Kinetics and mechanism of the racemization of aryl allenes catalyzed by cationic gold(i) phosphine complexes

Chemistry - A European Journal

Volumn 20, Issue 38, 2014, Pages 12245-12254

  Harris, Robert J ^a   Nakafuku, Kohki ^a   Widenhoefer, Ross A ^a  

^a DUKE UNIVERSITY   (United States)

Author keywords

allenes; allylic compounds; gold; pi complexes; racemization

Indexed keywords

CARRIER CONCENTRATION; CATALYSIS; ELECTRON DENSITY MEASUREMENT; ELECTRONS; GOLD; GOLD COMPOUNDS; KINETICS; LIGANDS; PHOSPHORUS COMPOUNDS;

ALLENES; ALLYLIC COMPOUNDS; CATALYST CONCENTRATION; CATION INTERMEDIATES; FIRST-ORDER DEPENDENCE; KINETICS AND MECHANISM; PI COMPLEXES; RACEMIZATION;

HYDROCARBONS;

EID: 84911492151     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201402729     Document Type: Article

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