메뉴 건너뛰기




Volumn 100, Issue 19, 1996, Pages 7778-7788

Solvent effects in the Raman spectra of the triiodide ion: Observation of dynamic symmetry breaking and solvent degrees of freedom

Author keywords

[No Author keywords available]

Indexed keywords


EID: 33749083442     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp953052x     Document Type: Article
Times cited : (118)

References (51)
  • 21
    • 85033055397 scopus 로고    scopus 로고
    • note
    • 4. The ethanol cross sections are therefore reproduced here in Table 1.
  • 22
    • 85033054065 scopus 로고    scopus 로고
    • note
    • 11 we mistakenly used twice the preresonant line width in the calculation of the resonance Raman spectra, giving the misleading impression that combination bands between the symmetric and antisymmetric stretches provided sufficient vibrational broadening on resonance. However, spectra that are calculated using the correct preresonant line widths are much sharper and show significantly more structure than the experimental spectra.
  • 32
    • 85033061193 scopus 로고    scopus 로고
    • note
    • 12 indicate that our current assumption of separability of the symmetric and antisymmetric stretches in the excited states is probably a good assumption.
  • 40
    • 0000534619 scopus 로고
    • Myers, A. B., Rizzo, T. R., Eds.; Wiley: New York
    • Myers, A. B. In Laser Techniques in Chemistry; Myers, A. B., Rizzo, T. R., Eds.; Wiley: New York, 1995; p 325.
    • (1995) Laser Techniques in Chemistry , pp. 325
    • Myers, A.B.1
  • 46
    • 85033059599 scopus 로고    scopus 로고
    • note
    • The nonexponential behavior of solvation dynamics implies that the assumption of an exponential decay of the solvent asymmetry in our simple model is probably not a good approximation. A better model would include a distribution of correlation times corresponding to different types of solvent motion.
  • 50
    • 85033061848 scopus 로고    scopus 로고
    • Personal communication
    • Ruhman, S. Personal communication.
    • Ruhman, S.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.