Graphene-based materials: Synthesis and gas sorption, storage and separation

Progress in Materials Science

Volumn 69, Issue , 2015, Pages 1-60

  Gadipelli, Srinivas ^a   Guo, Zheng Xiao ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

Carbon capture; Gas separation; Gas storage; Graphene; Graphene oxide; Hydrogen storage; Methane storage; Synthesis

Indexed keywords

CARBON CAPTURE; CARBON DIOXIDE; CRYSTALLINE MATERIALS; GASES; HYDROGEN STORAGE; METHANE; ORGANOMETALLICS; SEPARATION; SORPTION; STORAGE (MATERIALS); SULFUR DIOXIDE; SYNTHESIS (CHEMICAL);

GAS SEPARATIONS; GAS STORAGE; GRAPHENE OXIDES; HIERARCHICAL PORE STRUCTURES; METAL ORGANIC FRAMEWORK; METHANE STORAGE; RESEARCH ACTIVITIES; SURFACE FUNCTIONALIZATION;

GRAPHENE;

EID: 84912111818     PISSN: 00796425     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.pmatsci.2014.10.004     Document Type: Review

References (379)

1. Pierson HO. Handbook of carbon, graphite, diamond and fullerenes. NJ, USA: Noyes; 1993.
2. Dai L, Chang DW, Baek JB, Lu W. Carbon nanomaterials for advanced energy conversion and storage. Small 2012;8:113066.
3. Dreyer DR, Ruoff RS, Bielawski CW. From conception to realization: an historial account of graphene and some perspectives for its future. Angew Chem Int Ed 2012;51:7640-54.
4. Novoselov KS, Falko VI, Colombo L, Gellert PR, Schwab MG, Kim K. A roadmap for graphene. Nature 2012;490:192-200.
5. Sarma SD, Adam S, Hwang EH, Rossi E. Electronic transport in two-dimensional graphene. Rev Mod Phys 2011;83:407-70.
6. Abergel DSL, Apalkov V, Berashevich J, Ziegler K, Chakraborty T. Properties of graphene: a theoretical perspective. Adv Phys 2010;59:261-482.
7. Georgakilas V, Otyepka M, Bourlinos AB, Chandra V, Kim N, Kemp KC, et al. Functionalization of graphene: covalent and non-covalent approaches, derivatives and applications. Chem Rev 2012;112:6156-214.
8. Chen Y, Zhang B, Liu G, Zhuang X, Kang ET. Graphene and its derivatives: switching ON and OFF. Chem Soc Rev 2012;41:4688-707.
9. Wei W, Qu X. Extraordinary physical properties of functionalized graphene. Small 2012;8:2138-51.
10. Kuila T, Bose S, Mishra AK, Khanra P, Kim NH, Lee JH. Chemical functionalization of graphene and its applications. Prog Mater Sci 2012;57:1061-105.
11. Sun Z, James DK, Tour JM. Graphene chemistry: synthesis and manipulation. J Phys Chem Lett 2011;2:2425-32.
12. Huang X, Qi X, Boey F, Zhang H. Graphene-based composites. Chem Soc Rev 2012;41:666-86.
13. Singh V, Joung D, Zhai L, Das S, Khondaker SI, Seal S. Graphene based materials: past, present and future. Prog Mater Sci 2011;56:1178-271.
14. Huang X, Yin Z, Wu S, Qi X, He Q, Zhang Q, et al. Graphene-based materials: synthesis, characterization, properties, and applications. Small 2011;7:1876-902.
15. Weiss NO, Zhou H, Liao L, Liu Y, Jiang S, Huang Y, et al. Graphene: an emerging electronic material. Adv Mater 2012;24:5782-825.
16. Bonaccorso F, Sun Z, Hasan T, Ferrari AC. Graphene photonics and optoelectronics. Nat Photon 2010;4:611-22.
17. Yavari F, Koratkar N. Graphene-based chemical sensors. J Phys Chem Lett 2012;3:1746-53.
18. Huang X, Zeng Z, Fan Z, Liu J, Zhang H. Graphene-based electrodes. Adv Mater 2012;24:5979-6004.
19. Xiang Q, Yu J, Jaroniec M. Graphene-based semiconductor photocatalysts. Chem Soc Rev 2012;41:782-96.
20. Basu S, Bhattacharyya P. Recent developments on graphene and graphene oxide based solid state gas sensors. Sens Actuat B 2012;173:1-21.
21. Zhao G, Wen T, Chen C, Wang X. Synthesis of graphene-based nanomaterials and their application in energy related and environmental-related areas. RSC Adv 2012;2:9286-303.
22. Zhang N, Zhang Y, Xu YJ. Recent progress on graphene-based photocatalysts: current status and future perspectives. Nanoscale 2012;4:5792-813.
23. Shao Y, Wang J, Wu H, Liu J, Aksay IA, Lin Y. Graphene based electrochemical sensors and biosensors: a review. Electroanalysis 2010;22:1027-36.
24. Choi HJ, Jung SM, Seo JM, Chang DW, Dai L, Baek JB. Graphene for energy conversion and storage in fuel cells and supercapacitors. Nano Energy 2012;1:534-51.
25. Machado BF, Serp P. Graphene-based materials for catalysis. Catal Sci Technol 2012;2:54-75.
26. Malig J, Jux N, Guldi DM. Toward multifunctional wet chemically functionalized graphene-integration of oligomeric, molecular, and particulate building blocks that reveal photoactivity and redox activity. Acc Chem Res 2013;46:53-64.
27. Sahoo NG, Pan Y, Li L, Chan SH. Graphene-based materials for energy conversion. Adv Mater 2012;24:4203-10.
28. Kim K, Choi JY, Kim T, Cho SH, Chung HJ. A role for graphene in silicon-based semiconductor devices. Nature 2011;479:338-44.
29. Soldano C, Mahmood A, Dujardin E. Production, properties and potential of graphene. Carbon 2010;48:2127-50.
30. Wei D, Liu Y. Controllable synthesis of graphene and its applications. Adv Mater 2010;22:3225-41.
31. Zhu Y, Murali S, Cai W, Li X, Suk JW, Potts JR, et al. Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 2010;22:3906-24.
32. Chen L, Hernandez Y, Feng X, Mullen K. From nanographene and graphene nanoribbons to graphene sheets: chemical synthesis. Angew Chem Int Ed 2012;51:7640-54.
33. Chen D, Feng H, Li J. Graphene oxide: preparation, functionalization, and electrochemical applications. Chem Rev 2012;112:6027-53.
34. Zhu Y, James DK, Tour JM. New routes to graphene, graphene oxide and their related applications. Adv Mater 2012;24:4924-55.
35. Eda G, Chhowalla M. Chemically derived graphene oxide: towards large-area thin-film electronics and optoelectronics. Adv Mater 2010;22:2392-415.
36. Rao CNR, Sood AK, Subrahmanyam KS, Govindaraj A. Graphene: the new two-dimensional nanomaterial. Angew Chem Int Ed 2009;48:7752-77.
37. Luo J, Kim J, Huang J. Material processing of chemically modified graphene: some challenges and solutions. Acc Chem Res 2013;46:2225-34.
38. Bai S, Shen X. Graphene-inorganic nanocomposites. RSC Adv 2012;2:64-98.
39. Quintana M, Vazquez E, Prato M. Organic functionalization of graphene in dispersions. Acc Chem Res 2013;46:138-48.
40. Wang H, Maiyalagan T, Wang X. Review on recent progress in nitrogen-doped graphene: synthesis, characterization, and its potential applications. ACS Catal 2012;2:781-94.
41. Biro LP, Nemes-Incze P, Lambin P. Graphene: nanoscale processing and recent applications. Nanoscale 2012;4:1824-39.
42. Luo B, Liu S, Zhi L. Chemical approaches toward graphene-based nanomaterials and their applications in energy-related areas. Small 2012;8:630-46.
43. Li C, Shi G. Three-dimensional graphene architectures. Nanoscale 2012;4:5549-63.
44. Bai H, Li C, Shi G. Functional composite materials based on chemically converted graphene. Adv Mater 2011;23:1089-115.
45. Inagaki M, Kim YA, Endo M. Graphene: preparation and structural perfection. J Mater Chem 2011;21:3280-94.
46. Zhang Y, Zhang L, Zhou C. Review of chemical vapor deposition of graphene and related applications. Acc Chem Res 2013;46:2329-39.
47. Kuilla T, Bhadra S, Yao D, Kim NH, Bose S, Lee JH. Recent advances in graphene based polymer composites. Prog Polym Sci 2010;35:1350-75.
48. Terrones M, Botello-Méndez AR, Campos-Delgado J, López-Urías F, Vega-Cantú YI, Rodríguez-Macías FJ, et al. Graphene and graphite nanoribbons: morphology, properties, synthesis, defects and applications. Nano Today 2010;5:351-72.
49. Cai M, Thorpe D, Adamson DH, Schniepp HC. Methods of graphite exfoliation. J Mater Chem 2012;22:24992-5002.
50. Mao S, Pu H, Chen J. Graphene oxide and its reduction: modeling and experimental progress. RSC Adv 2012;2:2643-62.
51. Dreyer DR, Park S, Bielawski CW, Ruoff RS. The chemistry of graphene oxide. Chem Soc Rev 2010;39:228-40.
52. Kim J, Cote LJ, Huang J. Two dimensional soft material: new faces of graphene oxide. Acc Chem Res 2012;45:1356-64.
53. Chu S, Majumdar A. Opportunities and challenges for a sustainable energy future. Nature 2012;288:294-303.
54. 2 capture from ambient air. Proc Natl Acad Sci 2012;109:13156-62.
55. Scott V, Gilfillan S, Markusson N, Chalmers H, Haszeldine RS. Last chance for carbon capture and storage. Nat Clim Change 2013;3:105-11.
56. Eberle U, Muller B, von Helmolt R. Fuel cell electric vehicles and hydrogen infrastructure: status 2012. Energy Environ Sci 2012;5:8780-98.
57. Jena P. Materials for hydrogen storage: past, present, and future. J Phys Chem Lett 2011;2:206-11.
58. Yang J, Sudik A, Wolvertonb C, Siegel DJ. High capacity hydrogen storage materials: attributes for automotive applications and techniques for materials discovery. Chem Soc Rev 2010;39:656-75.
59. Graetz J. New approaches to hydrogen storage. Chem Soc Rev 2009;38:7-82.
60. Sahaym U, Norton MG. Advances in the application of nanotechnology in enabling a 'hydrogen economy'. J Mater Sci 2008;43:5395-429.
61. van den Berg AWC, Arean CO. Materials for hydrogen storage: current research trends and perspectives. Chem Commun 2008:668-81.
62. Felderhoff M, Weidenthaler C, von Helmolt R, Eberle U. Hydrogen storage: the remaining scientific and technological challenges. Phys Chem Chem Phys 2007;9:2643-53.
63. Murray LJ, Dinca M, Long JR. Hydrogen storage in metal-organic frameworks. Chem Soc Rev 2009;38:1294-314.
64. Drage TC, Snape CE, Stevens LA, Wood J, Wang J, Cooper AI, et al. Materials challenges for the development of solid sorbents for post-combustion carbon capture. J Mater Chem 2012;22:2815-23.
65. 2. Energy Environ Sci 2012;5:7281-305.
66. Zhang X, Zhang X, Dong H, Zhao Z, Zhang S, Huang Y. Carbon capture with ionic liquids: overview and progress. Energy Environ Sci 2012;5:6668-81.
67. 2 capture using solid sorbents: a review. Ind Eng Chem Res 2012;51:1438-63.
68. 2 capture by solid adsorbents and their applications: current status and new trends. Energy Environ Sci 2011;4:42-55.
69. 2 adsorption. Chem Eng J 2011;171:760-74.
70. Wang S, Yan S, Ma X, Gong J. Recent advances in capture of carbon dioxide using alkali-metal-based oxides. Energy Environ Sci 2011;4:3805-19.
71. D'Alessandro DM, Smit B, Long JR. Carbon dioxide capture: prospects for new materials. Angew Chem Int Ed 2010;49:6058-82.
72. Choi S, Drese JH, Jones CW. Adsorbent materials for carbon dioxide capture from large anthropogenic point sources. ChemSusChem 2009;2:796-854.
73. Bastos-Neto M, Patzschke C, Lange M, Mollmer J, Moller A, Fichtner S, et al. Assessment of hydrogen storage by physisorption in porous materials. Energy Environ Sci 2012;5:8294-303.
74. Li JR, Sculley J, Zhou HC. Metal-organic frameworks for separations. Chem Rev 2012;112:869-932.
75. Sumida K, Rogow DL, Mason JA, McDonald TM, Bloch ED, Herm ZR, et al. Carbon dioxide capture in metal-organic frameworks. Chem Rev 2012;112:724-81.
76. Dawson R, Cooper AI, Adams DJ. Nanoporous organic polymer networks. Prog Polym Sci 2012;37:530-63.
77. Vilela F, Zhang K, Antonietti M. Conjugated porous polymers for energy applications. Energy Environ Sci 2012;5:7819-32.
78. Feng X, Ding X, Jiang D. Covalent organic frameworks. Chem Soc Rev 2012;41:6010-22.
79. Holst JR, Trewin A, Cooper AI. Porous organic molecules. Nat Chem 2010;2:915-20.
80. Wang L, Yang RT. Hydrogen storage on carbon-based adsorbents and storage at ambient temperature by hydrogen spillover. Cat Rev: Sci Eng 2010;52:411-61.
81. Yurum Y, Taralp A, Veziroglu TN. Storage of hydrogen in nanostructured carbon materials. Int J Hydrogen Energy 2009;34:3784-98.
82. Thomas KM. Adsorption and desorption of hydrogen on metal-organic framework materials for storage applications: comparison with other nanoporous materials. Dalton Trans 2009:1487-505.
83. http://www1.eere.energy.gov/hydrogenandfuelcells/storage/pdfs/targets-onboard-hydro-storage-explanation.pdf.
84. http://www1.eere.energy.gov/cleancities/pdfs/ngvtf11-pfeifer.pdf.
85. http://www.npc.org/FTF-Topic-papers/2Advanced-Storage-Technologies.pdf.
86. Peng Y, Srinivas G, Wilmer CE, Eryazici I, Snurr RQ, Hupp JT, et al. Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111. Chem Commun 2013;49:2992-4.
87. Pumera M. Graphene-based nanomaterials for energy storage. Energy Environ Sci 2011;4:668-74.
88. Lee SY, Park SJ. Comprehensive review on synthesis and adsorption behaviors of graphene-based materials. Carbon Lett 2012;13:73-87.
89. Lu Y, Feng YP. Adsorptions of hydrogen on graphene and other forms of carbon structures: first principle calculations. Nanoscale 2011;3:2444-53.
90. Li JR, Kuppler RJ, Zhou HC. Selective gas adsorption and separation in metal-organic frameworks. Chem Soc Rev 2009;38:1477-504.
91. Yang RT. Adsorbents: fundamentals and applications. Hoboken: John Wiley Sons; 2003.
92. Zuttel A, Sudan P, Mauron P, Wenger P. Model for the hydrogen adsorption on carbon nanostructures. Appl Phys A 2004;78:941-6.
93. Deng WQ, Xu X, Goddard WA. New alkali doped pillared carbon materials designed to achieve practical reversible hydrogen storage for transportation. Phys Rev Lett 2004;92:166103.
94. Patchkovskii S, Tse JS, Yurchenko SN, Zhechkov L, Heine T, Seifert G. Graphene nanostructures as tunable storage media for molecular hydrogen. Proc Natl Acad Sci 2005;102:10439-44.
95. Aga RS, Fu CL, Krčmar M, Morris JR. Theoretical investigation of the effect of graphite interlayer spacing on hydrogen absorption. Phys Rev B 2007;76:165404.
96. Arellano JS, Molina LM, Rubio A, Alonso JA. Density functional study of adsorption of molecular hydrogen on graphene layers. J Chem Phys 2000;112:8114-9.
97. Heine T, Zhechkov L, Seifert G. Hydrogen storage by physisorption on nanostructured graphite platelets. Phys Chem Chem Phys 2004;6:980-4.
98. Peng L, Morris JR. Prediction of hydrogen adsorption properties in expanded graphite model and in nanoporous carbon. J Phys Chem C 2010;114:15522-9.
99. Kuc A, Zhechkov L, Patchkovskii S, Seifert G, Heine T. Hydrogen sieving and storage in fullerene intercalated graphite. Nano Lett 2007;7:1-5.
100. Mpourmpakis G, Tylianakis E, Froudakis GE. Carbon nanoscrolls: a promising material for hydrogen storage. Nano Lett 2007;7:1893-7.
101. 2 storage: cointercalation of graphite with lithium and small organic molecules. Phys Rev B 2008;78:144102.
102. Dimitrakakis GK, Tylianakis E, Froudakis GE. Pillared graphene: a new 3-D network nanostructure for enhanced hydrogen storage. Nano Lett 2008;8:3166-70.
103. Wu CD, Fang TH, Lo JY. Effects of pressure, temperature, and geometric structure of pillared graphene on hydrogen storage capacity. Int J Hydrogen Energy 2012;37:14211-6.
104. Lamari FD, Levesque D. Hydrogen adsorption on functionalized graphene. Carbon 2011;49:5196-200.
105. Kuchta B, Firlej L, Pfeifer P, Wexler C. Numerical estimation of hydrogen storage limits in carbon-based nanospaces. Carbon 2010;48:223-31.
106. Kuchta B, Firlej L, Cepel R, Pfeifer P, Wexler C. Structural and energetic factors in designing a nanoporous sorbent for hydrogen storage. Colloids Surf A: Physicochem Eng Aspects 2010;357:61-6.
107. Burress JW, Gadipelli S, Ford J, Simmons JM, Zhou W, Yildirim T. Graphene oxide framework materials: theoretical predictions and experimental results. Angew Chem Int Ed 2010;49:8902-4.
108. Chan Y, Hill JM. Hydrogen storage inside graphene-oxide frameworks. Nanotechnology 2011;22:305403.
109. Tylianakis E, Psofogiannakis GM, Froudakis GE. Li-doped pillared graphene oxide: a graphene-based nanostructured material for hydrogen storage. J Phys Chem Lett 2010;1:2459-64.
110. Wang L, Lee K, Sun YY, Lucking M, Chen Z, Zhao JJ, et al. Graphene oxide as an ideal substrate for hydrogen storage. ACS Nano 2009;3:2995-3000.
111. Park N, Hong S, Kim G, Jhi SH. Computational study of hydrogen storage characteristics of covalent-bonded graphenes. J Am Chem Soc 2007;129:8999-9003.
112. Kubas J. Metal-dihydrogen and σ-bond coordination: the consummate extension of the Dewar-Chatt-Duncanson model for metal-olefin π bonding. J Organomet Chem 2001;635:37-68.
113. Ding F, Yakobson BI. Challenges in hydrogen adsorptions: from physisorption to chemisorption. Front Phys 2011;6:142-50.
114. Bodrenko IV, Avdeenkov AV, Bessarabov DG, Bibikov AV, Nikolaev AV, Taran MD, et al. Hydrogen storage in aromatic carbon ring based molecular materials decorated with alkali or alkali-earth metals. J Phys Chem C 2012;116:25286-92.
115. Lochan RC, Head-Gordon M. Computational studies of molecular hydrogen binding affinities: the role of dispersion forces, electrostatics, and orbital interactions. Phys Chem Chem Phys 2006;8:1357-70.
116. Kim G, Jhi SH. Effective metal dispersion in pyridinelike nitrogen doped graphenes for hydrogen storage. Appl Phys Lett 2008;92:013106.
117. Jhi SH, Kim G, Park N. First-principles studies of metal-dispersed graphene fragments for hydrogen storage. J Kor Phys Soc 2008;52:1217-20.
118. Liu W, Zhao YH, Nguyen J, Li Y, Jiang Q, Lavernia EJ. Electric field induced reversible switch in hydrogen storage based on single-layer and bilayer graphenes. Carbon 2009;47:3452-60.
119. Ataca C, Aktürk E, Ciraci S, Ustunel H. High-capacity hydrogen storage by metallized graphene. Appl Phys Lett 2008;93:043123.
120. Du A, Zhu Z, Smith SC. Multifunctional porous graphene for nanoelectronics and hydrogen storage: new properties revealed by first principle calculations. J Am Chem Soc 2010;132:2876-7.
121. Durgun E, Ciraci S, Zhou W, Yildirim T. Transition-metal-ethylene complexes as high-capacity hydrogen-storage media. Phys Rev Lett 2006;97:226102.
122. Zhou W, Zhou J, Shen J, Ouyang C, Shi S. First-principles study of high-capacity hydrogen storage on graphene with Li atoms. J Phys Chem Solids 2012;73:245-51.
123. Li J, Wang X, Liu K, Sun Y, Chen L. High hydrogen-storage capacity of B-adsorbed graphene: first-principles calculation. Solid State Commun 2012;152:386-9.
124. Liu Y, Ren L, He Y, Cheng HP. Titanium-decorated graphene for high-capacity hydrogen storage studied by density functional simulations. J Phys: Condens Matter 2010;22:445301.
125. Li S, Zhao HM, Jena P. Ti-doped nano-porous graphene: a material for hydrogen storage and sensor. Front Phys 2011;6:204-8.
126. Zhou M, Lu Y, Zhang C, Feng YP. Strain effects on hydrogen storage capability of metal-decorated graphene: a first-principles study. Appl Phys Lett 2010;97:103109.
127. Tozzini V, Pellegrini V. Reversible hydrogen storage by controlled buckling of graphene layers. J Phys Chem C 2011;115:25523-8.
128. Zhou YG, Zu XT, Gao F, Nie JL, Xiao HY. Adsorption of hydrogen on boron-doped graphene: a first-principles prediction. J Appl Phys 2009;105:014309.
129. Firlej L, Kuchta B, Wexler C, Pfeifer P. Boron substituted graphene: energy landscape for hydrogen adsorption. Adsorption 2009;15:312-7.
130. 2C graphene as potential hydrogen storage medium. Appl Phys Lett 2011;98:173101.
131. Liu CS, Zeng Z. Boron-tuned bonding mechanism of Li-graphene complex for reversible hydrogen storage. Appl Phys Lett 2010;96:123101.
132. Beheshti E, Nojeh A, Servati P. A first-principles study of calcium-decorated, boron-doped graphene for high capacity hydrogen storage. Carbon 2011;49:1561-7.
133. Park HL, Yi SC, Chung YC. Hydrogen adsorption on Li metal in boron-substituted graphene: an ab initio approach. Int J Hydrogen Energy 2010;35:3583-7.
134. Park HL, Chung YC. Hydrogen storage in Al and Ti dispersed on graphene with boron substitution: first-principles calculations. Comput Mater Sci 2010;49:S297-301.
135. Lu R, Rao D, Lu Z, Qian J, Li F, Wu H, et al. Prominently improved hydrogen purification and dispersive metal binding for hydrogen storage by substitutional doping in porous graphene. J Phys Chem C 2012;116:21291-6.
136. Li D, Ouyang Y, Li J, Sun Y, Chen L. Hydrogen storage of beryllium adsorbed on graphene doping with boron: first-principles calculations. Solid State Commun 2012;152:422-5.
137. Cho JH, Yang SJ, Lee K, Park CR. Si-doping effect on the enhanced hydrogen storage of single walled carbon nanotubes and graphene. Int J Hydrogen Energy 2011;36:12286-95.
138. Ataca C, Aktürk E, Ciraci S. Hydrogen storage of calcium atoms adsorbed on graphene: first-principles plane wave calculations. Phys Rev B 2009;79:041406(R).
139. Yang X, Zhang RQ, Ni J. Stable calcium adsorbates on carbon nanostructures: applications for high-capacity hydrogen storage. Phys Rev B 2009;79:075431.
140. Kim G, Jhi SH, Lim S, Park N. Crossover between multipole Coulomb and Kubas interactions in hydrogen adsorption on metal-graphene complexes. Phys Rev B 2009;79:155437.
141. Wang V, Mizuseki H, He HP, Chen G, Zhang SL, Kawazoe Y. Calcium-decorated graphene for hydrogen storage: a van der Waals density functional study. Comput Mater Sci 2012;55:180-5.
142. Reunchan P, Jhi SH. Metal-dispersed porous graphene for hydrogen storage. Appl Phys Lett 2011;98:093103.
143. Lee H, Ihm J, Cohen ML, Louie SG. Calcium-decorated graphene-based nanostructures for hydrogen storage. Nano Lett 2010;10:793-8.
144. Kim G, Jhi SH. Ca-decorated graphene-based three-dimensional structures for high-capacity hydrogen storage. J Phys Chem C 2009;113:20499-503.
145. Chen C, Zhang J, Zhang B, Duan HM. Hydrogen adsorption of Mg-doped graphene oxide: a first-principles study. J Phys Chem C 2013;117:4337-44.
146. Ao ZM, Jiang Q, Zhang RQ, Tan TT, Li S. Al doped graphene: a promising material for hydrogen storage at room temperature. J Appl Phys 2009;105:074307.
147. Ao ZM, Peeters FM. High-capacity hydrogen storage in Al-adsorbed graphene. Phys Rev B 2010;81:205406.
148. 2 storage capacity of graphene at nanoribbon borders but not at central sites: a study using nonlocal van derWaals density functionals. Phys Rev B 2012;85:125435.
149. Durgun E, Ciraci S, Yildirim T. Functionalization of carbon-based nanostructures with light transition-metal atoms for hydrogen storage. Phys Rev B 2008;77:085405.
150. Wu M, Gao Y, Zhang Z, Zeng XC. Edge-decorated graphene nanoribbons by scandium as hydrogen storage media. Nanoscale 2012;4:915-20.
151. Sigal A, Rojas MI, Leiva EPM. Interferents for hydrogen storage on a graphene sheet decorated with nickel: a DFT study. Int J Hydrogen Energy 2011;36:3537-46.
152. Hussain T, Pathak B, Ramzan M, Maark TA, Ahuja R. Calcium doped graphane as a hydrogen storage material. Appl Phys Lett 2012;100:183902.
153. Sluiter MHF, Kawazoe Y. Cluster expansion method for adsorption: application to hydrogen chemisorption on graphene. Phys Rev B 2003;68:085410.
154. Antipina LY, Avramov PV, Sakai S, Naramoto H, Ohtomo M, Entani S, et al. High hydrogen-adsorption-rate material based on graphane decorated with alkali metals. Phys Rev B 2012;86:085435.
155. Hussain T, Pathak B, Maark TA, Araujo CM, Scheicher RH, Ahuja R. Ab initio study of lithium-doped graphane for hydrogen storage. EPL 2011;96:27013.
156. Hussain T, Sarkar AD, Ahuja R. Strain induced lithium functionalized graphane as a high capacity hydrogen storage material. Appl Phys Lett 2012;101:103907.
157. 2 on graphene. J Appl Phys 2003;93:3395-400.
158. 2 molecules on steric graphene surface: ab initio MD study based on DFT. Comput Theor Chem 2012;994:54-64.
159. + ions on graphene electrode as hydrogen storage reservoirs. Comput Mater Sci 2011;50:3257-64.
160. Wu HY, Fan X, Kuo JL, Deng WQ. DFT study of hydrogen storage by spillover on graphene with boron substitution. J Phys Chem C 2011;115:9241-9.
161. Han SS, Jung H, Jung DH, Choi SH, Park N. Stability of hydrogenation states of graphene and conditions for hydrogen spillover. Phys Rev B 2012;85:155408.
162. Psofogiannakis George M, Froudakis George E. Fundamental studies and perceptions on the spillover mechanism for hydrogen storage. Chem Commun 2011;47:7933-43.
163. Cabria I, Lopez MJ, Fraile S, Alonso JA. Adsorption and dissociation of molecular hydrogen on palladium clusters supported on graphene. J Phys Chem C 2012;116:21179-89.
164. Lopez-Corral I, German E, Volpe MA, Brizuela GP, Juan A. Tight-binding study of hydrogen adsorption on palladium decorated graphene and carbon nanotubes. Int J Hydrogen Energy 2010;35:2377-84.
165. Kayanuma M, Nagashima U, Nishihara H, Kyotani T, Ogawa H. Adsorption and diffusion of atomic hydrogen on a curved surface of microporous carbon: a theoretical study. Chem Phys Lett 2010;495:251-5.
166. Rangel E, Ramirez-Arellano JM, Carrillo I, Magana LF. Hydrogen adsorption around lithium atoms anchored on graphene vacancies. Int J Hydrogen Energy 2011;36:13657-62.
167. Lueking AD, Psofogiannakis G, Froudakis GE. Atomic hydrogen diffusion on doped and chemically modified graphene. J Phys Chem C 2013;117:6312-9.
168. Ao ZM, Peeters FM. Electric field activated hydrogen dissociative adsorption to nitrogen-doped graphene. J Phys Chem C 2010;114:14503-9.
169. Ao ZM, Hernandez-Nieves AD, Peeters FM, Li S. The electric field as a novel switch for uptake/release of hydrogen for storage in nitrogen doped graphene. Phys Chem Chem Phys 2012;14:1463-7.
170. 2 storage capacities. Adsor Sci Technol 2009;27:281-96.
171. Chen JJ, Li WW, Li XL, Yu HQ. Improving biogas separation and methane storage with multilayer graphene nanostructure via layer spacing optimization and lithium doping: a molecular simulation investigation. Environ Sci Technol 2012;46:10341-8.
172. Carrillo I, Rangel E, Magana LF. Adsorption of carbon dioxide and methane on graphene with a high titanium coverage. Carbon 2009;47:2752-60.
173. Wang L, Zhao J, Wang L, Yan T, Sun YY, Zhang SB. Titanium-decorated graphene oxide for carbon monoxide capture and separation. Phys Chem Chem Phys 2011;13:21126-31.
174. 2 adsorption on carbon models of organic constituents of gas shale and coal. Environ Sci Technol 2011;45:809-14.
175. 2 on defective graphene sheets. J Phys Chem A 2009;113:493-8.
176. Shayeganfar F, Neek-Amal M. Methane molecule over the defected and rippled graphene sheet. Solid State Commun 2012;152:1493-6.
177. Thierfelder C, Witte M, Blankenburg S, Rauls E, Schmidt WG. Methane adsorption on graphene from first principles including dispersion interaction. Surf Sci 2011;605:746-9.
178. 2 capture: a first-principles computational study. J Phys Chem C 2011;115:10990-5.
179. Ohba T, Kanoh H. Intensive edge effects of nanographenes in molecular adsorptions. J Phys Chem Lett 2012;3:511-6.
180. Wood BC, Bhide SY, Dutta D, Kandagal VS, Pathak AD, Punnathanam SN, et al. Methane and carbon dioxide adsorption on edge-functionalized graphene: a comparative DFT study. J Chem Phys 2012;137:054702.
181. Kandagal VS, Pathak A, Ayappa KG, Punnathanam SN. Adsorption on edge-functionalized bilayer graphene nanoribbons: assessing the role of functional groups in methane uptake. J Phys Chem C 2012;116:23394-403.
182. Katsnelson MI, Fasolino A. Graphene as a prototype crystalline membrane. Acc Chem Res 2013;46:97-105.
183. Leenaerts O, Partoens B, Peeters FM. Graphene: a perfect nanoballoon. Appl Phys Lett 2008;93:193107.
184. Miao M, Nardelli MB, Wang Q, Liu Y. First principles study of the permeability of graphene to hydrogen atoms. Phys Chem Chem Phys 2013;15:16132-7.
185. Tsetseris L, Pantelides ST. Graphene: an impermeable or selectively permeable membrane for atomic species? Carbon 2014;67:58-63.
186. Jiang D, Cooper VR, Dai S. Porous graphene as the ultimate membrane for gas separation. Nano Lett 2009;9:4019-24.
187. 2 separation through nanoporous graphene from molecular dynamics. Nanoscale 2013;5:9984-7.
188. Li Y, Zhou Z, Shen P, Chen Z. Two-dimensional polyphenylene: experimentally available porous graphene as a hydrogen purification membrane. Chem Commun 2010;46:3672-4.
189. Blankenburg S, Bieri M, Fasel R, Müllen K, Pignedoli CA, Passerone D. Porous graphene as an atmospheric nanofilter. Small 2010;6:2266-71.
190. Qin X, Meng Q, Feng Y, Gao Y. Graphene with line defect as a membrane for gas separation: design via a first-principles modelling. Surf Sci 2013;607:153-8.
191. Du H, Li J, Zhang J, Su G, Li X, Zhao Y. Separation of hydrogen and nitrogen gases with porous graphene membrane. J Phys Chem C 2011;115:23261-6.
192. Drahushuk LW, Strano MS. Mechanisms of gas permeation through single layer graphene membranes. Langmuir 2012;28:16671-8.
193. Tao Y, Xue Q, Liu Z, Shan M, Ling C, Wu T, et al. Tunable hydrogen separation in porous graphene membrane: first-principle and molecular dynamic simulation. ACS Appl Mater Interf 2014;6:8048-58.
194. Hauser AW, Schwerdtfeger P. Methane-selective nanoporous graphene membranes for gas purification. Phys Chem Chem Phys 2012;14:13292-8.
195. 2 separation performance of porous graphene membranes. Nanoscale 2012;4:5477-82.
196. Schrier J. Fluorinated and nanoporous graphene materials as sorbents for gas separations. ACS Appl Mater Interf 2011;3:4451-8.
197. Jungthawan S, Reunchan P, Limpijumnong S. Theoretical study of strained porous graphene structures and their gas separation properties. Carbon 2013;54:359-64.
198. Brunauer S, Emmett PH, Teller E. Adsorption of gases in multimolecular layers. J Am Chem Soc 1938;60:309-19.
199. Ma LP, Wu ZS, Li J, Wu ED, Ren WC, Cheng HM. Hydrogen adsorption behavior of graphene above critical temperature. Int J Hydrogen Energy 2009;34:2329-32.
200. Zheng Q, Ji X, Gao S, Wang X. Analysis of adsorption equilibrium of hydrogen on graphene sheets. Int J Hydrogen Energy 2013;38:10896-902.
201. Srinivas G, Zhu Y, Piner R, Skipper N, Ellerby M, Ruoff R. Synthesis of graphene-like nanosheets and their hydrogen adsorption capacity. Carbon 2010;48:630-5.
202. Wang Y, Guan C, Wang K, Guo CX, Li CM. Nitrogen, hydrogen, carbon dioxide, and water vapor sorption properties of three-dimensional graphene. J Chem Eng Data 2011;56:642-5.
203. Yuan W, Li B, Li L. A green synthetic approach to graphene nanosheets for hydrogen adsorption. Appl Surf Sci 2011;257:10183-7.
204. Lee SY, Park SJ. Isothermal exfoliation of graphene oxide by a new carbon dioxide pressure swing method. Carbon 2014;68:112-7.
205. Cunning BV, Pyle DS, Merritt CR, Brown CL, Webb CJ, Gray EM. Hydrogen adsorption characteristics of magnesium combustion derived graphene at 77 and 293 K. Int J Hydrogen Energy 2014;39:6783-8.
206. 2 by graphene. J Phys Chem C 2008;112:15704-7.
207. Subrahmanyam KS, Vivekchand SRC, Govindaraj A, Rao CNR. A study of graphenes prepared by different methods: characterization, properties and solubilisation. J Mater Chem 2008;18:1517-23.
208. Guo CX, Wang Y, Li CM. Hierarchical graphene-based material for over 4.0 wt.% physisorption hydrogen storage capacity. ACS Sustain Chem Eng 2013;1:14-8.
209. 2O. J Am Chem Soc 2011;133:14880-3.
210. Mishra AK, Ramaprabhu S. Carbon dioxide adsorption in graphene sheets. AIP Adv 2011;1:032152.
211. Meng LY, Park SJ. Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates. J Colloid Interface Sci 2012;386:285-90.
212. 2 capture. Appl Surf Sci 2012;258:4301-7.
213. 2 capture. J Mater Chem 2012;22:3708-12.
214. Enoki T, Suzuki M, Endo M. Graphite intercalation compounds and applications. Oxford: Oxford University Press; 2003.
215. 2 and graphite. J Solid State Chem 2011;184:1561-5.
216. 6. J Mater Chem 2009;19:5239-43.
217. Srinivas G, Lovell A, Howard CA, Skipper NT, Ellerby M, Bennington SM. Structure and phase stability of hydrogenated first-stage alkali- and alkaline-earth metal-graphite intercalation compounds. Synth Met 2010;160:1631-5.
218. Purewal JJ, Keith JB, Ahn CC, Fultz B, Brown CM, Tyagi M. Adsorption and melting of hydrogen in potassium-intercalated graphite. Phys Rev B 2009;79:054305.
219. Lovell A, Fernandez-Alonso F, Skipper NT, Refson K, Bennington SM, Parker SF. Quantum delocalization of molecular hydrogen in alkali-graphite intercalates. Phys Rev Lett 2008;101:126101.
220. Lueking AD, Pan L, Narayanan DL, Clifford CEB. Effect of expanded graphite lattice in exfoliated graphite nanofibers on hydrogen storage. J Phys Chem B 2005;109:12710-7.
221. 2 uptake using pillared-graphene oxide. Int J Hydrogen Energy 2012;37:14217-22.
222. Kim BH, Hong WG, Yu HY, Han YK, Lee SM, Chang SJ, et al. Thermally modulated multilayered graphene oxide for hydrogen storage. Phys Chem Chem Phys 2012;14:1480-5.
223. Hong WG, Kim BH, Lee SM, Yu HY, Yun YJ, Jun Y, et al. Agent-free synthesis of graphene oxide/transition metal oxide composites and its application for hydrogen storage. Int J Hydrogen Energy 2012;37:7594-9.
224. Ding Z, Qing L, Yi CQ, Chao ZY, Yi C, Tao W, et al. Graphene-manganese oxide hybrid porous material and its application in carbon dioxide adsorption. Chin Sci Bull 2012;57:3059-64.
225. Zhou D, Zhang TL, Han BH. One-step solvothermal synthesis of an iron oxide-graphene magnetic hybrid material with high porosity. Microporous Mesoporous Mater 2013;165:234-9.
226. Zhou D, Han BH. Graphene-based nanoporous materials assembled by mediation of polyoxometalate nanoparticles. Adv Funct Mater 2010;20:2717-22.
227. Srinivas G, Burress JW, Ford J, Yildirim T. Porous graphene oxide frameworks: synthesis and gas sorption properties. J Mater Chem 2011;21:11323-9.
228. Severin K. Boronic acids as building blocks for molecular nanostructures and polymeric materials. Dalton Trans 2009:5254-64.
229. Jin Z, Lu W, O'Neill KJ, Parilla PA, Simpson LJ, Kittrell C, et al. Nano-engineered spacing in graphene sheets for hydrogen storage. Chem Mater 2011;23:923-5.
230. Zhou D, Cheng QY, Cui Y, Wang T, Li X, Han BH. Graphene-terpyridine complex hybrid porous material for carbon dioxide adsorption. Carbon 2014;66:592-8.
231. 2 capture. RSC Adv 2013;3:16011-20.
232. 2 adsorption. Chem Commun 2014;50:10967-70.
233. Matsuo Y, Ueda S, Konishi K, Marco-Lozar JP, Lozano-Castello D, Cazorla-Amoros D. Pillared carbons consisting of silsesquioxane bridged graphene layers for hydrogen storage materials. Int J Hydrogen Energy 2012;37:10702-8.
234. Aboutalebi SH, Aminorroaya-Yamini S, Nevirkovets I, Konstantinov K, Liu HK. Enhanced hydrogen storage in graphene oxide-MWCNTs composite at room temperature. Adv Energy Mater 2012;2:1439-46.
235. Ruiz-García C, Pérez-Carvajal J, Berenguer-Murcia A, Darder M, Aranda P, Cazorla-Amorós D, et al. Clay-supported graphene materials: application to hydrogen storage. Phys Chem Chem Phys 2013;15:18635-41.
236. Ruiz-García C, Jiménez R, Pérez-Carvajal J, Berenguer-Murcia A, Darder M, Aranda P, et al. Graphene-clay based nanomaterials for clean energy storage. Sci Adv Mater 2014;6:151-8.
237. Petit C, Burress J, Bandosz TJ. The synthesis and characterization of copper-based metal-organic framework/graphite oxide composites. Carbon 2011;49:563-72.
238. Liu S, Sun L, Xu F, Zhang J, Jiao C, Li F, et al. Nanosized Cu-MOFs induced by graphene oxide and enhanced gas storage capacity. Energy Environ Sci 2013;6:818-23.
239. 4. Ind Eng Chem Res 2014;53:11176-84.
240. 2 sequestration. RSC Adv 2013;3:9932-41.
241. 2 capture. Adv Mater 2013;25:2130-4.
242. Sui ZY, Cui Y, Zhu JH, Han BH. Preparation of three-dimensional graphene oxide-polyethylenimine porous materials as dye and gas adsorbents. ACS Appl Mater Interf 2013;5:9172-9.
243. Prins R. Hydrogen spillover: facts and fiction. Chem Rev 2012;112:2714-38.
244. Hu ZL, Aizawa M, Wang ZM, Yoshizawa N, Hatori H. Synthesis and characteristics of graphene oxide-derived carbon nanosheet-Pd nanosized particle composites. Langmuir 2010;26:6681-8.
245. 2 alloys. J Phys: Condens Matter 2008;20:255224.
246. 2-hydrides. J Phys D: Appl Phys 2007;40:1183-9.
247. Huang CC, Pu NW, Wang CA, Huang JC, Sung Y, Ger MD. Hydrogen storage in graphene decorated with Pd and Pt nanoparticles using an electroless deposition technique. Sep Purif Technol 2011;82:210-5.
248. Chen CH, Chung TY, Shen CC, Yu MS, Tsao CS, Shi GN, et al. Hydrogen storage performance in palladium-doped graphene/carbon composites. Int J Hydrogen Energy 2013;38:3681-8.
249. Parambhath VB, Nagar R, Sethupathi K, Ramaprabhu S. Investigation of spillover mechanism in palladium decorated hydrogen exfoliated functionalized graphene. J Phys Chem C 2011;115:15679-85.
250. Parambhath VB, Nagar R, Ramaprabhu S. Effect of nitrogen doping on hydrogen storage capacity of palladium decorated graphene. Langmuir 2012;28:7826-33.
251. Vinayan BP, Sethupathi K, Ramaprabhu S. Facile synthesis of triangular shaped palladium nanoparticles decorated nitrogen doped graphene and their catalytic study for renewable energy applications. Int J Hydrogen Energy 2013;38:2240-50.
252. Vinayan BP, Nagar R, Ramaprabhu S. Solar light assisted green synthesis of palladium nanoparticle decorated nitrogen doped graphene for hydrogen storage application. J Mater Chem A 2013;1:11192-9.
253. Wang Y, Liu J, Wang K, Chen T, Tan X, Li CM. Hydrogen storage in NiB nanoalloy-doped 2D graphene. Int J Hydrogen Energy 2011;36:12950-4.
254. Wang Y, Guo CX, Wang X, Guan C, Yang H, Wang K, et al. Hydrogen storage in a Ni-B nanoalloy-doped three-dimensional graphene material. Energy Environ Sci 2011;4:195-200.
255. Bourlinos AB, Steriotis TA, Karakassides M, Sanakis Y, Tzitzios V, Trapalis C, et al. Synthesis, characterization and gas sorption properties of a molecularly-derived graphite oxide-like foam. Carbon 2007;45:852-7.
256. Psofogiannakis GM, Steriotis TA, Bourlinos AB, Kouvelos EP, Charalambopoulou GC, Stubos AK, et al. Enhanced hydrogen storage by spillover on metal-doped carbon foam: an experimental and computational study. Nanoscale 2011;3:933-6.
257. Wang L, Yang FH, Yang RT, Miller MA. Effect of surface oxygen groups in carbons on hydrogen storage by spillover. Ind Eng Chem Res 2009;48:2920-6.
258. Wu HC, Li YY, Sakoda A. Synthesis and hydrogen storage capacity of exfoliated turbostratic carbon nanofibers. Int J Hydrogen Energy 2010;35:4123-30.
259. Choucair M, Thordarson P, Stride JA. Gram-scale production of graphene based on solvothermal synthesis and sonication. Nat Nanotechnol 2009;4:30-3.
260. Deng D, Pan X, Yu L, Cui Y, Jiang Y, Qi J, et al. Toward N-doped graphene via solvothermal synthesis. Chem Mater 2011;23:1188-93.
261. Wang L, Stuckert NR, Yang RT. Unique hydrogen adsorption properties of graphene. AIChE 2011;57:2902-8.
262. Jin Z, Sun Z, Simpson LJ, O'Neill KJ, Parilla PA, Li Y, et al. Solution-phase synthesis of heteroatom-substituted carbon scaffolds for hydrogen storage. J Am Chem Soc 2010;132:15246-51.
263. Srinivas G, Burress J, Yildirim T. Graphene oxide derived carbons (GODCs): synthesis and gas adsorption properties. Energy Environ Sci 2012;5:6453-9.
264. 2 capture on N-doped carbon produced by chemical activation of polypyrrole functionalized graphene sheets. Chem Commun 2012;48:735-7.
265. 2 adsorption by an activated nitrogen doped graphene/polyaniline material. Nanotechnology 2013;24:235703.
266. 2 capture by S-doped microporous carbon materials. Carbon 2014;66:320-6.
267. Ning G, Xu C, Mu L, Chen G, Wang G, Gao J, et al. High capacity gas storage in corrugated porous graphene with a specific surface area-lossless tightly stacking manner. Chem Commun 2012;48:6815-7.
268. Guo GF, Huang H, Xue FH, Liu CJ, Yu HT, Quan X, et al. Electrochemical hydrogen storage of the graphene sheets prepared by DC arc-discharge method. Surf Coat Technol 2013;228:S120-5.
269. Chen Y, Wang Q, Zhu C, Gao P, Ouyang Q, Wang T, et al. Graphene/porous cobalt nanocomposite and its noticeable electrochemical hydrogen storage ability at room temperature. J Mater Chem 2012;22:5924-7.
270. 3C nanoparticles with high hydrogen storage ability. Int J Hydrogen Energy 2012;37:17126-30.
271. Subrahmanyam KS, Kumar P, Maitra U, Govindaraj A, Hembram KPSS, Waghmare UV, et al. Chemical storage of hydrogen in few-layer graphene. Proc Natl Acad Sci 2011;108:2674-7.
272. Pekker S, Salvetat JP, Jakab E, Bonard JM, Forro L. Hydrogenation of carbon nanotubes and graphite in liquid ammonia. J Phys Chem B 2001;105:7938-43.
273. Yang Z, Sun Y, Alemany LB, Narayanan TN, Billups WE. Birch reduction of graphite. Edge and interior functionalization by hydrogen. J Am Chem Soc 2012;134:18689-94.
274. Elias DC, Nair RR, Mohiuddin TMG, Morozov SV, Blake P, Halsall MP, et al. Control of graphene's properties by reversible hydrogenation: evidence of graphane. Science 2009;323:610-3.
275. Krishna R, Titus E, Costa LC, Menezes JCJMDS, Correia MRP, Pinto S, et al. Facile synthesis of hydrogenated reduced graphene oxide via hydrogen spillover mechanism. J Mater Chem 2012;22:10457-9.
276. Poh HL, Sanek F, Sofer Z, Pumera M. High-pressure hydrogenation of graphene: towards graphane. Nanoscale 2012;4:7006-11.
277. Johns JE, Hersam MC. Atomic covalent functionalization of graphene. Acc Chem Res 2013;46:77-86.
278. Chen DM, Ichikawa T, Fujii H, Ogita N, Udagawa M, Kitano Y, et al. Unusual hydrogen absorption properties in graphite mechanically milled under various hydrogen pressures up to 6 MPa. J Alloys Compd 2003;354:L5-9.
279. Orimo S, Matsushima T, Fujii H, Fukunaga T, Majer G. Hydrogen desorption property of mechanically prepared nanostructured graphite. J Appl Phys 2001;90:1545-9.
280. Orimo S, Majer G, Fukunaga T, Zuttel A, Schlapbach L, Fujii H. Hydrogen in the mechanically prepared nanostructured graphite. Appl Phys Lett 1999;75:3093-5.
281. Jeon I-Y, Choi H-J, Jung S-M, Seo J-M, Kim M-J, Dai L, et al. Large-scale production of edge-selectively functionalized graphene nanoplatelets via ball milling and their use as metal-free electrocatalysts for oxygen reduction reaction. J Am Chem Soc 2013;135:1386-93.
282. Bunch JS, Verbridge SS, Alden JS, van der Zande AM, Parpia JM, Craighead HG, et al. Impermeable atomic membranes from graphene sheets. Nano Lett 2008;8:2458-62.
283. Koenig SP, Wang L, Pellegrino J, Bunch JS. Selective molecular sieving through porous graphene. Nat Nanotechnol 2012;7:728-32.
284. Nair RR, Wu HA, Jayaram PN, Grigorieva IV, Geim AK. Unimpeded permeation of water through helium-leak-tight graphene-based membranes. Science 2012;335:442-4.
285. O'Hern SC, Stewart CA, Boutilier MSH, Idrobo JC, Bhaviripudi S, Das SK, et al. Selective molecular transport through intrinsic defects in a single layer of CVD graphene. ACS Nano 2012;6:10130-8.
286. Cohen-Tanugi D, Grossman JC. Water desalination across nanoporous graphene. Nano Lett 2012;12:3602-8.
287. Sutter E, Albrecht P, Camino FE, Sutter P. Monolayer graphene as ultimate chemical passivation layer for arbitrarily shaped metal surfaces. Carbon 2010;48:4414-20.
288. Chen S, Brown L, Levendorf M, Cai W, Ju SY, Edgeworth J, et al. Oxidation resistance of graphene-coated Cu and Cu/Ni alloy. ACS Nano 2011;5:1321-7.
289. Gadipelli S, Calizo I, Ford J, Cheng G, Walker ARH, Yildirim T. A highly practical route for large-area, single layer graphene from liquid carbon sources such as benzene and methanol. J Mater Chem 2011;21:16057-65.
290. Kang D, Kwon JY, Cho H, Sim JH, Hwang HS, Kim CS, et al. Oxidation resistance of iron and copper foils coated with reduced graphene oxide multilayers. ACS Nano 2012;6:7763-9.
291. Nilsson L, Andersen M, Balog R, Lægsgaard E, Hofmann P, Besenbacher F, et al. Graphene coatings: probing the limits of the one atom thick protection layer. ACS Nano 2012;6:10258-66.
292. Kim H, Macosko CW. Morphology and properties of polyester/exfoliated graphite nanocomposites. Macromolecules 2008;41:3317-27.
293. Kim H, Miura Y, Macosko CW. Graphene/polyurethane nanocomposites for improved gas barrier and electrical conductivity. Chem Mater 2010;22:3441-50.
294. Liu H, Kuila T, Kim NH, Ku BC, Lee JH. In situ synthesis of the reduced graphene oxide-polyethyleneimine composite and its gas barrier properties. J Mater Chem A 2013;1:3739-46.
295. Yang Y-H, Bolling L, Priolo MA, Grunlan JC. Super gas barrier and selectivity of graphene oxide-polymer multilayer thin films. Adv Mater 2013;25:503-8.
296. Yang J, Bai L, Feng G, Yang X, Lv M, Zhang C, et al. Thermal reduced graphene based poly(ethylene vinyl alcohol) nanocomposites: enhanced mechanical properties, gas barrier, water resistance, and thermal stability. Ind Eng Chem Res 2013;52:16745-54.
297. Kim HW, Yoon HW, Yoon SM, Yoo BM, Ahn BK, Cho YH, et al. Selective gas transport through few-layered graphene and graphene oxide membranes. Science 2013;342:91-5.
298. Li H, Song Z, Zhang X, Huang Y, Li S, Mao Y, et al. Ultrathin, molecular-sieving graphene oxide membranes for selective hydrogen separation. Science 2013;342:95-8.
299. Tang S, Cao Z. Adsorption of nitrogen oxides on graphene and graphene oxides: insights from density functional calculations. J Chem Phys 2011;134:044710.
300. Tang S, Cao Z. Adsorption and dissociation of ammonia on graphene oxides: a first-principles study. J Phys Chem C 2012;116:8778-91.
301. 2S adsorption: a first-principles study. Appl Surf Sci 2012;261:697-704.
302. 2) on light metal decorated graphene oxide. Phys Chem Chem Phys 2014;16:11031-6.
303. Slabaugh WH, Seiler BC. Interactions of ammonia with graphite oxide. J Phys Chem 1962;66:396-401.
304. Nguyen-Thanh D, Block K, Bandosz TJ. Adsorption of hydrogen sulfide on montmorillonites modified with iron. Chemosphere 2005;59:343-53.
305. Petit C, Seredych M, Bandosz TJ. Revisiting the chemistry of graphite oxides and its effect on ammonia adsorption. J Mater Chem 2009;19:9176-85.
306. Seredych M, Petit C, Tamashausky AV, Bandosz TJ. Role of graphite precursor in the performance of graphite oxides as ammonia adsorbents. Carbon 2009;47:445-56.
307. Seredych M, Bandosz TJ. Combined role of water and surface chemistry in reactive adsorption of ammonia on graphite oxides. Langmuir 2010;26:5491-8.
308. Seredych M, Rossin JA, Bandosz TJ. Changes in graphite oxide texture and chemistry upon oxidation and reduction and their effect on adsorption of ammonia. Carbon 2011;49:4392-402.
309. Bandosz TJ. Towards understanding reactive adsorption of small molecule toxic gases on carbonaceous materials. Cat Today 2012;186:20-8.
310. Seredych M, Bandosz TJ. Graphite oxide/AlZr polycation composites: surface characterization and performance as adsorbents of ammonia. Mater Chem Phys 2009;117:99-106.
311. Petit C, Bandosz TJ. Graphite oxide/polyoxometalate nanocomposites as adsorbents of ammonia. J Phys Chem C 2009;113:3800-9.
312. Seredych M, Tamashausky AV, Bandosz TJ. Surface features of exfoliated graphite/bentonite composites and their importance for ammonia adsorption. Carbon 2008;46:1241-52.
313. 2 composites as reactive adsorbents of ammonia at ambient conditions. Microporous Mesoporous Mater 2012;150:55-63.
314. Seredych M, Bandosz TJ. Adsorption of hydrogen sulfide on graphite derived materials modified by incorporation of nitrogen. Mater Chem Phys 2009;113:946-52.
315. 2 with zinc (hydr)oxide/graphene phase composites: visible light enhanced surface reactivity. J Phys Chem C 2012;116:2527-35.
316. Seredych M, Mabayoje O, Bandosz TJ. Visible-light-enhanced interactions of hydrogen sulfide with composites of zinc (oxy)hydroxide with graphite oxide and graphene. Langmuir 2012;28:1337-46.
317. 4 composites. J Phys Chem C 2010;114:14552-60.
318. 4 composites. Chem Eng J 2011;166:1032-8.
319. Mabayoje O, Seredych M, Bandosz TJ. Cobalt (hydr)oxide/graphite oxide composites: importance of surface chemical heterogeneity for reactive adsorption of hydrogen sulphide. J Colloid Interface Sci 2012;378:1-9.
320. Mabayoje O, Seredych M, Bandosz TJ. Enhanced reactive adsorption of hydrogen sulfide on the composites of graphene/graphite oxide with copper (hydr)oxychlorides. ACS Appl Mater Interf 2012;4:3316-24.
321. 2 on graphite oxide/iron composites. Ind Eng Chem Res 2009;48:10884-91.
322. 2 reduction on GO-PANI composites. Ind Eng Chem Res 2007;46:6925-35.
323. Petit C, Bandosz TJ. Exploring the coordination chemistry of MOF-graphite oxide composites and their applications as adsorbents. Dalton Trans 2012;41:4027-35.
324. Petit C, Bandosz TJ. Synthesis, characterization, and ammonia adsorption properties of mesoporous metal-organic framework (MIL(Fe))-graphite oxide composites: exploring the limits of materials fabrication. Adv Funct Mater 2011;21:2108-17.
325. Petit C, Wrabetz S, Bandosz TJ. Microcalorimetric insight into the analysis of the reactive adsorption of ammonia on Cu-MOF and its composite with graphite oxide. J Mater Chem 2012;22:21443-7.
326. Petit C, Levasseur B, Mendoza B, Bandosz TJ. Reactive adsorption of acidic gases on MOF/graphite oxide composites. Microporous Mesoporous Mater 2012;154:107-12.
327. Bandosz TJ, Petit C. MOF/graphite oxide hybrid materials: exploring the new concept of adsorbents and catalysts. Adsorption 2011;17:5-16.
328. Morishige K, Hamada T. Iron oxide pillared graphite. Langmuir 2005;21:6277-81.
329. Huang ZH, Liu G, Kang F. Glucose-promoted Zn-based metal-organic framework/graphene oxide composites for hydrogen sulfide removal. ACS Appl Mater Interf 2012;4:4942-7.
330. 3 catalyzed by graphene oxide foams. J Mater Chem 2011;21:13934-41.
331. Nijkamp MG, Raaymakers JEMJ, van Dillen AJ, de Jong KP. Hydrogen storage using physisorption-materials demands. Appl Phys A 2001;72:619-23.
332. Zhao W, Fierro V, Zlotea C, Aylon E, Izquierdo MT, Latroche M, et al. Activated carbons with appropriate micropore size distribution for hydrogen adsorption. Int J Hydrogen Energy 2011;36:5431-4.
333. Texier-Mandoki N, Dentzer J, Piquero T, Saadallah S, David P, Vix-Guterl C. Hydrogen storage in activated carbon materials: role of the nanoporous texture. Carbon 2004;42:2744-7.
334. Liu F, Seo TS. A controllable self-assembly method for large-scale synthesis of graphene sponges and free-standing graphene films. Adv Funct Mater 2010;20:1930-6.
335. Niu Z, Chen J, Hng HH, Ma J, Chen X. A leavening strategy to prepare reduced graphene oxide foams. Adv Mater 2012;24:4144-50.
336. 2-cross-linked three-dimensional graphene monoliths. J Phys Chem Lett 2011;2:921-5.
337. Worsley MA, Kucheyev SO, Mason HE, Merrill MD, Mayer BP, Lewicki J, et al. Mechanically robust 3D graphene macroassembly with high surface area. Chem Commun 2012;48:8428-30.
338. Zhang K, Ang BT, Zhang LL, Zhao XS, Wu J. Pyrolyzed graphene oxide/resorcinol-formaldehyde resin composites as high-performance supercapacitor electrodes. J Mater Chem 2011;21:2663-70.
339. Biener J, Dasgupta S, Shao L, Wang D, Worsley MA, Wittstock A, et al. Macroscopic 3D nanographene with dynamically tunable bulk properties. Adv Mater 2012;24:5083-7.
340. Lei Z, Christov N, Zhao XS. Intercalation of mesoporous carbon spheres between reduced graphene oxide sheets for preparing high-rate supercapacitor electrodes. Energy Environ Sci 2011;4:1866-73.
341. Huang X, Qian K, Yang J, Zhang J, Li L, Yu C, et al. Functional nanoporous graphene foams with controlled pore sizes. Adv Mater 2012;24:4419-23.
342. 2 carbon materials and their impact on the capacitance performance of these materials. J Am Chem Soc 2013;135:5921-9.
343. Guardia L, Suárez-García F, Paredes JI, Solís-Fernández P, Rozada R, Fernández-Merino MJ, et al. Synthesis and characterization of graphene-mesoporous silica nanoparticle hybrids. Microporous Mesoporous Mater 2012;160:18-24.
344. Yang S, Zhi L, Tang K, Feng X, Maier J, Müllen K. Efficient synthesis of heteroatom (N or S)-doped graphene based on ultrathin graphene oxide-porous silica sheets for oxygen reduction reactions. Adv Funct Mater 2012;22:3634-40.
345. Yavari F, Chen Z, Thomas AV, Ren W, Cheng HM, Koratkar N. High sensitivity gas detection using a macroscopic three-dimensional graphene foam network. Sci Rep 2011;1:166.
346. Shan C, Tang H, Wong T, He L, Lee ST. Facile synthesis of a large quantity of graphene by chemical vapor deposition: an advanced catalyst carrier. Adv Mater 2012;24:2491-5.
347. Wen Z, Wang X, Mao S, Bo Z, Kim H, Cui S, et al. Crumpled nitrogen-doped graphene nanosheets with ultrahigh pore volume for high-performance supercapacitor. Adv Mater 2012;24:5610-6.
348. Lin TW, Su CY, Zhang XQ, Zhang W, Lee YH, Chu CW, et al. Converting graphene oxide monolayers into boron carbonitride nanosheets by substitutional doping. Small 2012;8:1384-91.
349. Lin Z, Waller G, Liu Y, Liu M, Wong CP. Facile synthesis of nitrogen-doped graphene via pyrolysis of graphene oxide and urea, and its electrocatalytic activity toward the oxygen-reduction reaction. Adv Energy Mater 2012;2:884-8.
350. Guo J, Morris JR, Ihm Y, Contescu CI, Gallego NC, Duscher G, et al. Topological defects: origin of nanopores and enhanced adsorption performance in nanoporous carbon. Small 2012;8:3283-8.
351. Zhu X, Ning G, Fan Z, Gao J, Xu C, Qian W, et al. One-step synthesis of a graphene-carbon nanotube hybrid decorated by magnetic nanoparticles. Carbon 2012;50:2764-71.
352. Seredych M, Chen R, Bandosz TJ. Effects of the addition of graphite oxide to the precursor of a nanoporous carbon on the electrochemical performance of the resulting carbonaceous composites. Carbon 2012;50:4144-54.
353. Zhang D, Wen X, Shi L, Yan T, Zhang J. Enhanced capacitive deionization of graphene/mesoporous carbon composites. Nanoscale 2012;4:5440-6.
354. Wang L, Sun L, Tian C, Tan T, Mu G, Zhang H, et al. A novel soft template strategy to fabricate mesoporous carbon/graphene composites as high-performance supercapacitor electrodes. RSC Adv 2012;2:8359-67.
355. Hu C, Zhao Y, Cheng H, Hu Y, Shi G, Dai L, et al. Ternary Pd2/PtFe networks supported by 3D graphene for efficient and durable electrooxidation of formic acid. Chem Commun 2012;48:11865-7.
356. Sridhar V, Kim HJ, Jung JH, Lee C, Park S, Oh IK. Defect-engineered three-dimensional graphene-nanotube-palladium nanostructures with ultrahigh capacitance. ACS Nano 2012;6:10562-70.
357. 2 capture. Chem Commun 2012;48:11516-8.
358. z. ChemSusChem 2011;4:1662-70.
359. 2-graphene from in situ graphene-oxide reduction and its improved electrochemical properties. Carbon 2011;49:3250-7.
360. Liang J, Jiao Y, Jaroniec M, Qiao SZ. Sulfur and nitrogen dual-doped mesoporous graphene electrocatalyst for oxygen reduction with synergistically enhanced performance. Angew Chem Int Ed 2012;51:11496-500.
361. Fechler N, Fellinger TP, Antonietti M. "Salt templating": a simple and sustainable pathway toward highly porous functional carbons from ionic liquids. Adv Mater 2013;25:75-9.
362. Li Y, Fu ZY, Su BL. Hierarchically structured porous materials for energy conversion and storage. Adv Funct Mater 2012;22:4634-67.
363. Li X-H, Antonietti M. Polycondensation of boron- and nitrogen-codoped holey graphene monoliths from molecules: carbocatalysts for selective oxidation. Angew Chem Int Ed 2013;52:4572-6.
364. Weng Q, Wang X, Zhi C, Bando Y, Golberg D. Boron nitride porous microbelts for hydrogen storage. ACS Nano 2013;7:1558-65.
365. Li Y, Li Z, Shen PK. Simultaneous formation of ultrahigh surface area and three-dimensional hierarchical porous graphene-like networks for fast and highly stable supercapacitors. Adv Mater 2013;25:2474-80.
366. Zhang L, Zhang F, Yang X, Long G, Wu Y, Zhang T, et al. Porous 3D graphene-based bulk materials with exceptional high surface area and excellent conductivity for supercapacitors. Sci Rep 2013;3:1408.
367. Shen W, Fan W. Nitrogen-containing porous carbons: synthesis and application. J Mater Chem A 2013;1:999-1013.
368. Li J, Lin J, Xu X, Zhang X, Xue Y, Mi J, et al. Porous boron nitride with a high surface area: hydrogen storage and water treatment. Nanotechnology 2013;24:155603.
369. Masika E, Mokaya R. Exceptional gravimetric and volumetric hydrogen storage for densified zeolite templated carbons with high mechanical stability. Energy Environ Sci 2014;7:427-34.
370. Yang SJ, Kim T, Im JH, Kim YS, Lee K, Jung H, et al. MOF-derived hierarchically porous carbon with exceptional porosity and hydrogen storage capacity. Chem Mater 2012;24:464-70.
371. Jiang HL, Liu B, Lan YQ, Kuratani K, Akita T, Shioyama H, et al. From metal-organic framework to nanoporous carbon: toward a very high surface area and hydrogen uptake. J Am Chem Soc 2011;133:11854-7.
372. 2 capture in a hierarchically porous carbon with simultaneous high surface area and pore volume. Energy Environ Sci 2014;7:335-42.
373. Lee HJ, Choi S, Oh M. Well-dispersed hollow porous carbon spheres synthesized by direct pyrolysis of core-shell type metal-organic frameworks and their sorption properties. Chem Commun 2014;50:4492-5.
374. Li Y, Ben T, Zhang B, Fu Y, Qiu S. Ultrahigh gas storage both at low and high pressures in KOH-activated carbonized porous aromatic frameworks. Sci Rep 2013;2:2420.
375. 2 capture and enhanced capacitors. Chem Asian J 2013;8:1879-85.
376. Hu K, Gupta MK, Kulkarni DD, Tsukruk VV. Ultra-robust graphene oxide-silk fibroin nanocomposite membranes. Adv Mater 2013;25:2301-7.
377. Ou X, Chen P, Jiang L, Shen Y, Hu W, Liu M. P-conjugated molecules crosslinked graphene-based ultrathin films and their tunable performances in organic nanoelectronics. Adv Funct Mater 2013;24:543-54.
378. Zhong Z, Yao J, Low ZX, Chen R, He M, Wang H. Carbon composite membrane derived from a two-dimensional zeolitic imidazolate framework and its gas separation properties. Carbon 2014;72:242-9.
379. Yao J, Wang H. Zeolitic imidazolate framework composite membranes and thin films: synthesis and applications. Chem Soc Rev 2014;43:4470-93.