Chlorinative cyclization of 1,6-enynes by enantioselective palladium(II)/palladium(IV) catalysis

Advanced Synthesis and Catalysis

Volumn 353, Issue 7, 2011, Pages 1067-1070

  Takenaka, Kazuhiro ^a   Hashimoto, Shintaro ^a   Takizawa, Shinobu ^a   Sasai, Hiroaki ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

asymmetric catalysis; cyclization; enynes; lactones; palladium(II) palladium(IV) cycle

Indexed keywords

EID: 79955888444     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201000926     Document Type: Article

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36. 2 at 15 °C in AcOH (0.1 M)], not even a trace amount of (E)- 3f was detected after 3 days; (Z)- 3f was recovered quantitatively.