Cadmium complex possessing simultaneously silanethiolato- and dithiocarbamato-ligands. A novel single-source precursor of cadmium sulfide

Journal of Thermal Analysis and Calorimetry

Volumn 118, Issue 2, 2014, Pages 993-1001

  Mietlarek Kropidłowska, Anna ^a   Chojnacki, Jarosław ^a   Strankowski, Michał ^a   Fahmi, Amir ^b   Gazda, Maria ^a   Becker, Barbara ^a  

^a GDANSK UNIVERSITY OF TECHNOLOGY   (Poland)

^b RHINE WAAL UNIVERSITY OF APPLIED SCIENCES   (Germany)

Author keywords

Cadmium (II) complexes; Cadmium sulfide precursor; Dithiocarbamate; Silanethiolate; Structure; Thermal analysis

Indexed keywords

CADMIUM; COORDINATION REACTIONS; DECOMPOSITION; FILM PREPARATION; LIGANDS; STRUCTURE (COMPOSITION); SULFUR; THERMOANALYSIS;

CADMIUM COMPLEX; COORDINATION COMPOUNDS; DITHIOCARBAMATE LIGANDS; DITHIOCARBAMATES; ENDOTHERMIC DECOMPOSITION; SILANETHIOLATE; SINGLE-SOURCE PRECURSOR; X RAY STRUCTURE ANALYSIS;

CADMIUM SULFIDE;

EID: 84911992190     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-014-3842-z     Document Type: Article

References (27)

1. McCleverty JA, Meyer TJ, editors. Comprehensive coordination chemistry II. From biology to nanotechnology. Amsterdam: Elsevier; 2003.
2. Ruxandra V, Antohe S. The effect of the electron irradiation on the electrical properties of the polycrystalline CdS thin layers. J Appl Phys. 1998;84:727-33.
3. AlKuhaimi SA. Influence of preparation technique on the structural, optical and electrical properties of polycrystalline CdS films. Vacuum. 1998;51:349-55.
4. Valyomana AG, Vijayakumar KP, Purushothaman C. Conductivity studies on spray-pyrolysed CdS films in ambient conditions. J Mater Sci Lett. 1992;11:616-8.
5. Ozsan ME, Johnson DR, Sadeghi M, Svapathasundaram D, Godlet G, Furlong MJ, Peter LM, Shingleton AA. Optical and electrical characterization of CdS thin films. J Mater Sci Mater Electron. 1996;7:119-25.
6. Esteves ACC, Trindade T. Synthetic studies on II/VI semiconductor quantum dots. Curr Opin Solid State Mater Sci. 2002;6:347-53.
7. Fainer NI, Rumyantsev YuM, Salman EG, Kosinova ML, Yurjew GS, Sysoeva NP, Maximovskii EA, Sysoev SA, Golubenko AN. Plasma-deposited CdS layers from (o-phen) bis (diethyldithiocarbamate) cadmium. Thin Solid Films. 1998;286:122-6.
8. Fainer NI, Kosinova ML, Rumyantsev YM, Saman EG, Kuznetsov FA. Growth of PbS and CdS thin films by low-pressure chemical vapour deposition using dithiocarbamates. Thin Solid Films. 1996;280:16-9.
9. O'Brien P, Walsh JR, Watson IM, Hart L, Silva SRP. Properties of cadmium sulphide films grown by single-source metalorganic chemical vapour deposition with dithiocarbamate precursors. J Cryst Growth. 1996;167:133-42.
10. Coi I-H, Yu PY. Structural and optical properties of cubic-CdS and hexagonal-CdS thin films grown by MOCVD on GaAs substrates using a single-source precursor C14H30CdN2S4. Phys Status Solidi B. 2005;242:1610-6.
11. Zhang YC, Chen WW, Hu XY. Controllable synthesis and optical properties of Zn-doped CdS nanorods from single-source molecular precursors. Cryst Growth Des. 2007;7:580-6.
12. Byrom C, Malik MA, O'Brien P, White AJP, Williams DJ. Synthesis and X-ray single crystal structures of bis(diisobutyldithiophosphinato)cadmium(II) or zinc(II): potential single-source precursors for II/VI materials. Polyhedron. 2000;19:211-5.
13. Nair PS, Radhakrishnan T, Revaprasadu N, Kawole G, O'Brien P. Cadmium ethylxanthate: a novel single-source precursor for the preparation of CdS nanoparticles. J Mater Chem. 2002;12:2722-5.
14. Barreca D, Gasparotto A, Maragno C, Seraglia R, Tondello E, Venzo A, Krishnan V, Bertagnolli H. Cadmium O-alkylxanthates as CVD precursors of CdS: a chemical characterization. Appl Organomet Chem. 2005;19:59-67.
15. Cusack J, Drew MGB, Spalding TR. Syntheses and spectroscopy of diamine complexes of Zn(II) and Cd(II) ethylxanthates and the molecular structures of [M(S2COEt)2TMEDA]: formation of CdS nanoparticles from [Cd(S2COEt)2] and [Cd(S2COEt)2TMEDA]. Polyhedron. 2004;23:2315-21.
16. Nair PS, Radhakrishnan T, Revaprasadu N, Kolawole GA, O'Brien P. Cd(NH2CSNHNHCSNH2)Cl2: a new single-source precursor for the preparation of CdS nanoparticles. Polyhedron. 2003;22:3129-35.
17. Barone G, Chaplin T, Hibbert TG, Kana AT, Mahon MF, Molloy KC, Worsley ID, Parkin IP, Price LS. Synthesis and thermal decomposition studies of homo- and heteroleptic tin (IV) thiolates and dithiocarbamates: molecular precursors for tin sulfides. Dalton Trans. 2002;6:1085-92.
18. Kropidłowska A, Chojnacki J, Fahmi A, Becker B. In search of molecular precursors for cadmium sulfide - new complexes with sulfur-rich kernel: cadmium(II)tri-tert-butoxysilanethiolates with additional diethyldithiocarbamato ligand. Dalton Trans. 2008;47:6825-31.
19. Kropidłowska A, Rotaru A, Strankowski M, Becker B, Segal E. Thermal stability and non-isothermal decomposition kinetics of a heteroleptic cadmium(II) complex, potential precursor for semiconducting CdS layers. J Therm Anal Calorim. 2008;91:903-9.
20. Rotaru A, Mietlarek-Kropidłowska A, Constantinescu C, Scariooreanu N, Dumitru M, Strankowski M, Rotaru P, Ion V, Vasiliu C, Becker B, Dinescu M. CdS thin films obtained by thermal treatment of cadmium(II) complex precursor deposited by MAPLE technique. Appl Surf Sci. 2009;255:6786-9.
21. Wojnowski W, Becker B, Walz L, Peters K, Peters EM, von Schnering HG. Contributions to the chemistry of silicon-sulphur compounds - LX. Synthesis, molecular structure and properties of the dimeric cadmium(II) bis(tri-tert-butoxysilanethiolate)(t-C4H9O)3SiS2Cd2. Polyhedron. 1992;11:607-12.
22. ICDD PDF-2. Database Release 1998. ISSN 1084-3116.
23. Oxford Diffraction. CrysAlis CCD and CrysAlis RED, version 1.171.27p5. Abingdon: Oxford Diffraction Ltd; 2004.
24. Farrugia LJ. WinGX suite for small-molecule single-crystal crystallography. J Appl Cryst. 1999;32:837-8.
25. Kropidłowska A, Chojnacki J, Becker B. Bis(tetra-n-butyl-ammonium)tetra-bromocadmate(II) toluene disolvate. Acta Cryst E. 2006;62:m457-9.
26. Kropidłowska A, Chojnacki J, Becker B. Tetra-n-butylammonium iodido-(pyrrolidine-1-carbodithioato-κ2S, S')(tris-tert-butoxysilanethiolato-κS)cadmate(II). Acta Cryst E. 2008;64:m832.
27. O'Brien P, Park JH, Waters J. A single source approach to deposition of nickel sulfide thin films by LP-MOCVD. Thin Solid Films. 2003;431-432:502-5.