Tuning the catalytic activity of graphene nanosheets for oxygen reduction reaction via size and thickness reduction

ACS Applied Materials and Interfaces

Volumn 6, Issue 22, 2014, Pages 19726-19736

  Benson, John ^a   Xu, Qian ^b   Wang, Peng ^b   Shen, Yuting ^c   Sun, Litao ^c   Wang, Tanyuan ^d   Li, Meixian ^d   Papakonstantinou, Pagona ^a  

^a UNIVERSITY OF ULSTER   (United Kingdom)

^b NANJING UNIVERSITY   (China)

^c Southeast University   (China)

^d PEKING UNIVERSITY   (China)

Author keywords

Edges; Electrocatalyst; Graphene nanosheets; Ionic liquid exfoliation; Oxygen reduction reaction

Indexed keywords

CATALYST ACTIVITY; ELECTROCATALYSTS; ELECTROLYTIC REDUCTION; GRAPHENE NANOPLATELETS; IONIC LIQUIDS; NANOSHEETS; OXYGEN; OXYGEN REDUCTION REACTION;

CARBON BASED CATALYSTS; EDGES; ELECTRODE SUBSTRATES; ELECTRON COMMUNICATION; GRAPHENE NANOSHEETS; LIQUID EXFOLIATIONS; ORR ELECTROCATALYSTS; THICKNESS REDUCTION;

GRAPHENE;

EID: 84914693605     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/am5048202     Document Type: Article

References (70)

1. Steele, B. C. H.; Heinzel, A. Materials for Fuel-Cell Technologies. Nature 2001, 414, 345-352.
2. Debe, M. K. Electrocatalyst Approaches and Challenges for Automotive Fuel Cells. Nature 2012, 486, 43-51.
3. Gasteiger, H. A.; Markovic, N. M. Just a Dream - or Future Reality? Science 2009, 324, 48-49.
4. Girishkumar, G.; McCloskey, B.; Luntz, A. C.; Swanson, S.; Wilcke, W. Lithium-Air Battery: Promise and Challenges. J. Phys. Chem. Lett. 2010, 1, 2193-2203.
5. Lee, J. S.; Tai Kim, S.; Cao, R.; Choi, N. S.; Liu, M.; Lee, K. T.; Cho, J. Metal -Air Batteries with High Energy Density: Li-Air versus Zn-Air. Adv. Energy Mater. 2011, 1, 34-50.
6. Chen, Z.; Higgins, D.; Yu, A.; Zhang, L.; Zhang, J. A Review on Non-Precious Metal Electrocatalysts for PEM Fuel Cells. Energy Environ. Sci. 2011, 4, 3167-3192.
7. Jaouen, F.; Proietti, E.; Lefevre, M.; Chenitz, R.; Dodelet, J.-P.; Wu, G.; Chung, H. T.; Johnston, C. M.; Zelenay, P. Recent Advances in Non-Precious Metal Catalysis for Oxygen-Reduction Reaction in Polymer Electrolyte Fuel Cells. Energy Environ. Sci. 2011, 4, 114-130.
8. Stamenkovic, V. R.; Mun, B. S.; Arenz, M.; Mayrhofer, K. J. J.; Lucas, C. A.; Wang, G.; Ross, P. N.; Markovic, N. M. Trends in Electrocatalysis on Extended and Nanoscale Pt-Bimetallic Alloy Surfaces. Nat. Mater. 2007, 6, 241-247.
9. Su, D. S.; Zhang, J.; Frank, B.; Thomas, A.; Wang, X.; Paraknowitsch, J.; Schlögl, R. Metal-Free Heterogeneous Catalysis for Sustainable Chemistry. ChemSusChem 2010, 3, 169-180.
10. Zheng, Y.; Jiao, Y.; Jin, Y.; Jaroniec, M.; Qiao, S. Z. Nanostructured Metal-Free Electrochemical Catalysts for Highly Efficient Oxygen Reduction. Small 2012, 8, 3550-3566.
11. Huang, C.; Li, C.; Shi, G. Graphene based Catalysts. Energy. Environ. Sci. 2012, 5, 8848-8868.
12. He, C.; Zhang, J. J.; Shen, P. K. Nitrogen-Self Doped Graphene based Non-Precious Metal Catalyst with Superior Performance to Pt/ CB Catalyst Towards Oxygen Reduction Reaction. J. Mater. Chem. A 2014, 2, 3231-3236.
13. Qu, L.; Liu, Y.; Baek, J. B.; Dai, L. Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells. ACS Nano 2010, 4, 1321-1326.
14. Geng, D.; Chen, Y.; Chen, Y.; Li, Y.; Li, R.; Sun, X.; Ye, S.; Knights, S. Energy's Thirst for Water in China. Energy Environ. Sci. 2011, 4, 11760-11764.
15. Yang, Z.; Yao, Z.; Li, G.; Fang, G.; Nie, H.; Liu, Z.; Zhou, X.; Chen, X.; Huang, S. Sulfur-Doped Graphene as an Efficient Metal-free Cathode Catalyst for Oxygen Reduction. ACS Nano 2012, 6, 205-211.
16. Paraknowitsch, J. P.; Thomas, A. Doping Carbons beyond Nitrogen: An Overview of Advanced Heteroatom Doped Carbons with Boron, Sulfur, and Phosphorus for Energy Applications. Energy Environ. Sci. 2013, 6, 2839-2855.
17. Zheng, Y.; Jiao, Y.; Ge, L.; Jaroniec, M.; Qiao, S. Z. Two-Step Boron and Nitrogen Doping in Graphene for Enhanced Synergistic Catalysis. Angew. Chem., Int. Ed. 2013, 52, 3110-3116.
18. Liang, J.; Jiao, Y.; Jaroniec, M.; Qiao, S. Z. Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance. Angew. Chem., Int. Ed. 2012, 51, 11496-11500.
19. Zhang, L.; Xia, Z. Mechanisms of Oxygen Reduction Reaction on Nitrogen-Doped Graphene for Fuel Cells. J. Phys. Chem. C 2011, 115, 11170-11176.
20. Wang, S.; Zhang, L.; Xia, Z.; Roy, A.; Chang, D. W.; Baek, J.-B.; Dai, L. BCN Graphene as Efficient Metal-free electrocatalysts for the Oxygen Reduction Reaction. Angew. Chem., Int. Ed. 2012, 51, 4209-4212.
21. Nakada, K.; Fujita, M.; Dresselhaus, G.; Dresselhaus, M. S. Edge State in Graphene Ribbons: Nanometer Size Effect and Edge Shape Dependence. Phys. Rev. B 1996, 54, 17954-17961.
22. Fujii, S.; Ziatdinov, M.; Ohtsuka, M.; Kusakabe, K.; Kiguchi, M.; Enoki, T. Role of Edge Geometry and Chemistry in the Electronic Properties of Graphene Nanostructures. Faraday discuss. 2014, DOI: 10.1039/C4FD00073K.
23. Yuan, W.; Zhou, Y.; Li, Y.; Peng, H.; Zhang, J.; Liu, Z.; Dai, L.; Shi, G. The Edge and Basal Plane Specific Electrochemistry of a Single Layer Graphene Sheet. Sci. Rep. 2013, 3, 2248.
24. Geim, A. K.; Novoselov, K. S. The Rise of Graphene. Nat. Mater. 2007, 6, 183-191.
25. Neubeck, S.; You, Y. M.; Ni, Z. H.; Blake, P.; Shen, Z. X.; Geim, A. K.; Novoselov, K. S. Direct Determination of the Crystallographic Orientation of Graphene Edges by Atomic Resolution Imaging. Appl. Phys. Lett. 2010, 97, 053110.
26. Ritter, K. A.; Lyding, J. W. The Influence of Edge Structure on the Electronic Properties of Graphene Quantum Dots and Nanoribbons. Nat. Mater. 2009, 8, 235-242.
27. Wang, D. W.; Su, D. Heterogeneous Nanocarbon Materials for Oxygen Reduction Reaction. Energy Environ. Sci. 2014, 7, 576-591.
28. Ji, X.; Banks, C. E.; Crossley, A.; Compton, R. G. Oxygenated Edge Plane Sites Slow the Electron Transfer of the Ferro-/ Ferricyanide Redox Couple at Graphite Electrodes. ChemPhysChem 2006, 7, 1337-1344.
29. Shang, N. G.; Papakonstantinou, P.; Sharma, S.; Lubarsky, G.; Li, M.; McNeill, D. W.; Quinn, A. J.; Zhou, W.; Blackley, R. Controllable Selective Exfoliation of High-Quality Graphene Nanosheets and Nanodots by Ionic Liquid Assisted Grinding. Chem. Commun. 2012, 48, 1877-1879.
30. Fukushima, T.; Kosaka, A.; Ishimura, Y.; Yamamoto, T.; Takigawa, T.; Ishii, N. Molecular Ordering of Organic Molten Salts Triggered by Single-Walled Carbon Nanotubes. Science 2003, 300, 2072-2074.
31. Fukushima, T.; Aida, T. Ionic Liquids for Soft Functional Materials with Carbon Nanotubes. Chem. - Eur. J. 2007, 13, 5048-5058.
32. Ambrosi, A.; Chua, C. K.; Khezri, B.; Sofer, Z.; Webster, R. D.; Pumera, M. Chemically Reduced Graphene contains Inherent Metallic Impurities Present in Parent Natural and Synthetic Graphite. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 12899.
33. Ambrosi, A.; Chee, S. Y.; Khezri, B.; Webster, R. D.; Sofer, Z.; Pumera, M. Metallic Impurities in Graphenes Prepared from Graphite Can Dramatically Influence Their Properties. Angew. Chem., Int. Ed. 2012, 51, 500-503.
34. Han, M. Y.;Özyllmaz, B.; Zhang, Y.; Kim, P. Energy Band-Gap Engineering of Graphene Nanoribbons. Phys. Rev. Lett. 2007, 98, 206805.
35. 2 Particles. Chemistry. - Eur. J. 2013, 19, 11939-11948.
36. Long, D.; Li, W.; Ling, L.; Miyawaki, J.; Mochida, I.; Yoon, S. H. Preparation of Nitrogen-Doped Graphene Sheets by a Combined Chemical and hydrothermal Reduction of Graphene Oxide. Langmuir 2010, 26, 16096-16102.
37. Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.; Obergfell, D.; Roth, S.; Girit, C.; Zettl, A. On the Roughness of Singleand Bi-Layer Graphene Membranes. Solid State Commun. 2007, 143, 101-109.
38. Horiuchi, S.; Gotou, T.; Fujiwara, M.; Sotoaka, R.; Hirata, M.; Kimoto, K.; Asaka, T.; Yokosawa, T.; Matsui, Y.; Watanabe, K.; Sekita, M. Carbon Nanofilm with a New Structure and Property. Jpn. J. Appl. Phys. 2003, 42, 1073-1076.
39. Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.; Booth, T. J.; Roth, S. The Structure of Suspended Graphene Sheets. Nature 2007, 446, 60-63.
40. Jeon, I. Y.; Choi, H.-J.; Choi, M.; Seo, J.-M.; Jung, S.-M.; Kim, M.-J.; Zhang, S.; Zhang, L.; Xia, Z.; Dai, L.; Park, N.; Baek, J. B. Facile, Scalable Synthesis of Edge-Halogenated Graphene Nanoplatelets as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction. Sci. Rep. 2013, 3, 1810.
41. Jeon, I.-Y.; Zhang, S.; Zhang, L.; Choi, H.-J.; Seo, J.-M.; Xia, Z.; Dai, L.; Baek, J. B. Edge-Selectively Sulfurized Graphene Nanoplatelets as Effient Metal Free Electrocatalysts for Oxygen Reduction Reaction: The Electron Spin Effect. Adv. Mater. 2013, 25, 6138-6145.
42. Dresselhaus, M. S.; Jorio, A.; Hofmann, M.; Dresselhaus, G.; Saito, R. Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy. Nano Lett. 2010, 10, 751-758.
43. Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri, M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth, S.; Geim, A. K. Raman Spectrum of Graphene and Graphene Layers. Phys. Rev. Lett. 2006, 97, 187401.
44. Casiraghi, C.; Hartschuh, A.; Qian, H.; Piscanec, S.; Georgi, C.; Novoselov, K. S.; Basko, D. M.; Ferrari, A. C. Raman spectroscopy of Graphene Edges. Nano Lett. 2009, 9, 1433-1441.
45. Mattevi, C.; Eda, G.; Agnoli, S.; Miller, S.; Mkhoyan, K. A.; Celik, O.; Mastrogiovanni, D.; Granozzi, G.; Garfunkel, E.; Chhowalla, M. Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin Films. Adv. Funct. Mater. 2009, 19, 2577.
46. Su, C. Y.; Xu, Y.; Zhang, W.; Zhao, J.; Tang, X.; Tsai, C. H.; Li, L. J. Electrical and Spectroscopic Characterization of Ultra-Large Reduced Graphene Oxide Monolayers. Chem. Mater. 2009, 21, 5674-5680.
47. Wang, H.; Robinson, J. T.; Li, X.; Dai, H. Solvothermal Reduction of Chemically Exfoliated Graphene Sheets. J. Am. Chem. Soc. 2009, 131, 9910-9911.
48. Welham, N. J.; Williams, J. S. Extended Milling of Graphite and Activated Carbon. Carbon. 1998, 36, 1309-1315.
49. Jiang, W.; Nadeau, G.; Zaghib, K.; Kinoshita, K. Thermal Analysis of the Oxidation of Natural Graphite - Effect of Particle Size. Thermochim. Acta 2000, 351, 85-93.
50. Ganguly, A.; Sharm, S.; Papakonstantinou, P.; Hamilton, J. Probing the Thermal Deoxygenation of Graphene Oxide Using High- Resolution in Situ X-ray based Spectroscopies. J. Phys. Chem. C 2011, 115, 17009-17019.
51. Li, H. Determination of Oxygen Functionality on Highly Oriented Pyrolytic Graphite (HOPG). Ph.D. Thesis, Freie University, Berlin, December 2012.
52. Skaltsas, T.; Ke, X.; Bittencourt, C.; Tagmatarchis, N. Ultrasonication Induces Oxygenated Species and Defects onto Exfoliated Graphene. J. Phys. Chem. C 2013, 117, 23272-23278.
53. Zhang, Y.; Ge, J.; Wang, L.; Wang, D.; Ding, F.; Tao, X.; Chen, W. Manageable N-Doped Graphene for High Performance Oxygen Reduction Reaction. Sci. Rep. 2013, 3, 2771.
54. Sun, Y.; Li, C.; Shi, G. Nanoporous Nitrogen Doped Carbon Modified Graphene as Electrocatalyst for Oxygen Reduction. J. Mater. Chem. 2012, 22, 12810-12816.
55. 4 Nanoparticles as Efficient Electrocatalysts for the Oxygen Reduction Reaction. J. Am. Chem. Soc. 2012, 134, 9082-9085.
56. Parvez, K.; Yang, S.; Hernandez, Y.; Winter, A.; Turchanin, A.; Feng, X.; Müllen, K. Nitrogen-Doped Graphene and its Iron-Based Composite as Efficient Electrocatalysts for Oxygen Reduction Reaction. ACS Nano 2012, 6, 9541-9550.
57. Deng, D. H.; Yu, L.; Pan, X. L.; Wang, S.; Chen, X. Q.; Hu, P.; Sun, L. X.; Bao, X. H. Size Effect of Graphene on Electrocatalytic Activation of Oxygen. Chem. Commun. 2011, 47, 10016-10018.
58. McCrory, C. C. L.; Jung, S.; Peters, J. C.; Jaramillo, T. F. Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction. J. Am. Chem. Soc. 2013, 135, 16977-16987.
59. Nakada, K.; Fujita, M.; Dresselhaus, G.; Dresselhaus, M. S. Edge State in Graphene Ribbons: Nanometer Size Effect and Edge Shape Dependence. Phys. Rev. B 1996, 54, 17954-17961.
60. Choi, C. H.; Lim, H.-K.; Chung, M. W.; Park, J. C.; Shin, H.; Kim, H.; Woo, S. I. Long-Range Electron Transfer over Graphenebased Catalysts for High-Performing Oxygen Reduction Reactions: Importance of Size, N-Doping and Metallic Impurities. J. Am. Chem. Soc. 2014, 136, 9070-9077.
61. Li, F.; Chen, Z. Graphene-based Materials as Nanocatalysts [Online]. In Graphene Chemistry: Theoretical Perspective; Jiang, D., Chen, Z., Eds.; John Wiley & Sons: New York, 2013; Chapter 15, pp 347-349. http://eu.wiley.com/WileyCDA/WileyTitle/productCd- 1119942128.html# (accessed October 2, 2014).
62. Yu, H. Recent Advances in Photoresponsive Liquid-Crystalline Polymers Containing Azobenzene Chromophores. J. Mater. Chem. A 2014, 2, 3047-3054.
63. Benck, J. D.; Chen, Z.; Kuritzky, L. Y.; Forman, A. J.; Jaramillo, T. F. Amorphous Molybdenum Sulfide Catalysts for Electrochemical Hydrogen Production: Insights into the Origin of their Catalytic Activity. ACS Catal. 2012, 9, 1916-1923.
64. Zhang, L.; Niu, J.; Li, M.; Xia, Z. Catalytic Mechanism of Sulfur- Doped Graphene as Efficient Oxygen Reduction Reaction Catalysts for Fuel Cells. J. Phys. Chem. C 2014, 118, 3545-3553.
65. Tian, J.; Cao, H.; Wu, W.; Yu, Q.; Chen, Y. P. Direct Imaging of Graphene Edges: Atomic Structure and Electronic Scattering. Nano Lett. 2011, 11, 3663-3668.
66. Kaye, G. W. C.; Laby, T. H. Tables of Physical and Chemical Constants and Some Mathematical Functions, 14th ed.; Longman: London, 1973.
67. Cheon, J. Y.; Kim, J. H.; Kim, J. H.; Goddeti, K. C.; Park, J. Y.; Joo, S. H. Intrinsic Relationship between Enhanced Oxygen Reduction Reaction Activity and Nanoscale Work Function of Doped Carbons. J. Am. Chem. Soc. 2014, 136, 8875-8878.
68. Takahashi, T.; Tokailin, H.; Sagawa, T. Tuning the Graphene Work Function by Electric Field Effect. Phys. Rev. B 1985, 32, 8317-8324.
69. Giovannetti, G.; Khomyakov, P. A.; Brocks, G.; Karpan, V. M.; van den Brink, J.; Kelly, P. J. Doping Graphene with Metal Contacts. Phys. Rev. Lett. 2008, 101, 026803.
70. Hibino, H.; Kageshima, H.; Kotsugi, M.; Maeda, F.; Guo, F.-Z.; Watanabe, Y. Dependence of Electronic Properties of Epitaxial Few- Layer Graphene on the Number of Layers Investigated by Photoelectron Emission Microscopy. Phys. Rev. B 2009, 79, 125437.