Ligands control reactivity and selectivity in palladium-catalyzed functionalization of unactivated C sp3-H bonds

ChemCatChem

Volumn 6, Issue 8, 2014, Pages 2188-2190

  Fernández Ibáñez, M Ángeles ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

C H activation; ligand effects; N ligands; N,O ligands; palladium

Indexed keywords

ACTIVATION ANALYSIS; CATALYSIS; FUNCTIONAL GROUPS; PALLADIUM;

C-H ACTIVATION; DIRECTING GROUPS; FUNCTIONALIZATIONS; H-BONDS; LIGAND EFFECT; N ,O LIGANDS; N LIGANDS; PALLADIUM-CATALYZED;

LIGANDS;

EID: 84905583799     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201402269     Document Type: Article

References (23)

1. For recent reviews on C-H functionalization, see: a) T. W. Lyons, M. S. Sanford, Chem. Rev. 2010, 110, 1147
2. L. McMurray, F. O'Hara, M. J. Gaunt, Chem. Soc. Rev. 2011, 40, 1885
3. D. Y.-K. Chen, S. W. Youn, Chem. Eur. J. 2012, 18, 9452
4. For a recent special issue dedicated to this topic, see: Acc. Chem. Res. 2012, Issue 6, 777-958.
5. J. Wencel-Delord, T. Dröge, F. Liu, F. Glorius, Chem. Soc. Rev. 2011, 40, 4740
6. J. Wencel-Delord, F. Glorius, Nat. Chem. 2013, 5, 369.
7. K. M. Engle, J.-Q. Yu, J. Org. Chem. 2013, 78, 8927.
8. 2-H functionalization, see:, D. Alberico, M. E. Scott, M. Lautens, Chem. Rev. 2007, 107, 174.
9. 3-H functionalization, see: a) R. Jazzar, J. Hitce, A. Renaudat, J. Sofack-Kreutzer, O. Baudoin, Chem. Eur. J. 2010, 16, 2654
10. M. Wasa, K. M. Engle, J.-Q. Yu, Isr. J. Chem. 2010, 50, 605
11. H. Li, B.-J. Li, Z.-J. Shi, Catal. Sci. Technol. 2011, 1, 191.
12. 3-H bonds via the formation of lithium enolates, see
13. A. Renaudat, L. Jean-Gérard, R. Jazzar, C. E. Kefalidis, E. Clot, O. Baudoin, Angew. Chem. Int. Ed. 2010, 49, 7261
14. Angew. Chem. 2010, 122, 7419
15. A. Millet, P. Larini, E. Clot, O. Baudoin, Chem. Sci. 2013, 4, 2241.
16. P. Novák, A. Correa, J. Gallardo-Donaire, R. Martin, Angew. Chem. Int. Ed. 2011, 50, 12236
17. Angew. Chem. 2011, 123, 12444
18. A. Iglesias, R. Álvarez, A. R. de Lera, K. Muñiz, Angew. Chem. Int. Ed. 2012, 51, 2225
19. Angew. Chem. 2012, 124, 2268.
20. M. Wasa, K. S. L. Chan, X.-G. Zhang, J. He, M. Miura, J.-Q. Yu, J. Am. Chem. Soc. 2012, 134, 18570.
21. K. S. L. Chan, M. Wasa, L. Chu, B. N. Laforteza, M. Miura, Y.-Q. Yu, Nat. Chem. 2014, 6, 146
22. J. He, S. Li, Y. Deng, H. Fu, B. N. Laforteza, J. E. Spangler, A. Homs, J.-Q. Yu, Science 2014, 343, 1216
23. S. Li, G. Chen, C.-G. Feng, W. Gong, J.-Q. Yu, J. Am. Chem. Soc. 2014, 136, 5267.