulfur-Stabilized Gold Nanoparticles J. Am. Chem. Soc. 2010, 132, 8378-8384
33. Leuchtner, R. E.; Harms, A. C.; Castleman, A. W. Thermal Metal Cluster Anion Reactions: Behavior of Aluminum Clusters with Oxygen J. Chem. Phys. 1989, 91, 2753-2754
34. - Cluster to Charge Neutral Cluster via Air Oxidation J. Phys. Chem. C 2008, 112, 14221-14224
35. 25 Cluster and Optical Properties J. Am. Chem. Soc. 2008, 130, 5883-5885
36. 18] J. Am. Chem. Soc. 2008, 130, 3754-3755
37. 38 Nanoparticles J. Am. Chem. Soc. 2010, 132, 8280-8281
38. 24 Angew. Chem., Int. Ed. 2012, 51, 13114-13118
39. 24 Nanocluster with FCC-Like Core J. Phys. Chem. Lett. 2013, 4, 3186-3191
40. Schmid, G. The relevance of shape and size of Au55 clusters Chem. Soc. Rev. 2008, 37, 1909-1930
41. 12 Cage Inorg. Chem. 2005, 44, 9604-9606
42. Teo, B. K. Cluster of clusters: a new series of high nuclearity gold-silver clusters Polyhedron 1988, 2317-2320
43. Hall, K. P.; Mingos, D. M. P. Homo- and heteronuclear cluster compounds of gold Prog. Inorg. Chem. 1984, 32, 237-325
44. 13 Clusters Small 2010, 6, 1216-1220
45. 20 Nanocluster Protected by Hemilabile Phosphines J. Am. Chem. Soc. 2012, 134, 14750-14752
46. Chen, J.; Zhang, Q.-F.; Bonaccorso, T. A.; Williard, P. G.; Wang, L.-S. Controlling Gold Nanoclusters by Diphospine Ligands J. Am. Chem. Soc. 2014, 136, 92-95
47. x (x = 2, 4, 8) Bimetallic Nanoclusters: Ligand Engineering to Control the Exposure of Metal Sites J. Am. Chem. Soc. 2013, 135, 9568-9571
48. 2+ (n = 2-18): A Stepping Stone to Cluster-Assembled Materials J. Phys. Chem. C 2007, 111, 7845-7847
49. 25 Nanoclusters Inorg. Chem. 2011, 50, 10735-10739
50. Iwasa, T.; Nobusada, K.; Nakajima, A. Electronic and Optical Properties of Vertex-Sharing Homo- and Hetero-Biicosahedral Gold Clusters J. Phys. Chem. C 2013, 117, 24586-24591
51. 24 Nanocluster J. Am. Chem. Soc. 2012, 134, 20286-20289
52. 24 ACS Nano 2013, 7, 6138-6145
53. 44 Nanoscale 2012, 4, 4206-4210
54. 3) J. Phys. Chem. Lett. 2010, 1, 2594-2599
55. 25 Clusters Against Core Etching Small 2007, 3, 835-839
56. 25 Nanoclusters J. Mater. Chem. 2009, 19, 622-626
57. 38 Clusters J. Phys. Chem. A 2009, 113, 4281-4284
58. 38 clusters RSC Adv. 2012, 2, 2276-2283
59. Schaaff, T. G.; Whetten, R. L. Giant Gold-Glutathione Cluster Compounds: Intense Optical Activity in Metal-Based Transitions J. Phys. Chem. B 2000, 104, 2630-2641
60. 23 Nanomolecules J. Am. Chem. Soc. 2011, 133, 9175-9177