Diastereoselective carbocyclization of 1,6-heptadienes triggered by rhodium-catalyzed activation of an olefinic C-H bond

Angewandte Chemie - International Edition

Volumn 53, Issue 16, 2014, Pages 4209-4212

  Aïssa, Christophe ^a   Ho, Kelvin Y T ^a   Tetlow, Daniel J ^a   Pin Nõ, María ^a  

^a UNIVERSITY OF LIVERPOOL   (United Kingdom)

Author keywords

C H activation; diastereoselectivity; diene; rearrangement; rhodium

Indexed keywords

ACTIVATION ANALYSIS; CATALYSIS; FUNCTIONAL GROUPS; HYDROGEN BONDS; OLEFINS; RHODIUM;

C-H ACTIVATION; CARBON-HYDROGEN BOND; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE; DIENE; MIGRATORY INSERTION; REARRANGEMENT; STEREOGENIC CENTERS;

STEREOSELECTIVITY;

ALKADIENE; RHODIUM;

CATALYSIS; CHEMISTRY; CYCLIZATION; STEREOISOMERISM;

ALKADIENES; CATALYSIS; CYCLIZATION; RHODIUM; STEREOISOMERISM;

EID: 84898849241     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201400080     Document Type: Article

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