Stereoconvergent arylations and alkenylations of unactivated alkyl electrophiles: Catalytic enantioselective synthesis of secondary sulfonamides and sulfones

Journal of the American Chemical Society

Volumn 136, Issue 34, 2014, Pages 12161-12165

  Choi, Junwon ^a,b   Martín Gago, Pablo ^a   Fu, Gregory C ^a  

^a California Institute of Technology   (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES; CHELATION; SULFUR COMPOUNDS;

CROSS-COUPLING PRODUCTS; ELECTROPHILES; ENANTIOSELECTIVE SYNTHESIS; MECHANISTIC STUDIES; MEDICINAL CHEMISTRY; ORGANIC SYNTHESIS; REACTION PARTNERS; SOLVENT CAGES;

ALKENYLATION;

ALKENE; ELECTROPHILE; NICKEL; NUCLEOPHILE; SOLVENT; SULFONAMIDE; SULFONE; ALKANE; AROMATIC HYDROCARBON; ORGANOMETALLIC COMPOUND; ZINC; ZIRCONIUM;

ARTICLE; ARYLATION; CATALYST; CROSS COUPLING REACTION; ENANTIOMER; ENANTIOSELECTIVITY; MEDICINAL CHEMISTRY; STEREOCHEMISTRY; SYNTHESIS; CATALYSIS; CHEMISTRY; CYCLIZATION; ELECTRON TRANSPORT; STEREOISOMERISM;

ALKANES; ALKENES; CATALYSIS; CYCLIZATION; ELECTRON TRANSPORT; HYDROCARBONS, AROMATIC; NICKEL; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM; SULFONAMIDES; SULFONES; ZINC; ZIRCONIUM;

EID: 84906766693     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja506885s     Document Type: Article

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