Catalytic asymmetric synthesis of tertiary alkyl fluorides: Negishi cross-couplings of racemic α,α-dihaloketones

Journal of the American Chemical Society

Volumn 136, Issue 14, 2014, Pages 5520-5524

  Liang, Yufan ^a,b   Fu, Gregory C ^a,b  

^a California Institute of Technology   (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; COUPLINGS;

ALKYL FLUORIDES; ASYMMETRIC SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; MEDICINAL CHEMISTRY; NEGISHI REACTIONS; ORGANOFLUORINE COMPOUNDS; SCIENTIFIC DISCIPLINE; SELECTIVE REACTIONS;

FLUORINE COMPOUNDS;

ALPHA,ALPHA DIHALOKETONE; ELECTROPHILE; FLUORIDE; KETONE; UNCLASSIFIED DRUG; FLUORINATED HYDROCARBON;

ARTICLE; ARYLATION; ASYMMETRIC SYNTHESIS; CATALYST; CHEMICAL BOND; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; ENANTIOSELECTIVITY; NEGISHI CROSS COUPLING REACTION; STEREOCHEMISTRY; CATALYSIS; CHEMISTRY; SYNTHESIS;

CATALYSIS; HYDROCARBONS, FLUORINATED; KETONES; MOLECULAR STRUCTURE;

EID: 84897970502     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja501815p     Document Type: Article

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