Green gold: Au30(S- t -C4H9)18 molecules

Journal of Physical Chemistry C

Volumn 117, Issue 42, 2013, Pages 22094-22097

  Crasto, David ^a   Dass, Amala ^a  

^a UNIVERSITY OF MISSISSIPPI   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; ELECTROSPRAY IONIZATION; ENERGY GAP; GOLD; LIGANDS; MASS SPECTROMETRY; METAL NANOPARTICLES; MOLECULES; NEAR INFRARED SPECTROSCOPY; OPTICAL PROPERTIES;

BUTYL LIGANDS; DIRECT SYNTHESIS; ELECTRONIC TRANSITION; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; GREEN REGIONS; HIGH RESOLUTION; ONE-POT REACTION; UV-VIS-NIR SPECTROSCOPY;

SYNTHESIS (CHEMICAL);

EID: 84886666325     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp407341y     Document Type: Article

References (32)

1. Tolman, C. A. Steric Effects of Phosphorus Ligands in Organometallic Chemistry and Homogeneous Catalysis Chem. Rev. 1977, 77, 313-348
2. Mingos, D. M. P. Steric Effects in Metal Cluster Compounds Inorg. Chem. 1982, 21, 464-466
3. Chen, S.; Murray, R. W. Arenethiolate Monolayer-Protected Gold Clusters Langmuir 1999, 15, 682-689
4. Templeton, A. C.; Chen, S.; Gross, S. M.; Murray, R. W. Water-Soluble, Isolable Gold Clusters Protected by Tiopronin and Coenzyme A Monolayers Langmuir 1998, 15, 66-76
5. Dameron, A. A.; Charles, L. F.; Weiss, P. S. Structures and Displacement of 1-Adamantanethiol Self-Assembled Monolayers on Au{111} J. Am. Chem. Soc. 2005, 127, 8697-8704
6. Krommenhoek, P. J.; Wang, J.; Hentz, N.; Johnston-Peck, A. C.; Kozek, K. A.; Kalyuzhny, G.; Tracy, J. B. Bulky Adamantanethiolate and Cyclohexanethiolate Ligands Favor Smaller Gold Nanoparticles with Altered Discrete Sizes ACS Nano 2012, 6, 4903-4911
7. Nishigaki, J.-I.; Tsunoyama, R.; Tsunoyama, H.; Ichikuni, N.; Yamazoe, S.; Negishi, Y.; Ito, M.; Matsuo, T.; Tamao, K.; Tsukuda, T. A New Binding Motif of Sterically Demanding Thiolates on a Gold Cluster J. Am. Chem. Soc. 2012, 134, 14295-14297
8. 23 Nanomolecules J. Am. Chem. Soc. 2011, 133, 9175-9177
9. Price, R. C.; Whetten, R. L. All-Aromatic, Nanometer-Scale, Gold-Cluster Thiolate Complexes J. Am. Chem. Soc. 2005, 127, 13750-13751
10. Chen, S. W.; Murray, R. W. Arenethiolate Monolayer-Protected Gold Clusters Langmuir 1999, 15, 682-689
11. Price, R. C. Nanocrystalline Gold Arylthiolate Molecules. Ph.D. Dissertation, Georgia Institute of Technology, 2006.
12. Yao, H.; Miki, K.; Nishida, N.; Sasaki, A.; Kimura, K. Large Optical Activity of Gold Nanocluster Enantiomers Induced by a Pair of Optically Active Penicillamines J. Am. Chem. Soc. 2005, 127, 15536-15543
13. 24 and Larger Clusters Anal. Chem. 2011, 83, 5056-5061
14. 18 Nanoclusters ACS Nano 2010, 4, 4691-4700
15. 34 Molecular Gold Nanoclusters with 34-Electron Shell Closing J. Am. Chem. Soc. 2009, 131, 11666-11667
16. x J. Am. Chem. Soc. 2008, 130, 5940-5946
17. Gronbeck, H.; Walter, M.; Hakkinen, H. Theoretical Characterization of Cyclic Thiolated Gold Clusters J. Am. Chem. Soc. 2006, 128, 10268-10275
18. x J. Am. Chem. Soc. 2008, 130, 5940-5946
19. Schaaff, T. G.; Shafigullin, M. N.; Khoury, J. T.; Vezmar, I.; Whetten, R. L.; Cullen, W. G.; First, P. N.; Gutierrez-Wing, C.; Ascensio, J.; Jose-Yacaman, M. J. Isolation of Smaller Nanocrystal Au Molecules: Robust Quantum Effects in Optical Spectra J. Phys. Chem. B 1997, 101, 7885-7891
20. Alvarez, M. M.; Khoury, J. T.; Schaaff, T. G.; Shafigullin, M. N.; Vezmar, I.; Whetten, R. L. Optical Absorption Spectra of Nanocrystal Gold Molecules J. Phys. Chem. B 1997, 101, 3706-3712
21. 18 Nanoparticles (M = Au, Ag) J. Phys. Chem. C 2008, 112, 19797-19800
22. Gutierrez, E.; Powell, R. D.; Furuya, F. R.; Hainfeld, J. F.; Schaaff, T. G.; Shafigullin, M. N.; Stephens, P. W.; Whetten, R. L.; Greengold, A. Giant Cluster Compound of Unusual Electronic Structure Eur. Phys. J. D 1999, 9, 647-651
23. Hakkinen, H. The Gold-Sulfur Interface at the Nanoscale Nat. Chem. 2012, 4, 443-455
24. Wang, L.-M.; Wang, L.-S. Probing the Electronic Properties and Structural Evolution of Anionic Gold Clusters in the Gas Phase Nanoscale 2012, 4, 4038-4053
25. Aikens, C. M. Electronic Structure of Ligand-Passivated Gold and Silver Nanoclusters J. Phys. Chem. Lett. 2010, 2, 99-104
26. Walter, M.; Akola, J.; Lopez-Acevedo, O.; Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Whetten, R. L.; Gronbeck, H.; Hakkinen, H. A Unified View of Ligand-Protected Gold Clusters as Superatom Complexes Proc. Natl. Acad. Sci. 2008, 105, 9157-9162
27. 18 Nanoclusters J. Am. Chem. Soc. 2012, 134, 16937-16940
28. 25 Clusters Against Core Etching Small 2007, 3, 835-839
29. Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution Science 2007, 318, 430-433
30. 18] J. Am. Chem. Soc. 2008, 130, 3754-3755
31. 38 Nanoparticles J. Am. Chem. Soc. 2010, 132, 8280-8281
32. 24 Angew. Chem., Int. Ed. 2012, 51, 13114-13118