Synthesis of α-trifluoromethyl ketones via the Cu-catalyzed trifluoromethylation of silyl enol ethers using an electrophilic trifluoromethylating agent

Journal of Organic Chemistry

Volumn 79, Issue 11, 2014, Pages 5145-5152

  Li, Lun ^a   Chen, Qing Yun ^a   Guo, Yong ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ETHERS; KETONES;

SILYL ENOL ETHERS; TRIFLUOROMETHYL RADICAL; TRIFLUOROMETHYLATION; TRIFLUOROMETHYLKETONE;

CATALYSIS;

ALPHA TRIFLUOROMETHYLKETONE; ETHER DERIVATIVE; KETONE; RADICAL; SILYL ETHER; TRIMETHYLSILYL DERIVATIVE; UNCLASSIFIED DRUG; ALCOHOL DERIVATIVE; FLUORINATED HYDROCARBON; SILANE DERIVATIVE;

ARTICLE; COLUMN CHROMATOGRAPHY; COMPARATIVE STUDY; ELECTROPHILICITY; FLUORINE NUCLEAR MAGNETIC RESONANCE; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; METHYLATION; REACTION ANALYSIS; SCREENING; SYNTHESIS; TRIFLUOROMETHYLATION; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM;

ALCOHOLS; CATALYSIS; ETHERS; HYDROCARBONS, FLUORINATED; KETONES; METHYLATION; MOLECULAR STRUCTURE; SILANES; STEREOISOMERISM;

EID: 84902095842     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo500713f     Document Type: Article

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