Atomically precise gold nanoclusters as new model catalysts

Accounts of Chemical Research

Volumn 46, Issue 8, 2013, Pages 1749-1758

  Li, Gao ^a   Jin, Rongchao ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84882658098     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar300213z     Document Type: Article

References (50)

1. Thomas, J. M.; Thomas, W. J. Principles and Practices of Heterogeneous Catalysis; Wiley: New York, 1996.
2. Bond, G. C.; Louis, C.; Thompson, D. T. Catalysis by Gold; Imperial College Press: London, 2006.
3. 3 Catalyst Appl. Catal., A 2000, 201, 71-80
4. Ertl, G. Reactions at Surfaces: From Atoms to Complexity (Nobel Lecture) Angew. Chem., Int. Ed. 2008, 47, 3524-3535
5. Somorjai, G. A.; Park, J. Y. Concepts, Instruments, And Model Systems That Enabled the Rapid Evolution of Surface Science Surf. Sci. 2009, 603, 1293-1300
6. Han, P.; Axnanda, S.; Lyubinetsky, I.; Goodman, D. W. Atomic-Scale Assembly of a Heterogeneous Catalytic Site J. Am. Chem. Soc. 2007, 129, 14355-14361
7. Heiz, U.; Landman, U., Eds. Nanocatalysis; Springer: New York, 2007.
8. 2(110) for the CO Oxidation Reaction J. Am. Chem. Soc. 2010, 132, 13097-13099
9. Gates, B. C. Supported Metal Clusters: Synthesis, Structure, and Catalysis Chem. Rev. 1995, 95, 511-522
10. Kulkarni, A.; Lobo-Lapidus, R. J.; Gates, B. C. Metal Clusters on Supports: Synthesis, Structure, Reactivity, and Catalytic Properties Chem. Commun. 2010, 46, 5997-6015
11. Jin, R. The Impacts of Nanotechnology on Catalysis by Precious Metal Nanoparticles Nanotechnol. Rev. 2012, 1, 31-56
12. Li, Y.; Liu, Q.; Shen, W. Morphology-Dependent Nanocatalysis: Metal Particles Dalton Trans. 2011, 40, 5811-5826
13. Chen, J. Y.; Lim, B.; Lee, E. P.; Xia, Y. N. Shape-Controlled Synthesis of Platinum Nanocrystals for Catalytic and Electrocatalytic Applications Nano Today 2009, 4, 81-95
14. -3 Torr) to Liquid Interfaces Phys. Chem. Chem. Phys. 2007, 9, 3500-3513
15. Qian, H.; Zhu, M.; Wu, Z.; Jin, R. Quantum Sized Gold Nanoclusters with Atomic Precision Acc. Chem. Res. 2012, 45, 1470-1479
16. 25 Cluster and Optical Properties J. Am. Chem. Soc. 2008, 130, 5883-5885
17. Tsukuda, T. Toward an Atomic-Level Understanding of Size-Specific Properties of Protected and Stabilized Gold Clusters Bull. Chem. Soc. Jpn. 2012, 85, 151-168
18. 25 Clusters J. Am. Chem. Soc. 2008, 130, 1138-1139
19. 25 Nanoclusters J. Mater. Chem. 2009, 19, 622-626
20. Jin, R.; Qian, H.; Wu, Z.; Zhu, Y.; Zhu, M.; Mohanty, A.; Garg, N. Size Focusing: A Methodology for Synthesizing Atomically Precise Gold Nanoclusters J. Phys. Chem. Lett. 2010, 1, 2903-2910
21. Qian, H.; Zhu, Y.; Jin, R. Atomically Precise Gold Nanocrystal Molecules with Surface Plasmon Resonance Proc. Natl. Acad. Sci. U.S.A. 2012, 109, 696-700
22. 18 Clusters by NMR and Mass Spectrometry J. Am. Chem. Soc. 2009, 131, 6535-6542
23. 11 Clusters J. Am. Chem. Soc. 2005, 127, 13464-13465
24. 38 Nanoparticles J. Am. Chem. Soc. 2010, 132, 8280-8281
25. m Nanoclusters Chem.-Eur. J. 2010, 16, 11455-11462
26. Min, B. K.; Friend, C. M. Heterogeneous Gold-Based Catalysis for Green Chemistry: Low-Temperature CO Oxidation and Propene Oxidation Chem. Rev. 2007, 107, 2709-2724
27. - Cluster to Charge Neutral Cluster via Air Oxidation J. Phys. Chem. C 2008, 112, 14221-14224
28. 4 J. Catal. 1993, 144, 175-192
29. 18 Nanoclusters and Identification of Perimeter Sites as Active Centers ACS Nano 2012, 6, 6014-6022
30. Haruta, M. Spiers Memorial Lecture: Role of Perimeter Interfaces in Catalysis by Gold Nanoparticles Faraday Discuss. 2011, 152, 11-32
31. n Nanoclusters as Catalysts for Selective Oxidation and Hydrogenation Processes Adv. Mater. 2010, 22, 1915-1920
32. 25 Clusters on Hydroxyapatite Chem. Commun. 2010, 46, 550-552
33. Jiang, D.-e.; Tiago, M. L.; Luo, W.; Dai, S. The "Staple" Motif: A Key to Stability of Thiolate-Protected Gold Nanoclusters J. Am. Chem. Soc. 2008, 130, 2777-2779
34. Liu, Y.; Tsunoyama, H.; Akita, T.; Xie, S.; Tsukuda, T. Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled Au Clusters on Hydroxyapatite: Size Effect in the Sub-2 nm Regime ACS Catal. 2011, 1, 2-6
35. 25 clusters by single Pd atom doping ACS Catal. 2012, 2, 1519-1523
36. 18 Nanoparticles As Catalysts for the Selective Hydrogenation of Alpha,Beta-Unsaturated Ketones and Aldehydes Angew. Chem., Int. Ed. 2010, 49, 1295-1298
37. Yamamoto, H.; Yano, H.; Kouchi, H.; Obora, Y.; Arakawa, R.; Kawasaki, H. N, N -Dimethylformamide-Stabilized Gold Nanoclusters as a Catalyst for the Reduction of 4-Nitrophenol Nanoscale 2012, 4, 4148-4154
38. 25 Clusters for the Reduction of 4-Nitrophenol Chem. Commun. 2013, 49, 276-278
39. 2 Electrodes Adv. Mater. 2010, 22, 3185-3188
40. 2 under Visible and near Infrared Light Electrochem. Commun. 2010, 12, 996-999
41. 2 Nanoscale 2012, 4, 4217-4221
42. 2 Nanoparticle Photocatalysts Modified with Monolayer-Protected Gold Clusters J. Phys. Chem. C 2010, 114, 18366-18371
43. Chen, W.; Chen, S. Oxygen Electroreduction Catalyzed by Gold Nanoclusters: Strong Core Size Effects Angew. Chem., Int. Ed. 2010, 48, 4386-4389
44. 25 Nanoparticles and Their pH Dependent Electrocatalytic Activity Electroanalysis 2011, 23, 2116-2124
45. 2: A Unique Interaction and Enhanced Electrocatalytic Activity J. Am. Chem. Soc. 2012, 134, 10237-10243
46. 20 Nanoclusters: Superatoms or Not? J. Phys. Chem. Lett. 2010, 1, 1003-1007
47. 25 Nanoparticle Catalyst for Hydrogenation of Cyclic Ketone J. Catal. 2010, 271, 155-160
48. 18 Nanoclusters from EXAFS: The Interplay of Metallic and Molecular Behavior J. Phys. Chem. C 2011, 115, 15282-15287
49. Lopez-Acevedo, O.; Kacprzak, K. A.; Akola, J.; Hakkinen, H. Quantum Size Effects in Ambient CO Oxidation Catalysed by Ligand-Protected Gold Clusters Nat. Chem. 2010, 2, 329-334
50. 6 in Selective Oxidation ACS Nano 2010, 4, 2009-2020