Rhodium-catalyzed coupling reaction of 2-vinylpyridines with 1,5-hexadiene: Effects of phosphine ligands

Tetrahedron Letters

Volumn 40, Issue 43, 1999, Pages 7691-7694

  Lim, Yeong Gweon ^a   Kang, Jung Bu ^a   Koo, Bon Tak ^a  

^a Agency for Defence Development   (South Korea)

Author keywords

C H bond activation; Coupling reaction; Rhodium catalyst

Indexed keywords

LIGAND; PHOSPHINE DERIVATIVE; PHOSPHITE; PYRIDINE DERIVATIVE; RHODIUM;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; HYDROGEN BOND; MOLECULAR INTERACTION; STRUCTURE ACTIVITY RELATION;

EID: 0033595890     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01550-6     Document Type: Article

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26. These experiments were carried out to obtain information for the mechanistic aspect. These results imply that 5-membered ring rhodium intermediate formed from 1,5-hexadiene is stable in catalytic cycle.