From superatomic Au 25(SR) 18- to superatomic M@Au 24(SR) 18 q core-shell clusters

Inorganic Chemistry

Volumn 48, Issue 7, 2009, Pages 2720-2722

  Jiang, De En ^a,b   Dai, Sheng ^a,b,c  

^a OAK RIDGE NATIONAL LABORATORY   (United States)

^b Chemical Sciences Division   (United States)

^c Center for Nanophase Materials Science   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 64349083369     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic8024588     Document Type: Article

References (39)

1. (a) Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Science 2007, 318, 430.
2. (b) Whetten, R. L.; Price, R. C. Science 2007, 318, 407.
3. (a) Heaven, M. W.; Dass, A.; White, P. S.; Holt, K. M; Murray, R. W. J. Am. Chem. Soc. 2008, 130, 3754.
4. (b) Zhu, M; Aikens, C. M: Hollander, F. J.; Schatz, G. C; Jin, R. J. Am. Chem. Soc. 2008, 130. 5883.
5. Walter, M.; Akola, J.; Lopez-Acevedo, O.; Jadzinsky, P. D.; Calero, G; Ackerson, C. J.; Whetten, R. L.; Gönbeck, H.; Häkkinen, H. Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 9157.
6. de Heer, W. A. Rev. Mod. Phys. 1993, 65, 611.
7. Kiran, B.; Jena, P.; Li, X.; Grubisic, A.; Stokes, S. T.; Gantefor, G. F.; Bowen, K. H.; Burgert, R.; Schnöckel, H. Phys. Rev. Lett. 2007, 98. 256802.
8. Akola, J.; Walter, M.; Whetten, R. L.; Häkkinen, H.; Grönbeck, H. J. Am. Chem. Soc. 2008, 130, 3756.
9. Ball, P. New Sci. 2005, 186, 30.
10. (a) Bergeron, D. E.; Roach, P. J.; Castleman, A. W.; Jones, N.; Khanna. S. N. Science 2005, 307, 231.
11. (b) Reveles, J. U.; Khanna, S. N.; Roach. P. J.; Castleman, A. W. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 18405.
12. Daniel, M. C; Astruc, D. Chem. Rev. 2004, 104, 293.
13. (a) Pyykkö, P.; Runeberg, N. Angew. Chem, Int. Ed. 2002, 41, 2174.
14. (b) Li, X.; Kiran, B.; Li, J.; Zhai, H. J.; Wang, L. S. Angew. Chem., Int. Ed. 2002, 41, 4786.
15. (c) Gao, Y.; Bulusu, S.; Zeng, X. C. ChemPhysChem 2006, 7, 2275.
16. (d) Wang, L. M.; Bulusu, S.; Zhai. H. J.; Zeng, X. C; Wang, L. S. Angew. Chem., Int. Ed. 2007, 46. 2915.
17. (e) Sun, Q.; Wang, Q.; Jena, P.; Kawazoe, Y. ACS Nano 2008. 2, 341.
18. h).
19. Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry: Prentice-Hall: Englewood Cliffs, NJ, 1990.
20. We did not pursue early transition metals and rare-earth elements for the center atom out of concern for their low-lying unoccupied d states interfering with the superatomic electron-shell levels.
21. The Turbomole V5.10 quantum chemistry program package was used. See the Supporting Information for computational details.
22. (a) Jiang, D. E.; Tiago, M. L.; Luo, W. D.; Dai, S. J. Am. Chem. Soc. 2008, 130, 2777.
23. (b) Pei, Y.; Gao, Y.; Zeng, X. C. J. Am. Chem. Soc. 2008, 130, 7830.
24. (c) Jiang, D. E.; Luo, W.; Tiago, M. L.; Dai, S. J. Phys. Chem. C 2008, 112, 13905.
25. (d) Gao, Y.; Shao, N.; Zeng, X. C. ACS Nano 2008, 2, 1497.
26. (e) Li, Y.; Galli, G.; Gygi, F. ACS Nano 2008, 2, 1896.
27. (a) Mingos, D. M. P.; Watson, M. J. Transition Met. Chem. 1991, 16. 285.
28. (b) Pignolet, L. H.; Aubart, M. A.; Craighead, K. L.; Gould, R. A. T.; Krogstad, D. A.; Wiley, J. S. Coord. Chem. Rev. 1995, 143, 219.
29. (c) Krogstad, D. A.; Konze, W. V.; Pignolet, L. H. Inorg. Chem. 1996, 35, 6763.
30. Shichibu, Y.; Negishi, Y.; Tsukuda, T.; Teranishi, T. J. Am. Chem. Soc. 2005, 127, 13464.
31. Kittel, C. Introduction to Solid State Physics, 7th ed.; Wiley: New York, 1997.
32. q structure and not relaxed.
33. Massalski, T. B. Binary Alloy Phase Diagrams, 2nd ed.; American Society for Metals: Metals Park, OH, 1990; Vol. 1.
34. (a) Lee, D.; Donkers, R. L.; Wang, G. L.; Harper, A. S.; Murray. R. W. J. Am Chem. Soc. 2004, 126, 6193.
35. (b) Guo, R.; Murray, R. W. J. Am. Chem. Soc. 2005, 127, 12140.
36. (c) Wang, G. L.; Huang, T.; Murray, R. W.; Menard, L.; Nuzzo, R. G. J. Am. Chem. Soc. 2005. 127, 812.
37. (d) Wang, G. L.; Guo, R.; Kalyuzhny, G.; Choi, J. P.: Murray, R. W. J. Phys. Chem. B 2006, 110, 20282.
38. (e) Negishi, Y.: Chaki, N. K.; Shichibu, Y.; Whetten, R. L.; Tsukuda, T. J. Am. Chem. Soc. 2007, 129, 11322.
39. (f) Parker, J. F.; Choi, J. P.; Wang, W.; Murray. R. W. J. Phys. Chem. C 2008, 112, 13976.