A hydrogen bond rationale for the enantioselective β-alkenylboration of enones catalyzed by O-monoacyltartaric acids

Journal of Organic Chemistry

Volumn 79, Issue 14, 2014, Pages 6754-6758

  Grimblat, Nicolás ^a   Sugiura, Masaharu ^a,b   Pellegrinet, Silvina C ^a  

^a Universidad Nacional de Rosario   (Argentina)

^b KUMAMOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ENANTIOSELECTIVITY;

CARBONYL GROUPS; CARBOXY GROUPS; DFT CALCULATION; ENANTIOSELECTIVE; HYDROGEN BONDING INTERACTIONS; HYDROGEN-BOND INTERACTIONS; L-TARTARIC ACIDS; TRANSITION STRUCTURES;

HYDROGEN BONDS;

ALKENE DERIVATIVE; BORANE DERIVATIVE; CARBONYL DERIVATIVE; CARBOXYL GROUP; CYCLIC ACYLOXYBORANE; ENONE DERIVATIVE; HYDROGEN; OXYGEN; TARTARIC ACID DERIVATIVE; UNCLASSIFIED DRUG; KETONE; TARTARIC ACID;

ALKENYLBORATION; ARTICLE; ASYMMETRIC CATALYSIS; CATALYST; CHEMICAL INTERACTION; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CONJUGATION; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; HYDROGEN BOND; MOLECULAR STABILITY; CATALYSIS; CHEMISTRY; CONFORMATION; STEREOISOMERISM; SYNTHESIS;

BORANES; CATALYSIS; HYDROGEN BONDING; KETONES; MOLECULAR CONFORMATION; STEREOISOMERISM; TARTRATES;

EID: 84904569280     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo5012398     Document Type: Article

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