Intramolecular iron-mediated C-H bond heterolysis with an assist of pendant base in a [FeFe]-hydrogenase model

Journal of the American Chemical Society

Volumn 136, Issue 48, 2014, Pages 16817-16823

  Zheng, Dehua ^a   Wang, Ning ^b,c   Wang, Mei ^a   Ding, Shengda ^b   Ma, Chengbing ^d   Darensbourg, Marcetta Y ^b   Hall, Michael B ^b   Sun, Licheng ^a,e  

^a DALIAN UNIVERSITY OF TECHNOLOGY   (China)

^b TEXAS A AND M UNIVERSITY   (United States)

^c HENAN UNIVERSITY OF TECHNOLOGY   (China)

^d FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^e ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL ACTIVATION; DESIGN FOR TESTABILITY; IRON; PROTONS;

DFT CALCULATION; HETEROLYTIC CLEAVAGE; HYDROGEN ACTIVATION; METALLOENZYMES; PENDANT AMINES; PROTON SHUTTLE; SULFUR BRIDGES; SYNTHETIC MODELS;

IRON COMPOUNDS;

AMINE; CARBON; DIIRON HYDROGENASE; HYDROGEN; IRON; IRON HYDROGENASE; PROTON; UNCLASSIFIED DRUG; HYDROGENASE; IRON DERIVATIVE; IRON SULFUR PROTEIN;

ARTICLE; COVALENT BOND; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ENZYME ACTIVE SITE; HETEROLYSIS; HYDROGEN BOND; LYSIS; MOLECULAR INTERACTION; OXIDATION; PROTON TRANSPORT; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; METABOLISM; OXIDATION REDUCTION REACTION; QUANTUM THEORY; SYNTHESIS;

HYDROGENASE; IRON COMPOUNDS; IRON-SULFUR PROTEINS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; QUANTUM THEORY;

EID: 84915820409     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5078014     Document Type: Article

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