Graphene coatings: Probing the limits of the one atom thick protection layer

ACS Nano

Volumn 6, Issue 11, 2012, Pages 10258-10266

  Nilsson, Louis ^a   Andersen, Mie ^a   Balog, Richard ^a   Lægsgaard, Erik ^a   Hofmann, Philip ^a   Besenbacher, Flemming ^a   Hammer, Bjørk ^a   Stensgaard, Ivan ^a   Hornekær, Liv ^a  

^a AARHUS UNIVERSITY   (Denmark)

Author keywords

CO; coating; graphene; hydrogen; O2; STM

Indexed keywords

ANNEALING EXPERIMENTS; ATOMIC HYDROGEN; BASAL PLANES; COATING LAYER; DENSITY FUNCTIONAL THEORY CALCULATIONS; EXTREME CONDITIONS; GRAPHENE LAYERS; METAL SURFACES; PROTECTION LAYERS; PROTECTIVE EFFECTS; PT(100); REACTIVE SURFACES; SMALL MOLECULES; STM;

COATINGS; COBALT; DENSITY FUNCTIONAL THEORY; GRAPHENE; HYDROGEN; PLATINUM; SCANNING TUNNELING MICROSCOPY;

SURFACE RECONSTRUCTION;

GRAPHITE; NANOPARTICLE; PLATINUM;

ADSORPTION; ARTICLE; CHEMISTRY; MATERIALS TESTING; ULTRASTRUCTURE;

ADSORPTION; GRAPHITE; MATERIALS TESTING; NANOPARTICLES; PLATINUM;

EID: 84870449223     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn3040588     Document Type: Article

References (39)

1. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric Field Effect in Atomically Thin Carbon Films Science 2004, 306, 666-669
2. Geim, A. K.; Novoselov, K. S. The Rise of Graphene Nat. Mater. 2007, 6, 183-191
3. Coraux, J.; N'Diaye, A. T.; Busse, C.; Michely, T. Structural Coherency of Graphene on Ir(111) Nano Lett. 2008, 8, 565-570
4. Wintterlin, J.; Bocquet, M. L. Graphene on Metal Surfaces Surf. Sci. 2009, 603, 1841-1852
5. Nilsson, L.; Andersen, M.; Bjerre, J.; Balog, R.; Hammer, B.; Hornekær, L.; Stensgaard, I. Preservation of the Pt(100) Surface Reconstruction after Growth of a Continuous Layer of Graphene Surf. Sci. 2012, 606, 464-469
6. Sutter, P.; Sadowski, J. T.; Sutter, E. A. Chemistry under Cover: Tuning Metal-Graphene Interaction by Reactive Intercalation J. Am. Chem. Soc. 2010, 132, 8175-8179
7. Borca, B.; Calleja, F.; Hinarejos, J. J.; de Parga, A. L. V.; Miranda, R. Reactivity of Periodically Rippled Graphene Grown on Ru(0001) J. Phys. Condens. Mater. 2009, 21, 134002
8. Dedkov, Y. S.; Fonin, M.; Laubschat, C. A Possible Source of Spin-Polarized Electrons: The Inert Graphene/Ni(111) System Appl. Phys. Lett. 2008, 92, 052506
9. Chen, S.; Brown, L.; Levendorf, M.; Cai, W.; Ju, S.-Y.; Edgeworth, J.; Li, X.; Magnuson, C. W.; Velamakanni, A.; Piner, R. D. et al. Oxidation Resistance of Graphene-Coated Cu and Cu/Ni Alloy ACS Nano 2011, 5, 1321-1327
10. Topsakal, M.; Sahin, H.; Ciraci, S. Graphene Coatings: An Efficient Protection from Oxidation Phys. Rev. B 2012, 85, 155445
11. Kirkland, N. T.; Schiller, T.; Medhekar, N.; Birbilis, N. Exploring Graphene as a Corrosion Protection Barrier Corros. Sci. 2012, 56, 1-4
12. Prasai, D.; Tuberquia, J. C.; Harl, R. R.; Jennings, G. K.; Bolotin, K. I. Graphene: Corrosion-Inhibiting Coating ACS Nano 2012, 6, 1102-1108
13. Cho, J.; Gao, L.; Tian, J.; Cao, H.; Wu, W.; Yu, Q.; Yitamben, E. N.; Fisher, B.; Guest, J. R.; Chen, Y. P. et al. Atomic-Scale Investigation of Graphene Grown on Cu Foil and the Effects of Thermal Annealing ACS Nano 2011, 5, 3607-3613
14. Vinogradov, N. A.; Schulte, K.; Ng, M. L.; Mikkelsen, A.; Lundgren, E.; Mårtensson, N.; Preobrajenski, A. B. Impact of Atomic Oxygen on the Structure of Graphene Formed on Ir(111) and Pt(111) J. Phys. Chem. C 2011, 115, 9568-9577
15. Gadipelli, S.; Calizo, I.; Ford, J.; Cheng, G.; Walker, A. R. H.; Yildirim, T. A Highly Practical Route for Large-Area, Single Layer Graphene from Liquid Carbon Sources Such as Benzene and Methanol J. Mater. Chem. 2011, 21, 16057-16065
16. Mu, R.; Fu, Q.; Jin, L.; Yu, L.; Fang, G.; Tan, D.; Bao, X. Visualizing Chemical Reactions Confined under Graphene Angew. Chem., Int. Ed. 2012, 51, 4856-4859
17. May, J. W. Platinum Surface Leed Rings Surf. Sci. 1969, 17, 267-270
18. Helveg, S.; Lopez-Cartes, C.; Sehested, J.; Hansen, P. L.; Clausen, B. S.; Rostrup-Nielsen, J. R.; Abild-Pedersen, F.; Norskov, J. K. Atomic-Scale Imaging of Carbon Nanofibre Growth Nature 2004, 427, 426-429
19. 2-Exposed Pt(100)-Hex-R0.7-Degrees Surf. Sci. 1994, 306, 10-20
20. Hu, X.; Lin, Z. Hydrogen-Adsorption-Induced Phase Transitions on Pt(100)-Hex and the Surface Structure of Pt(100)-(1×1)H Phys. Rev. B: Condens. Matter 1995, 52, 11467
21. Hornekaer, L.; Sljivancanin, Z.; Xu, W.; Otero, R.; Rauls, E.; Stensgaard, I.; Laegsgaard, E.; Hammer, B.; Besenbacher, F. Metastable Structures and Recombination Pathways for Atomic Hydrogen on the Graphite (0001) Surface Phys. Rev. Lett. 2006, 96, 156104
22. Balog, R.; Jorgensen, B.; Wells, J.; Laegsgaard, E.; Hofmann, P.; Besenbacher, F.; Hornekaer, L. Atomic Hydrogen Adsorbate Structures on Graphene J. Am. Chem. Soc. 2009, 131, 8744-8745
23. Guisinger, N. P.; Rutter, G. M.; Crain, J. N.; First, P. N.; Stroscio, J. A. Exposure of Epitaxial Graphene on SiC(0001) to Atomic Hydrogen Nano Lett. 2009, 9, 1462-1466
24. Sljivancanin, Z.; Rauls, E.; Hornekaer, L.; Xu, W.; Besenbacher, F.; Hammer, B. Extended Atomic Hydrogen Dimer Configurations on the Graphite(0001) Surface J. Chem. Phys. 2009, 131, 084706
25. Casolo, S.; Lovvik, O. M.; Martinazzo, R.; Tantardini, G. F. Understanding Adsorption of Hydrogen Atoms on Graphene J. Chem. Phys. 2009, 130, 054704
26. Ferro, Y.; Teillet-Billy, D.; Rougeau, N.; Sidis, V.; Morisset, S.; Allouche, A. Stability and Magnetism of Hydrogen Dimers on Graphene Phys. Rev. B 2008, 78, 085417
27. Zecho, T.; Horn, A.; Biener, J.; Kuppers, J. Hydrogen Atom Reactions with Monolayer Graphite Edges on Pt(100) Surfaces: Hydrogenation and H Abstraction Surf. Sci. 1998, 397, 108-115
28. Redhead, P. A. Thermal Desorption of Gases Vacuum 1962, 12, 203-211
29. Jorgensen, B.; Thrower, J.; Baouche, S.; Balog, R.; Nilsson, L.; Friis, E. E.; Baurichter, A.; Zecho, T.; Besenbacher, F.; Luntz, A., et al. Substrate Enhanced Stability of Hydrogen Adsorption Complexes on Graphene on Ir(111). Unpublished.
30. Balog, R.; Jorgensen, B.; Nilsson, L.; Andersen, M.; Rienks, E.; Bianchi, M.; Fanetti, M.; Laegsgaard, E.; Baraldi, A.; Lizzit, S. et al. Bandgap Opening in Graphene Induced by Patterned Hydrogen Adsorption Nat. Mater. 2010, 9, 315-319
31. Havu, P.; Blum, V.; Havu, V.; Rinke, P.; Scheffler, M. Large-Scale Surface Reconstruction Energetics of Pt(100) and Au(100) by All-Electron Density Functional Theory Phys. Rev. B 2010, 82, 161418
32. Sofo, J. O.; Chaudhari, A. S.; Barber, G. D. raphane: A Two-Dimensional Hydrocarbon Phys. Rev. B 2007, 75, 153401
33. Laegsgaard, E.; Besenbacher, F.; Mortensen, K.; Stensgaard, I.; Fully, A Automated, Thimble-Size Scanning Tunnelling Microscope J. Microsc. (Oxford, U.K.) 1988, 152, 663-669
34. Tschersich, K. G. Intensity of a Source of Atomic Hydrogen Based on a Hot Capillary J. Appl. Phys. 2000, 87, 2565-2573
35. Artacho, E.; Anglada, E.; Dieguez, O.; Gale, J. D.; Garcia, A.; Junquera, J.; Martin, R. M.; Ordejon, P.; Pruneda, J. M.; Sanchez-Portal, D. et al. The Siesta Method; Developments and Applicability J. Phys. Condens. Mater 2008, 20, 064208
36. Soler, J. M.; Artacho, E.; Gale, J. D.; Garcia, A.; Junquera, J.; Ordejon, P.; Sanchez-Portal, D. The Siesta Method for Ab Initio Order-N Materials Simulation J. Phys. Condens. Mater 2002, 14, 2745-2779
37. Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized Gradient Approximation Made Simple Phys. Rev. Lett. 1996, 77, 3865-3868
38. Troullier, N.; Martins, J. L. Efficient Pseudopotentials for Plane-Wave Calculations Phys. Rev. B 1991, 43, 1993-2006
39. Enkovaara, J.; Rostgaard, C.; Mortensen, J. J.; Chen, J.; Dulak, M.; Ferrighi, L.; Gavnholt, J.; Glinsvad, C.; Haikola, V.; Hansen, H. A. et al. Electronic Structure Calculations with GPAW: A Real-Space Implementation of the Projector Augmented-Wave Method J. Phys. Condens. Mater 2010, 22, 253202