Breaking the symmetry of ions at the air-water interface

Journal of Physical Chemistry C

Volumn 118, Issue 46, 2014, Pages 26629-26633

  Brandes, Eva ^a   Karageorgiev, Peter ^a   Viswanath, Padmanabhan ^b   Motschmann, Hubert ^a  

^a UNIVERSITY OF REGENSBURG   (Germany)

^b CENTRE FOR NANO AND SOFT MATTER SCIENCES   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AIR; ELECTROLYTES; IONS; IRON METALLOGRAPHY; SURFACE TENSION;

AIR WATER INTERFACES; EQUILIBRIUM ISOTHERMS; EXPERIMENTAL EVIDENCE; INFRARED VISIBLE SUM FREQUENCY GENERATION SPECTROSCOPY; INTERFACIAL CONCENTRATIONS; NONLINEAR OPTICAL TECHNIQUE; POTASSIUM FERROCYANIDE; SURFACE TENSION MEASUREMENTS;

PHASE INTERFACES;

EID: 84914690650     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp5045805     Document Type: Article

References (43)

1. Evans, D. F. The Colloidal Domain: Where Physics, Chemistry, Biology, and Technology Meet, 2nd ed.; Wiley: New York, 1998.
2. Onsager, L.; Samaras, N. N. T. The Surface Tension of Debye-Hückel Electrolytes. J. Chem. Phys. 1934, 2, 528-536.
3. Randles, J. E. B. Structure at the Free Surface of Water and Aqueous Electrolyte Solutions. Phys. Chem. Liq. 1977, 7, 107-179.
4. - Ion Concentration: Te Effect of Chemical Reaction at the Interface. J. Phys. Chem. 1995, 99, 8768-8776.
5. Knipping, E. M.; Lakin, M. J.; Foster, K. L.; Jungwirth, P.; Tobias, D. J.; Gerber, R. B.; Dabdub, D.; Finlayson-Pitts, B. J. Experiments and Simulations of Ion-Enhanced Interfacial Chemistry on Aqueous NaCl Aerosols. Science 2000, 288, 301-306.
6. Jungwirth, P.; Tobias, D. J. Specific Ion Effects at the Air/Water Interface. Chem. Rev. 2006, 106, 1259-1281.
7. Jungwirth, P.; Tobias, D. J. Molecular Structure of Salt Solutions: A New View of the Interface with Implications for Heterogeneous Atmospheric Chemistry. J. Phys. Chem. B 2001, 105, 10468-10472.
8. Horinek, D.; Herz, A.; Vrbka, L.; Sedlmeier, F.; Mamatkulov, S. I.; Netz, R. R. Specific Ion Adsorption at the Air/water Interface: The Role of Hydrophobic Solvation. Chem. Phys. Lett. 2009, 479, 173-183.
9. Gopalakrishnan, S.; Jungwirth, P.; Tobias, D. J.; Allen, H. C. Air-Liquid Interfaces of Aqueous Solutions Containing Ammonium and Sulfate: Spectroscopic and Molecular Dynamics Studies. J. Phys. Chem. B 2005, 109, 8861-8872.
10. 3 Aqueous Solutions. J. Phys. Chem. C 2013, 117, 19082-19090.
11. Padmanabhan, V.; Daillant, J.; Belloni, L.; Mora, S.; Alba, M.; Konovalov, O. Specific Ion Adsorption and Short-Range Interactions at the Air Aqueous Solution Interface. Phys. Rev. Lett. 2007, 99, No. 086105.
12. Kunz, W.; Lo Nostro, P.; Ninham, B. W. The Present State of Affairs with Hofmeister Effects. Curr. Opin. Colloid Interface Sci. 2004, 9, 1-18.
13. Collins, K. D. Ions from the Hofmeister Series and Osmolytes: Effects on Proteins in Solution and in the Crystallization Process. Methods 2004, 34, 300-311.
14. Shen, Y. R. Surfaces probed by nonlinear optics. Surf. Sci. 1994, 299-300, 551-62.
15. Johnson, A. E.; Myers, A. B. Solvent Effects in the Raman Spectra of the Triiodide Ion: Observation of Dynamic Symmetry Breaking and Solvent Degrees of Freedom. J. Phys. Chem. 1996, 100, 7778-7788.
16. -: Raman Spectra of Nitrate Salts and Ab Initio Resonance Raman Spectra of Nitrate-Water Complexes. J. Chem. Phys. 2001, 114, 6249-6258.
17. - in Aqueous Solution: NO Asymmetric Stretch Frequency Distribution and Mean Splitting. J. Phys. Chem. A 2010, 114, 1255-1269.
18. Kido Soule, M. C.; Blower, P. G.; Richmond, G. L. Nonlinear Vibrational Spectroscopic Studies of the Adsorption and Speciation of Nitric Acid at the Vapor/Acid Solution Interface. J. Phys. Chem. A 2007, 111, 3349-3357.
19. Myers Kelley, A.; Shoute, L. C. T.; Blanchard-Desce, M.; Bartholomew, G. P.; Bazan, G. C. Resonance Raman, Hyper-Raman, and Hyper-Rayleigh Depolarization Ratios and Symmetry Breaking in Solution. Mol. Phys. 2006, 104, 1239-1247.
20. Manciu, M.; Ruckenstein, E. Ions Near the Air/water Interface. Part 1. Compatibility of Zeta Potential and Surface Tension Experiments. Colloids Surf., A 2012, 400, 27-35.
21. Viswanath, P.; Aroti, A.; Motschmann, H.; Leontidis, E. Vibrational Sum Frequency Generation Spectroscopic Investigation of the Interaction of Thiocyanate Ions with Zwitterionic Phospholipid Monilayers at the Air-Water Interface. J. Phys. Chem. A 2009, 113, 14816-14823.
22. Siefermann, K. R.; Liu, Y.; Lugovoy, E.; Link, O.; Faubel, M.; Buck, U.; Winter, B.; Abel, B. Binding energies, lifetimes and implications of bulk and interface solvated electrons in water. Nat. Chem. 2010, 2, 274.
23. Sando, G. M.; Zhong, Q.; Owrutsky, J. C. Vibrational and Rotational Dynamics of Cyanoferrates in Solution. J. Chem. Phys. 2004, 121, 2158-2168.
24. Engel, N.; Bokarev, S. I.; Suljoti, E.; Garcia-Diez, R.; Lange, K. M.; Atak, K.; Golnak, R.; Kothe, A.; Dantz, M.; Khn, O.; et al. Chemical Bonding in Aqueous Ferrocyanide: Experimental and Theoretical X-ray Spectroscopic Study. J. Phys. Chem. B 2014, 118, 1555-1563.
25. 6]: A Direct Probe of Back-Bonding. J. Am. Chem. Soc. 2006, 128, 10442-10451.
26. Stein, G. Photochemistry of the Ferrocyanide Ion in Aqueous Solution: Hydrated Electron Formation and Aquation. Isr. J. Chem. 1970, 8, 691-697.
27. Bode, A. A. C.; Vonk, V.; van den Bruele, F. J.; Kok, D. J.; Kerkenaar, A. M.; Mantilla, M. F.; Jiang, S.; Meijer, J. A. M.; van Enckevort, W. J. P.; Vlieg, E. Anticaking Activity of Ferrocyanide on Sodium Chloride Explained by Charge Mismatch. Cryst. Growth Des. 2012, 12, 1919-1924.
28. Terenziani, F.; Painelli, A.; Katan, C.; Charlot, M.; Blanchard-Desce, M. Charge Instability in Quadrupolar Chromophores: Symmetry Breaking and Solvatochromism. J. Am. Chem. Soc. 2006, 128, 15742-15755.
29. Perrin, J. S.; Charles, L. Lau Hydrogen-Bond Symmetry in Zwitterionic Phthalate Anions: Symmetry Breaking by Solvation. J. Am. Chem. Soc. 2006, 128, 11820-11824.
30. Margulis, C. J.; Coker, D. F.; Lynden-Bell, R. M. Symmetry Breaking of the Triiodide Ion in Acetonitrile Solution. Chem. Phys. Lett. 2001, 341, 557-560.
31. 2. Chem. Phys. Lett. 1990, 170, 128-132.
32. 2O with Third-Order Nonlinear Infrared Spectroscopy. J. Phys. Chem. A 2004, 108, 1333-1341.
33. Petersen, P. B.; Saykally, R. J. Adsorption of Ions to the Surface of Dilute Electrolyte Solutions: The Jones-Ray Effect Revisited. J. Am. Chem. Soc. 2005, 127, 15446-15452.
34. Lunkenheimer, K.; Pergande, H. J.; Krueger, H. Apparatus for Programmed High-Performance Purification of Surfactant Solutions. Rev. Sci. Instrum. 1987, 58, 2313-2316.
35. Lunkenheimer, K.; Wienskol, G.; Prosser, A. Automated High-performance Purification of Surfactant Solutions: Study of Convective-Enhanced Adsorption. Langmuir 2004, 20, 5738-5744.
36. Viswanath, P.; Motschmann, H. Effect of Interfacial Presence of Oriented Thiocyanate on Water Structure. J. Phys. Chem. C 2008, 112, 2099-2103.
37. Karageorgiev, P.; Petrov, J. G.; Motschmann, H.; Moehwald, H. Why Fluorination of the Polar Heads Reverses the Positive Sign of the Dipole Potential of Langmuir Monolayers: A Vibrational Sum Frequency Spectroscopic Study. Langmuir 2013, 29, 4726-4736.
38. Du, Q.; Superfine, R.; Freysz, E.; Shen, Y. R. Vibrational spectroscopy of water at the vapor/water interface. Phys. Rev. Lett. 1993, 70, 2313-2316.
39. Liu, D.; Ma, G.; Levering, L. M.; Allen, H. C. Vibrational Spectroscopy of Aqueous Sodium Halide Solutions and Air-Liquid Interfaces: Observation of Increased Interfacial Depth. J. Phys. Chem. B 2004, 108, 2252.
40. Raymond, E. A.; Richmond, G. L. Probing the Molecular Structure and Bonding of the Surface of Aqueous Salt Solutions. J. Phys. Chem. B 2004, 108, 5051.
41. Sovago, M.; Campen, R. K.; Wurpel, G. W. H.; Müller, M.; Bakker, H. J.; Bonn, M. Vibrational Response of Hydrogen-Bonded Interfacial Water is Dominated by Intramolecular Coupling. Phys. Rev. Lett. 2008, 100, No. 173901.
42. Fan, Y.; Chen, X.; Yang, L.; Cremer, P. S.; Gao, Y. Q. On the Structure of Water at the Aqueous/Air Interface. J. Phys. Chem. B 2009, 113, 11672-11679.
43. Brandes, E.; Stage, C.; Motschmann, H.; Rieder, J.; Buchner, R. Is surface layering of aqueous alkali halides determined by ion pairing in the bulk solution? J. Chem. Phys. 2014, 141, 18C509-1.