X-ray reflectivity reveals a nonmonotonic ion-density profile perpendicular to the surface of ErCl3 aqueous solutions

Journal of Physical Chemistry C

Volumn 117, Issue 37, 2013, Pages 19082-19090

  Luo, Guangming ^a,d   Bu, Wei ^c   Mihaylov, Miroslav ^c   Kuzmenko, Ivan ^b   Schlossman, Mark L ^c   Soderholm, L ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

^b ARGONNE NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

^d INSTITUTE OF HIGH ENERGY PHYSICS   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; CHLORINE COMPOUNDS; ELECTROLYTES; ERBIUM COMPOUNDS; METAL IONS; METALS; MOLECULAR DYNAMICS; PHASE INTERFACES; POSITIVE IONS; REFLECTION; SOLUTIONS; X RAYS;

DEPLETION-LAYER THICKNESS; ELECTRON DENSITY PROFILES; GIBBS ADSORPTION EQUATION; LIQUID/VAPOR INTERFACES; MOLECULAR DYNAMICS SIMULATIONS; NON-MONOTONIC VARIATION; SURFACE TENSION MEASUREMENTS; X-RAY REFLECTIVITY MEASUREMENTS;

SOLUTION MINING;

EID: 84884562060     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4067247     Document Type: Article

References (47)

1. Jungwirth, P.; Tobias, D. J. Specific Ion Effects at the Air/Water Interface Chem Rev 2006, 106, 1259-1281
2. Tasker, P. A.; Plieger, P. G.; West, L. C. Metal Complexes for Hydrometallurgy and Extraction. In Comprehensive Coordination Chemistry II: From Biology to Nanotechnology; McCleverty, J. A.; Meyer, T. J., Eds.; Elsevier: Oxford, 2004; Vol. 9, pp 759-808.
3. Fenter, P.; Sturchio, N. C. Mineral-Water Interfacial Structures Revealed by Synchrotron X-Ray Scattering Prog. Surf. Sci. 2004, 77, 171-258
4. 3: Dissecting Environmental Interfaces with a Nonlinear Optical Swiss Army Knife Annu. Rev. Phys. Chem. 2009, 60, 61-83
5. Seinfeld, J. H. Meeting at the Interface Science 2000, 288, 285
6. Takata, Y.; Ohshima, H. Interfacial Tension of Aqueous Electrolyte Solutions: Ion-Free Layer. In Electrical Phenomena at Interfaces and Biointerfaces: Fundamentals and Applications in Nano-, Bio-, and Environmental Sciences; Ohshima, H., Ed.; John Wiley & Sons: Hoboken, NJ, 2012; pp 223-240.
7. Wagner, C. Die Oberflächenspannung Verdünnter Elektrolytlösungen Phys. Z. 1924, 25, 474-477
8. Onsager, L.; Samaras, N. N. T. The Surface Tension of Debye Hückel Electrolytes J. Chem. Phys. 1934, 2, 528-536
9. Markin, V. S.; Volkov, A. G. Quantitative Theory of Surface Tension and Surface Potential of Aqueous Solutions of Electrolytes J. Phys. Chem. B 2002, 106 (45) 11810-11817
10. Ruckenstein, E.; Manciu, M. Specific Ion Effects Via Ion Hydration: II. Double Layer Interaction Adv. Colloid Interface Sci. 2003, 105, 177-200
11. Edwards, S. A.; Williams, D. R. M. Surface Tension of Electrolyte Solutions: Comparing the Effects of Ionic Dispersion Forces and Solvation Europhys. Lett. 2006, 74 (5) 854-860
12. Ninham, B. W.; Yaminsky, V. Ion Binding and Ion Specificity: The Hofmeister Effect and Onsager and Lifshitz Theories Langmuir 1997, 13 (7) 2097-2108
13. Levin, Y.; Flores-Mena, J. R. Surface Tension of Strong Electrolytes Europhys. Lett. 2001, 56 (2) 187-192
14. Padmanabhan, V.; Daillant, J.; Belloni, L.; Mora, S.; Alba, M.; Konovalov, O. Specific Ion Adsorption and Short-Range Interactions at the Air Aqueous Solution Interface Phys. Rev. Lett. 2007, 99, 086105
15. Jungwirth, P.; Tobias, D. J. Molecular Structure of Salt Solutions: A New View of the Interface with Implications for Atmospheric Chemistry J. Phys. Chem. B 2001, 105, 10468-10472
16. Jungwirth, P.; Tobias, D. J. Ions at the Air/Water Interface J. Phys. Chem. B 2002, 106 (25) 6361-6373
17. Mucha, M.; Frigato, T.; Levering, L. M.; Allen, H. C.; Tobias, D. J.; Dang, L. X.; Jungwirth, P. Unified Molecular Picture of the Surfaces of Aqueous Acid, Base, and Salt Solutions J. Phys. Chem. B 2005, 109 (16) 7617-7623
18. Chang, T. M.; Dang, L. X. Recent Advances in Molecular Simulations of Ion Solvation at Liquid Interfaces Chem. Rev. 2006, 106 (4) 1305-1322
19. Garrett, B. C. Ions at the Air/Water Interface Science 2004, 303 (5661) 1146-1147
20. Liu, D. F.; Ma, G.; Levering, L. M.; Allen, H. C. Vibrational Spectroscopy of Aqueous Sodium Halide Solutions and Air-Liquid Interfaces: Observation of Increased Interfacial Depth J.Phys. Chem. B 2004, 108 (7) 2252-2260
21. Weber, R.; Winter, B.; Schmidt, P. M.; Widdra, W.; Hertel, I. V.; Dittmar, M.; Faubel, M. Photoemission from Aqueous Alkali-Metal-Iodide Salt Solutions Using VUV Synchrotron Radiation J. Phys. Chem. B 2004, 108 (15) 4729-4736
22. Ghosal, S.; Hemminger, J. C.; Bluhm, H.; Mun, B. S.; Hebenstreit, E. L. D.; Ketteler, G.; Ogletree, D. F.; Requejo, F. G.; Salmeron, M. Electron Spectroscopy of Aqueous Solution Interfaces Reveals Surface Enhancement of Halides Science 2005, 307, 563-566
23. Petersen, P. B.; Saykally, R. J. On the Nature of Ions at the Liquid Water Surface Annu. Rev. Phys. Chem. 2006, 57, 333-364
24. 2 and Application to Atmospheric Marine Aerosol Chemistry Proc. Natl. Acad. Sci. U.S.A. 2010, 107 (15) 6616-6621
25. Jubb, A. M.; Hua, W.; Allen, H. C. Environmental Chemistry at Vapor/Water Interfaces: Insights from Vibrational Sum Frequency Generation Spectroscopy Annu. Rev. Phys. Chem. 2012, 63, 6.1-6.24
26. Vrbka, L.; Mucha, M.; Minofar, B.; Jungwirth, P.; Brown, E. C.; Tobias, D. J. Propensity of Soft Ions for the Air/Water Interface Curr. Opin. Colloid Interface Sci. 2004, 9, 67-73
27. Xu, M.; Spinney, R.; Allen, H. C. Water Structure at the Air-Aqueous Interface of Divalent Cation and Nitrate Solutions J. Phys. Chem. B 2009, 113 (13) 4102-4110
28. 2 Production from the Oxidation of Aqueous Bromide-Containing Aerosols and Atmospheric Implications Atmos. Environ. 2009, 43, 3951-3962
29. 3 J. Chem. Phys. 1979, 70, 2797-2806
30. Johansson, G.; Yokoyama, H. Inner-Sphere and Outer-Sphere Complex-Formation in Aqueous Erbium Halide and Perchlorate Solutions-an X-Ray-Diffraction Study Using Isostructural Substitution Inorg. Chem. 1990, 29 (13) 2460-2466
31. Soderholm, L.; Skanthakumar, S.; Wilson, R. E. Structures and Energetics of Erbium Chloride Complexes in Aqueous Solution J. Phys. Chem. A 2009, 113 (22) 6391-6397
32. Schwartz, D. K.; Schlossman, M. L.; Pershan, P. S. Re-Entrant Appearance of Phases in a Relaxed Langmuir Monolayer of Tetracosanoic Acid as Determined by X-Ray Scattering J. Chem. Phys. 1992, 96, 2356-2370
33. Pershan, P. S.; Schlossman, M. L. Liquid Surfaces and Interfaces: Synchrotron X-Ray Methods; Cambridge University Press: Cambridge, 2012.
34. Landau, D. P.; Binder, K. A Guide to Monte Carlo Simulations in Statistical Physics; Cambridge University Press: Cambridge, 2000.
35. Molina, J. J.; Duvail, M.; Dufreche, J.-F.; Guilbaud, P. Atomistic Description of Binary Lanthanoid Salt Solutions: A Coarse-Graining Approach J. Phys. Chem. B 2011, 115, 4329-4340
36. Senapati, S.; Berkowitz, M. L. Computer Simulation Study of the Interface Width of the Liquid/Liquid Interface Phys. Rev. Lett. 2001, 87, 176101
37. Yeh, I.-C.; Berkowitz, M. L. Ewald Summation for Systems with Slab Geometry J. Chem. Phys. 1999, 111, 3155-3162
38. Kawata, M.; Mikami, M. Rapid Calculation of Two-Dimensional Ewald Summation Chem. Phys. Lett. 2001, 340, 157-164
39. Pershan, P. S.; Braslau, A.; Weiss, A. H.; Als-Nielsen, J. Smectic Layering at the Free Surface of Liquid Crystals in the Nematic Phase: X-Ray Reflectivity Phys. Rev. A 1987, 35, 4800
40. Mioduski, T.; Gumiński, C.; Zeng, D. IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd-Lu) J. Phys. Chem. Ref. Data 2009, 38, 925-1011
41. Rydberg, J.; Cox, M.; Musikas, C.; Choppin, G. R. Solvent Extraction Principles and Practice; Marcel Dekker, Inc.: New York, 1992; p 773.
42. Morss, L. R. Thermochemical Properties of Yttrium, Lanthanum, and the Lanthanide Elements and Ions Chem. Rev. 1976, 76, 827-441
43. Sloutskin, E.; Baumert, J.; Ocko, B. M.; Kuzmenko, I.; Checco, A.; Tamam, L.; Ofer, E.; Gog, T.; Gang, O.; Deutsch, M. The Surface Structure of Concentrated Aqueous Salt Solutions J. Chem. Phys. 2007, 126, 054704
44. Peppard, D. F.; Mason, G. W.; Hugher, I. Stability Constants of Certain Lanthanide(III) and Actinide(III) Chloride and Nitrate Complexes J. Inorg. Nucl. Chem. 1962, 24, 881-888
45. Smith, R. M.; Martell, A. E. Critical Stability Constants, Vol. 4: Inorganic Complexes; Plenum Press: New York, 1976.
46. Fernandez-Ramirez, E.; Jimenez-Reyes, M.; Solache-Rios, J. Effects of Ionic Strength and Charge Density on the Stability of Chloride Complexes of Trivalent Lanthanides J. Chem. Eng. Data 2008, 53, 1756-1761
47. Beuchat, C.; Hagberg, D.; Spezia, R.; Gagliaridi, L. Hydration of Lanthanide Chlordide Salts: A Quantum Chemical and Classical Molecular Dynamics Simulation Study J. Phys. Chem. B 2010, 114, 15590-15597