Palladium enolate umpolung: Cyclative diacetoxylation of alkynyl cyclohexadienones promoted by a Pd/SPRIX catalyst

Angewandte Chemie - International Edition

Volumn 53, Issue 18, 2014, Pages 4675-4679

  Takenaka, Kazuhiro ^a   Mohanta, Suman C ^a   Sasai, Hiroaki ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

cyclization; enyne; palladium; spiro compounds; umpolung

Indexed keywords

ACETIC ACID; CATALYSIS; CATALYSTS; CYCLIZATION; CYCLOHEXANE; LIGANDS; ORGANIC COMPOUNDS; OXYGEN; PALLADIUM; PH;

ENYNE; HIGH ENANTIOSELECTIVITY; ISOXAZOLINES; NUCLEOPHILIC ATTACK; OXYGEN ATMOSPHERE; PALLADIUM-CATALYZED REACTIONS; SPIRO COMPOUNDS; UMPOLUNG;

OLEFINS;

EID: 84899515880     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201311172     Document Type: Article

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