Hydrogen from Bioethanol

Renewable Hydrogen Technologies: Production, Purification, Storage, Applications and Safety

Volumn , Issue , 2013, Pages 135-169

  Llorca, Jordi ^a   Corberán, Vicente Cortés ^b   Divins, Núria J ^a   Fraile, Raquel Olivera ^b   Taboada, Elena ^a  

^a UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

^b INSTITUTO DE CATÁLISIS Y PETROLEOQUÍMICA   (Spain)

Author keywords

Autothermal reforming of ethanol; Bioethanol; Catalytic membrane reactors; Ethanol steam reforming; Hydrogen production; Noble metal catalysts; Partial oxidation of ethanol; Photocatalysts; Structured catalysts

Indexed keywords

BIOETHANOL; BIOREACTORS; CATALYSTS; CATALYTIC OXIDATION; CATALYTIC REFORMING; DEPOSITION; ETHANOL; OXIDATION; PHOTOCATALYSTS; PRECIOUS METALS; SINTERING; STEAM REFORMING;

AUTO-THERMAL REFORMING OF ETHANOLS; CATALYTIC MEMBRANE REACTORS; ETHANOL STEAM REFORMING; NOBLE METAL CATALYSTS; PARTIAL OXIDATION OF ETHANOL; STRUCTURED CATALYST;

HYDROGEN PRODUCTION;

EID: 84897907392     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1016/B978-0-444-56352-1.00007-6     Document Type: Chapter

References (272)

1. Logsdon J.E. Ethanol. Kirk-Othmer Encyclopedia of Chemical Engineering 2004, Vol. 10:527-567. Wiley-Interscience, New York. 5th ed. A. Seidel (Ed.).
2. Shapouri H., Duffield J.A., Wang M. The Energy Balance of Corn Ethanol 2002, An Update. AER-814, USDA Office of the Chief Economist, Washington, D.C.
3. Shapouri H., Duffield J.A., Wang M. The Energy Balance of Corn Ethanol Revisited. Trans. ASAE 2003, 46:959-968.
4. Deluga G.A., Salge J.R., Schmidt L.D., Verykios X.E. Renewable Hydrogen from Ethanol by Autothermal Reforming. Science 2004, 303:993-997.
5. Subramani V., Song C. Advances in Catalysis and Process for Hydrogen Production from Ethanol Reforming. Catalysis 2007, 20:65-106.
6. World Fuel Ethanol Production 2012, Renewable Fuels Association, (accessed 30 July 2012). http://ethanolrfa.org/pages/World-Fuel-Ethanol-Production.
7. Ni M., Leung D.Y.C., Leung M.K.H. A Review on Reforming Bio-Ethanol for Hydrogen Production. Int. J. Hydrogen Energy 2007, 32:3238-3247.
8. Galbe M., Zacchi G.A. A Review of the Production of Ethanol from Softwood. Appl. Microbiol. Biotechnol. 2002, 59:618-628.
9. Vasudeva K., Mitra N., Umasankar P., Dhingra S.C. Steam Reforming of Ethanol for Hydrogen Production: Thermodynamic Analysis. Int. J. Hydrogen Energy 1996, 21(1):13-18.
10. Brown L.F. A Comparative Study of Fuels for On-Board Hydrogen Production for Fuel-Cell-Powered Automobiles. Int. J. Hydrogen Energy 2001, 26:381-397.
11. Material Safety Sheet Ethanol 2012, Murtagh and Associates, (accessed June 2012). http://www.distill.com/materialsafety/msds-eu.html.
12. Velu S., Satoh N., Gopinath C.S., Suzuki K. Oxidative Reforming of Bio-Ethanol over CuNiZnAl Mixed Oxide Catalysts for Hydrogen Production. Catal. Lett. 2002, 82:145-152.
13. Casanovas A., de Leitenburg C., Trovarelli A., Llorca J. Catalytic Monoliths for Ethanol Steam Reforming. Catal. Today 2008, 138:187-192.
14. Rabenstein G., Hacker V. Hydrogen for Fuel Cells from Ethanol by Steam-Reforming, Partial-Oxidation and Combined Auto-Thermal Reforming: A Thermodynamic Analysis. J. Power Sources 2008, 185:1293-1304.
15. Benito M., Sanz J.L., Isabel R., Padilla R., Arjona R., Daza L. Bio-Ethanol Steam Reforming: Insights on the Mechanism for Hydrogen Production. J Power Sources 2005, 151:11-17.
16. Haryanto A., Fernando S., Murali N., Adhikari S. Current Status of Hydrogen Production Techniques by Steam Reforming of Ethanol: A Review. Energy Fuels 2005, 19:2098-2106.
17. Vaidya P.D., Rodrigues A.E. Insight into Steam Reforming of Ethanol to Produce Hydrogen for Fuel Cells. Chem. Eng. J. 2006, 117:39-49.
18. Bion N., Duprez D., Epron F. Design of Nanocatalysts for Green Hydrogen Production from Bioethanol. ChemSusChem 2012, 5:76-84.
19. Hohn K.L., Lin Y.-C. Catalytic Partial Oxidation of Methanol and Ethanol for Hydrogen Generation. ChemSusChem 2009, 2:927-940.
20. 3 Spinel Oxide-Supported Rh Catalysts. J. Catal. 2005, 233:464-477.
21. Idriss H., Scott M., Llorca J., Chan S., Chiu W., Sheng P., Yee A., Blackford M., Pas S., Hill A., Alamgir F., Rettew R., Petersburg C., Senanayake S., Barteau M. A Phenomenological Study of the Metal-Oxide Interface: The Role of Catalysis in Hydrogen Production from Renewable Resources. ChemSusChem 2008, 1:905-910.
22. 3 Catalysts. Energy Fuels 2000, 14:1195-1199.
23. Auprêtre F., Descorme C., Duprez D. Bio-Ethanol Catalytic Steam Reforming Over Supported Metal Catalysts. Catal. Commun. 2002, 3:263-267.
24. Breen J., Burch R., Coleman H. Metal-Catalyzed Steam Reforming of Ethanol in the Production of Hydrogen for Fuel Cell Applications. Appl. Catal. B: Environ. 2002, 39:65-74.
25. 2 Catalysts. Catal. Commun. 2002, 3:565-571.
26. Romero-Sarria F., Vargas J.C., Roger A.-C., Kiennemann A. Hydrogen Production by Steam Reforming of Ethanol. Catal. Today 2008, 133-135:149-153.
27. 2 Catalyst. Appl. Catal. A: Gen. 2010, 383:33-42.
28. Liguras D.K., Kondarides D.I., Verykios X.E. Production of Hydrogen for Fuel Cells by Steam Reforming of Ethanol over Supported Noble Metal Catalysts. Appl. Catal. B: Environ 2003, 43:345-354.
29. 2/YSZ (M=Ru, Pd, Ag) Nanocomposites. Catal. Today 2012, 180:96-104.
30. Siang J.-Y., Lee C.-C., Wang C.-H., Wang W.-T., Deng C.-Y., Yeh C.-T., Wang C.-B. Hydrogen Production from Steam Reforming of Ethanol Using Ceria-Supported Iridium Catalyst: Effect of Different Ceria Supports. Int. J. Hydrogen Energy 2010, 35:3456-3462.
31. 2 Catalyst: Reaction Mechanism and Stability of the Catalyst. Int. J. Hydrogen Energy 2008, 33:4377-4386.
32. 3. J. Phys. Chem. A 2010, 114:3873-3882.
33. 2 Catalysts. Top. Catal. 2008, 51:13-21.
34. Idriss H. Ethanol Reactions over the Surfaces of Noble Metal/Cerium Oxide Catalysts. Platin. Met. Rev. 2004, 48:105-115.
35. Simson A., Farrauto R., Castaldi M. Steam Reforming of Ethanol/Gasoline Mixtures: Deactivation, Regeneration and Stable Performance. Appl. Catal. B: Environ. 2011, 106:295-303.
36. De Lima S., Colman R., Jacobs G., Davis B.H., Souza K.R., de Lima A.F.F., Appel L.G., Mattos L.V., Noronha F.B. Hydrogen Production from Ethanol for PEM Fuel Cells. An Integrated Fuel Processor Comprising Ethanol Reforming and Preferential Oxidation of CO. Catal. Today 2009, 146:110-123.
37. 2 Catalyst: Reaction Mechanism and Deactivation. Appl. Catal. A: Gen. 2009, 352:95-113.
38. 2 Catalyst. Appl. Catal. B: Environ. 2011, 102:94-109.
39. Scott M.S., Idriss H. Heterogeneous Catalysis for Hydrogen Production. Handbook of Green Chemistry 2010, pp. 223-246.
40. 2 Catalysts. Appl. Catal. B: Environ. 2010, 96:190-197.
41. Erdohelyi A., Rasko J., Kecskes T., Toth M., Domok M., Baan K. Hydrogen formation in ethanol reforming on supported noble metal catalysts. Catalysis Today 2006, 367-376.
42. 2 Production. Appl. Catal. B: Environ. 2008, 79:17-25.
43. 2 Selective Catalysts for Ethanol Steam Reforming. Catal. Lett. 2006, 108:15-19.
44. 2-Containing Materials. Catal. Rev. Sci. Eng. 1996, 38:439-520.
45. 3 Catalysts in a Microchannel Reactor. Chem. Eng. J. 2011, 167:578-587.
46. 3 Nanocomposite for Ethanol Steam Reforming. J. Alloys Compd. 2008, 451:516-520.
47. 3 Catalysts for High-Temperature Fuel-Cell Feeds. React. Kinet. Mech. Catal. 2011, 104:75-87.
48. Moura J.S., Souza M.O.G., Bellido J.D.A., Assaf E.M., Opportus M., Reyes P., Rangel M.C. Ethanol Steam Reforming over Rhodium and Cobalt-Based Catalysts: Effect of the Support. Int. J. Hydrogen Energy 2012, 37:3213-3224.
49. 2 Catalysts. Top. Catal. 2008, 49:32-37.
50. 2 Prepared Via a Glycine Nitrate Process. Energy Fuels 2008, 22:1873-1879.
51. 3 Catalyst. Appl. Catal. B: Environ. 2004, 49:135-144.
52. Galvita V.V., Semin G.L., Belyaev V.D., Semikolenov V.A., Tsikaras P., Sobyanin V.A. Synthesis Gas Production by Steam Reforming of Ethanol. Appl. Catal. A: Gen. 2001, 220:123-127.
53. Galvita V.V., Belyaev V.D., Semikolenov V.A., Tsikaras P., Frumin A., Sobyanin V.A. Ethanol Decomposition over Pd-Based Catalyst in the Presence of Steam. React. Kinet. Catal. Lett. 2002, 76:343-351.
54. 3 Catalyst. Catal. Lett. 2008, 126:49-57.
55. 2 Co-Feeding. Appl. Catal. B: Environ. 2010, 96:387-398.
56. Yaseneva P., PAvlova S., Sadykov V., Alikina G., Lykashevich A., Rogov V., Belochapkine, Ross J. Combinatorial Approach to the Preparation and Characterization of Catalysts for Biomass Steam Reforming into Syngas. Catal. Today 2008, 137:23-28.
57. Kaspar J., Fornasiero P. Catalysis by Ceria and Related Materials. Catalytic Science Series 2002, Vol. 2:217. Imperial College Press, London, UK. A. Trovarelli (Ed.).
58. 3 Catalysts for Ethanol Steam Reforming. J. Phys. Chem. C 2008, 112:14145-14153.
59. Le Valant A., Can F., Bion N., Duprez D., Epron F. Hydrogen Production from Raw Bioethanol Steam Reforming: Optimization of Catalyst Composition with Improved Stability Against Various Impurities. Int. J. Hydrogen Energy 2010, 35:5015-5020.
60. 4 Catalyst. Catal. Today 2008, 138:169-174.
61. Bshish A., Yahkkob Z., Narayanan B., Ramakrishnan R., Ebshish A. Steam Reforming of Ethanol for Hydrogen Production. Rev. Chem. Papers 2011, 65(3):251-266.
62. Li M.S., Wang X.D., Li S.R., Wang S.P., Ma X.B. Hydrogen Production from Ethanol Steam Reforming over Nickel Based Catalyst Derived from Ni/Mg/Al Hydrotalcite-Like Compounds. Int. J. Hydrogen Energy 2010, 35(13):6699-6708.
63. Wang W. Production of Hydrogen by Steam Reforming of Bioethanol over Copper-Nickel Bimetallic Catalysts. Int. J. Green Energy 2009, 6(1):92-103.
64. Yang Y., Ma J., Wu F. Production of Hydrogen by Steam Reforming of Ethanol over a Ni/ZnO Catalyst. Int. J. Hydrogen Energy 2006, 31(7):877-882.
65. Frusteri F., Freni S., Chiodo V., Spadaro L., Blasi O.Di, Bonura G., Cavallaro S. Steam Reforming of Bio-Ethanol on Alkali-Doped Ni/MgO Catalysts: Hydrogen Production for MC Fuel Cell. Appl. Catal. A: Gen. 2004, 270:1-7.
66. 2-Supported Ni-Rh Bimetallic Catalysts for Hydrogen Production. Catal. Lett. 2005, 101(3-4):255-264.
67. 3 Catalysts: Effect of Second Metal Addition. J. Power Sources 2006, 162:1270-1274.
68. 3 Catalysts in the Hydrogen Production by Auto-Thermal Reforming of Ethanol. J. Mol. Catal. A: Chem. 2007, 261:276-281.
69. 3 Catalysts: Effect of Magnesium Addition. Int. J. Hydrogen Energy 2008, 33(13):3489-3492.
70. Vizcaino A.J., Carrero A., Calles J.A. Ethanol Steam Reforming on Mg- and Ca-Modified Cu-Ni/SBA-15 Catalysts. Catal. Today 2009, 146(1-2):63-70.
71. 2 Catalysts for Ethanol Steam Reforming. Chem. Eng. J. 2010, 63(3):395-402.
72. Zhang C., Li S., Li M., Wang S., Ma X., Gong J. Enhanced Oxygen Mobility and Reactivity for Ethanol Steam Reforming. AlChE J. 2012, 58(2):516-525.
73. 3. II. Acidity/Basicity, Water Adsorption and Catalytic Activity. Appl. Catal. A: Gen. 2011, 407(1-2):155-162.
74. Urasaki K., Tokunaga K., Sekine Y., Matsukata M., Kikuchi E. Production of Hydrogen by Steam Reforming of Ethanol over Cobalt and Nickel Catalysts Supported on Perovskite-Type Oxides. Catal. Commun. 2008, 9(5):600-604.
75. Chen S.Q., Li Y.D., Liu Y., Bai X. Regenerable and Durable Catalyst for Hydrogen Production from Ethanol Steam Reforming. Int. J. Hydrogen Energy 2011, 36(10):5849-5856.
76. Busca G., Constantin U., Montanari T., Ramis G., Resini C., Sisani M. Nickel Versus Cobalt Catalysts for Hydrogen Production by Ethanol Steam Reforming: Ni-Co-Zn-Al Catalysts from Hydrotalcite-Like Precursors. Int. J. Hydrogen Energy 2010, 35(11):5356-5366.
77. Yu X., Chu W., Wang N., Ma F. Hydrogen Production by Ethanol Steam Reforming on NiCuMgAl Catalysts Derived from Hydrotalcite-Like Precursors. Catal. Lett. 2011, 141(8):1228-1236.
78. 3-MyOz (M = Si, La, Mg and Zn) Catalysts. J. Nat. Gas Chem. 2009, 18(1):55-65.
79. 2 Catalysts: Effect of Cu/Ni Ratio. Appl. Catal. B: Environ. 2011, 106(3-4):639-649.
80. 3 Catalysts in Supercritical Water for Hydrogen Production. Int. J. Hydrogen Energy 2011, 36(4):2877-2886.
81. 2 Catalysts: Effect of Support on Product Distribution. Int. J. Hydrogen Energy 2012, 37(3):2940-2949.
82. Vizcaino A.J., Lindo M., Carrero A., Calles J.A. Hydrogen Production by Steam Reforming of Ethanol Using Ni Catalysts Based on Ternary Mixed Oxides Prepared by Coprecipitation. Int. J. Hydrogen Energy 2012, 37(2):1985-1992.
83. 2-δ Catalysts for Hydrogen Production by the Steam Reforming of a Mixture of Oxygenated Hydrocarbons. Energy Fuels 2012, 26(2):816-828.
84. Iriondo A., Barrio V.L., El Doukkali M., Cambra J.F., Gueemez M.B., Requies J., Arias P.L., Sanchez-Sanchez M.C., Navarro R., Fierro J.L.G. International Journal of Hydrogen Energy 2012, 37(2):2028-2036.
85. 2 Production by Ethanol Reforming. Int. J. Hydrogen Energy 2010, 35(22):12588-12595.
86. Ozkan G., Gok S., Ozkan G. Active Carbon-Supported Ni, Ni/Cu and Ni/Cu/Pd Catalysed Steam Reforming of Ethanol for the Production of Hydrogen. Chem. Eng. J. 2011, 171(3):1270-1275.
87. Calles J.A., Carrero A., Vizcaino A.J. Ce and La Modification of Mesoporous Cu-Ni/SBA-15 Catalysts for Hydrogen Production through Ethanol Steam Reforming. Microporous and Mesoporous Materials 2009, 119(1-3):200-207.
88. 2 Production from Ethanol Steam Reforming by Zeolite Basicity. Int. J. Hydrogen Energy 2011, 36(23):15195-15202.
89. Kwak Byeong Sub, Lee Jun Su, Lee Jun Sung, Choi Byung-Hyun, Ji Mi Jung, Kang Misook Applied Energy 2011, 88(12):4366-4375.
90. Haga F., Nakajima T., Miya H., Mishima S. Catalytic Properties of Supported Cobalt Catalysts for Steam Reforming of Ethanol. Catal. Lett. 1997, 48:223-227.
91. Cavallaro S., Mondello N., Freni S. Hydrogen Produced from Ethanol for Internal Reforming Molten Carbonate Fuel Cell. J. Power Sources 2001, 102:198-204.
92. Llorca J., Homs N., Sales J., Ramírez de la Piscina P. Efficient Production of Hydrogen over Supported Cobalt Catalysts from Ethanol Steam Reforming. J. Catal. 2002, 209:306-317.
93. 3 Catalysts used for Ethanol Steam Reforming. Catal. Commun. 2004, 5:339-345.
94. Batista M.S., Santos R.K.S., Assaf E.M., Assaf J.M., Ticianelli E.A. High Efficiency Steam Reforming of Ethanol by Cobalt-Based Catalysts. J. Power Sources 2004, 134:27-32.
95. Llorca J., Dalmon J.A., Ramírez de la Piscina P., Homs N. In Situ Magnetic Characterisation of Supported Cobalt Catalysts under Steam-Reforming of Ethanol. Appl. Catal. A: Gen. 2003, 243:261.
96. Llorca J., Ramírez de la Piscina P., Dalmon J.A., Sales J., Homs N. CO-Free Hydrogen from Steam-Reforming of Bioethanol over ZnO-Supported Cobalt Catalysts: Effect of the Metallic Precursor. Appl. Catal. B: Environ. 2003, 43:355-369.
97. Llorca J., Homs N., Ramírez de la Piscina P. In Situ DRIFT-Mass Spectrometry Study of the Ethanol Steam-Reforming Reaction over Carbonyl-Derived Co/ZnO Catalysts. J. Catal. 2004, 227:556.
98. Martono E., Hyman M.P., Vohs J.M. Reaction Pathways for Ethanol on Model Co/ZnO (0001) Catalysts. Phys. Chem. Chem. Phys. 2011, 13:9880-9886.
99. 2+ During Steam Reforming of Ethanol on Co/MgO Catalysts. ACS Catal. 2011, 1:279-286.
100. Hyman M.P., Vohs J.M. Reaction of Ethanol on Oxidized and Metallic Cobalt Surfaces. Surf. Sci. 2011, 605:383-389.
101. 3 Catalyst. Chem. Eng. J. 2007, 125:139-147.
102. Karim A.M., Su Y., Sun J., Yang C., Strohm J.J., King D.L., Wang Y. A Comparative Study between Co and Rh for Steam Reforming of Ethanol. Appl. Catal. B: Environ. 2010, 96:441-448.
103. Song H., Zhang L., Ozkan U.S. Investigation of the reaction Network in Ethanol Steam Reforming over Supported Cobalt Catalysts. Ind. Eng. Chem. Res. 2010, 49:8984-8989.
104. 4 during Ethanol Steam-Re-forming. Activation Process for Hydrogen Production. Chem. Mater. 2004, 16:3573-3578.
105. Bayram B., Soykal I.I., von Deak D., Miller J.T., Ozkan U.S. Ethanol Steam Reforming over Co-Based Catalysts: Investigation of Cobalt Coordination Environment under Reaction Conditions. J. Catal. 2011, 284:77-89.
106. Lin S.S.Y., Kim D.H., Ha S.Y. Metallic Phases of Cobalt-Based Catalysts in Ethanol Steam Reforming: The Effect of Cerium Oxide. Appl. Catal. A: Gen. 2009, 355:69-77.
107. Bichon P., Haugom G., Venvik H.J., Holmen A., Blekkan E.A. Steam Reforming of Ethanol over Supported Co and Ni Catalysts. Top. Catal. 2008, 49:38-45.
108. 2 Catalyst. Chem. Eng. J. 2008, 145:25-31.
109. Llorca J., Homs N., Sales J., Fierro J.L.G., Ramírez de la Piscina P. Effect of Sodium Addition on the Performance of Co-ZnO-Based Catalysts for Hydrogen Production from Bioethanol. J. Catal. 2004, 222:470-480.
110. Kim K.S., Seo H.R., Lee S.Y., Ahn J.G., Shin W.C., Lee Y.K. TPR and EXAFS Studies on Na-Promoted Co/ZnO Catalysts for Ethanol Steam Reforming. Top. Catal. 2010, 53:615-620.
111. Galetti A.E., Gómez M.F., Arrua L.A., Marchi A.J., Abelló M.C. Study of CuCoZnAl Oxide as Catalyst for the Hydrogen Production from Ethanol Reforming. Catal. Commun. 2008, 9:1201-1208.
112. 3, and Fe- and Mn-Promoted Co/ZnO Catalysts. J. Power Sources 2007, 169:158-166.
113. Casanovas A., de Leitenburg C., Trovarelli A., Llorca J. Ethanol Steam Reforming and Water Gas Shift Reaction over Co-Mn/ZnO Catalysts. Chem. Eng. J. 2009, 154:267-273.
114. Casanovas A., Roig M., de Leitenburg C., Trovarelli A., Llorca J. Ethanol Steam Reforming and Water Gas Shift over Co/ZnO Catalytic Honeycombs Doped with Fe, Ni, Cu, Cr and Na. Int. J. Hydrogen Energy 2010, 35:7690-7698.
115. Sekine Y., Kazama A., Izutsu Y., Matsukata M., Kikuchi E. Steam Reforming of Ethanol over Cobalt Catalysts Modified with Small Amount of Iron. Catal. Lett. 2009, 132:329-334.
116. 3 for Steam Reforming of Ethanol. Appl. Catal. A: Gen. 2010, 383:96-101.
117. Song H., Ozkan U.S. Ethanol Steam Reforming over Co-Based Catalysts: Role of Oxygen Mobility. J. Catal. 2009, 261:66-74.
118. Song H., Bao X., Hadad C.M., Ozkan U.S. Adsorption/Desorption Behavior of Ethanol Steam Reforming Reactants and Intermediates over Supported Cobalt Catalysts. Catal. Lett. 2011, 141:43-54.
119. 2 Catalyst. J. Catal. 2009, 268:268-281.
120. Avila-Neto C.N., Liberatori J.W.C., da Silva A.M., Zanchet D., Hori C.E., Noronha F.B., Bueno J.M.C. Understanding the Stability of Co-Supported Catalysts During Ethanol Reforming as Addressed by In Situ Temperature and Spatial Resolved XAFS Analysis. J. Catal. 2012, 287:124-137.
121. Rybak P., Tomaszewska B., Machocki A., Grzegorczyk W., Denis A. Conversion of Ethanol over Supported Cobalt Oxide Catalysts. Catal. Today 2011, 176:14-20.
122. 2 Catalysts. ChemSusChem 2011, 4:1679-1684.
123. Song H., Ozkan U.S. Changing the Oxygen Mobility in Co/Ceria Catalysts by Ca Incorporation: Implications for Ethanol Steam Reforming. J. Phys. Chem. A 2010, 114:3796-3801.
124. 2 Catalysts Prepared by Impregnation and Coprecipitation for Ethanol Steam Reforming. Appl. Catal. A: Gen. 2009, 366:252-261.
125. 2 as Ethanol Steam Reforming Catalysts. Catal. Lett. 2009, 132:422-429.
126. Benito M., Padilla R., Serrano-Lotina A., Rodríguez L., Brey J.J., Daza L. The Role of Surface Reactions on the Active and Selective Catalyst Design for Bioethanol Steam Reforming. J. Power Sources 2009, 192:158-164.
127. 3 Catalysts: Effect of Addition of Small Quantities of Noble Metals. J. Power Sources 2008, 175:482-489.
128. Profeti L.P.R., Ticianelli E.A., Assaf E.M. Ethanol Steam Reforming for Production of Hydrogen on Magnesium Aluminate-Supported Cobalt Catalysts Promoted by Noble Metals. Appl. Catal. A: Gen. 2009, 360:17-25.
129. Contreras J.L., Salmones J., García L.A., Ponce A., Zeifert B., Fuentes G.A. Hydrogen Production by Ethanol Steam Reforming over Co-Hydrotalcites Having Basic Sites. J. New Mater. Electrochem. Systems 2008, 11:109-117.
130. Contreras J.L., Ortiz M.A., Fuentes G.A., Luna R., Salmones J., Zeifert N., Nuno L., Vázquez A. Tungsten Effect over Co-Hydrotalcite Catalysts to Produce Hydrogen from Bio-Ethanol. J. New Mater. Electrochem. Systems 2010, 13:253-259.
131. He L., Bernstsen H., Ochoa-Fernández E., Walmsley J.C., Blekkan E.A., Chen D. Co-Ni Catalysts Derived from Hydrotalcite-Like Materials for Hydrogen Production by Ethanol Steam Reforming. Top. Catal. 2009, 52:206-217.
132. Lucredio A.F., Bellido J.A., Assaf E.M. Cobalt Catalysts Derived from Hydrotalcite-Type Precursors Applied to Steam Reforming of Ethanol. Catal. Commun. 2011, 12:1286-1290.
133. Espinal R., Taboada E., Molins E., Chimentao R.J., Medina F., Llorca J. Cobalt Hydrotalcite for the Steam Reforming of Ethanol with Scarce Carbon Production. RSC Adv. 2012, 2:2946-2956.
134. Da Costa-Serra J.F., Chica A. Bioethanol Steam Reforming on Co/ITQ-18 Catalyst: Effect of the Crystalline Structure of the Delaminated Zeolite ITQ-18. Int. J. Hydrogen Energy 2011, 36:3862-3869.
135. Espinal R., Taboada E., Molins E., Chimentao R.J., Medina F., Llorca J. Cobalt Hydrotalcites as Catalysts for Bioethanol Steam Reforming. The Promoting Effect of Potassium on Catalyst Activity and Long-Term Stability. Appl. Catal. B: Environ. 2012, 127:59-67.
136. Domínguez M., Taboada E., Idriss H., Molins E., Llorca J. Fast and Efficient Hydrogen Generation Catalyzed by Cobalt Talc Nanolayers Dispersed in Silica Aerogel. J. Mater. Chem. 2010, 20:4875-4883.
137. Casanovas A., Saint-Gerons M., Griffon F., Llorca J. Autothermal Generation of Hydrogen from Ethanol in a Microreactor. Int. J. Hydrogen Energy 2008, 33:1827-1833.
138. 2 Aerogel-Coated Catalytic Walls for the Generation of Hydrogen. Catal. Today 2008, 138:193-197.
139. Nedyalkova R., Casanovas A., Llorca J., Montané D. Electrophoretic Deposition of Co-Me/ZnO (Me=Mn, Fe) Ethanol Steam Reforming Catalysts on Stainless Steel Plates. Int. J. Hydrogen Energy 2009, 34:2591-2599.
140. 2 by Steady State Reactions, Temperature Programmed Desorption, and In Situ FT-IR. J. Catal. 1999, 186:279-295.
141. 2 by Temperature-Programmed Desorption and In Situ FT-IR Spectroscopy: Evidence of Benzene Formation. J. Catal. 2000, 191:30-45.
142. 2. Catal. Today 2000, 63:327-335.
143. Idriss H., Seebauer E.G. Reactions of Ethanol over Metal Oxides. J. Mol. Catal. A: Chem. 2000, 152:201-212.
144. 2 Catalysts: The Role of Rh for the Efficient Dissociation of the Carbon-Carbon Bond. J. Catal. 2002, 208:393-403.
145. Mattos L.V., Noronha F.B. Partial Oxidation of Ethanol on Supported Pt Catalysts. J. Power Sources 2005, 145:10-15.
146. 2 Catalysts: the Effect of the Reaction Conditions and Reaction Mechanism. J. Catal. 2005, 233:453-463.
147. Mattos L.V., Noronha F.B. The Influence of the Nature of the Metal on the Performance of Cerium Oxide Supported Catalysts in the Partial Oxidation of Ethanol. J. Power Sources 2005, 152:50-59.
148. 2-Supported Pt and Rh Catalysts. Catal. Today 2008, 133-135. 755-761. 27.
149. 2: the Role of Catalyst, Abstracts EuropaCat IX 2009, Catalysis for a Sustainable World, Salamanca (Spain), P8-P96.
150. Bi J.-L., Hsu S.-N., Yeh C.-T., Wang C.B. Low-Temperature Mild Partial Oxidation of Ethanol over Supported Platinum Catalysts. Catal. Today 2007, 129:330-335.
151. Hsu S.N., Bi J.L., Wang W.F., Yeh C.T., Wang C.B. Low-Temperature Partial Oxidation of Ethanol over Supported Platinum Catalysts for Hydrogen Production. Int. J. Hydrogen Energy 2008, 33:693-699.
152. 2 Catalyst Preparation and Characterization for Hydrogen Production from Ethanol Partial Oxidation. J. Mater. Sci. 2008, 43:440-449.
153. 2 Catalysts: A Comparative Study of Steam Reforming, Partial Oxidation and Oxidative Steam Reforming. J. Catal. 2008, 257:96-107.
154. 3 Catalysts. Catal. Today 2008, 138:147-151.
155. 3 catalysts for hydrogen production. Catal. Today 2007, 129:297-304.
156. Olivera Fraile R. Activity and Stability of Catalysts for Hydrogen Production by Partial Oxidation and Reforming of Ethanol 2012, Madrid, PhD Thesis, UAM, (in Spanish).
157. 2: Catalyst Role, Deactivation and Recovery, Book of abstracts 6th World Congress on Oxidation Catalysis 2009, Lille, France, poster 3C-1044.
158. 2. Appl. Catal. A: Gen. 2004, 261:171-181.
159. Silva A.M., Duarte de Farias A.M., Costa L.O.O., Barandas A.P.M.G., Mattos L.V., Fraga M.A., Noronha F.B. Partial Oxidation and Water-Gas Shift Reaction in an Integrated System for Hydrogen Production from Ethanol. Appl. Catal. A: Gen. 2008, 334:179-186.
160. Wang W., Wang Z., Ding Y., Xi J., Lu G. Partial Oxidation of Ethanol to Hydrogen over Ni-Fe Catalysts. Catal. Lett. 2002, 81:63-68.
161. Guarido C.E.M., Cesar D.V., Souza M.M.V.M., Schmal M. Ethanol Reforming and Partial Oxidation with Cu/Nb2O5 Catalyst. Catal. Today 2009, 142:252-257.
162. Rodrigues C.P., Teixeira V., Schmal M. Partial Oxidation of Ethanol on Cu/Alumina/Cordierite Monolith. Catal. Commun. 2009, 10:1697-1701.
163. Rodrigues C.P., Teixeira V., Schmal M. Partial Oxidation of Ethanol over Cobalt Oxide Based Cordierite Monolith Catalyst. Appl. Catal. B: Environ. 2010, 96:1-9.
164. Rodrigues C.P., Schmal M. Nickel-Alumina Wash Coating on Monoliths for the Partial Oxidation of Ethanol to Hydrogen Production. Int. J. Hydrogen Energy 2011, 36:10709-10718.
165. Hickman D.A., Schmidt L.D. Synthesis Gas Formation by Direct Oxidation of Methane over Pt Monoliths. J. Catal. 1992, 138:267-282.
166. Salge J.R., Deluga G.A., Schmidt L.D. Catalytic Partial Oxidation of Ethanol over Noble Metal Catalysts. J. Catal. 2005, 235:69-78.
167. Hebben N., Diehm C., Deutschmann O. Catalytic Partial Oxidation of Ethanol on Alumina-Supported Rhodium Catalysts: An Experimental Study. Appl. Catal. A: Gen. 2010, 388:225-231.
168. Loganathan K., Leclerc C.A. Partial oxidation of ethanol over platinum and platinum-tin catalysts at millisecond contact times for hydrogen production. Fuel 2012, 96:434-439.
169. Fierro V., Klouz V., Akdim O., Mirodatos C. Oxidative Reforming of Biomass Derived Ethanol for Hydrogen Production in Fuel Cell Applications. Catal. Today 2002, 75:141-144.
170. 3 Catalyst. J. Power Sources 2003, 123:10-16.
171. Vesselli E., Comelli G., Rosei R., Freni S., Fustrieri F., Cavallaro S. Ethanol Auto-Thermal Reforming on Rhodium Catalysts and Initial Steps Simulation on Single Crystals Under UHV Conditions. Appl. Catal. A: Gen. 2005, 281:139-147.
172. 2 Catalyst. Catal. Today 2008, 138:152-156.
173. Gutierrez A., Karinen R., Airaksinen S., Kaila R., Krause A.O.I. Autothermal Reforming of Ethanol on Noble Metal Catalysts. Int. J. Hydrogen Energy 2011, 36:8967-8977.
174. 2 Catalyst. J. Catal. 2008, 257:356-368.
175. Liguras D.K., Goundani K., Verykios X.E. Production of Hydrogen for Fuel Cells by Catalytic Partial Oxidation of Ethanol over Structured Ru Catalysts. Int. J. Hydrogen Energy 2004, 29:419-427.
176. Casanovas A., Llorca J., Homs N., Fierro J.L.G., Ramirez dela Piscina P. Ethanol Reforming Processes over ZnO-Supported Palladium Catalysts: Effect of Alloy Formation. J. Mol. Catal. A: Chem. 2006, 250:44-49.
177. Chen H., Yu H., Tang Y., Pan M., Yang G., Peng F., Wang H., Yang J. Hydrogen Production via Autothermal Reforming of Ethanol over Noble Metal Catalysts Supported on Oxides. J. Nat. Gas Chem. 2009, 18:191-198.
178. 2 Catalyst for Hydrogen Production. Chem. Eng. J. 2011, 167:322-327.
179. Liguras D.K., Goundani K., Verykios X.E. Production of Hydrogen for Fuel Cells by Catalytic Partial Oxidation of Ethanol over Structured Ni Catalysts. J. Power Sources 2004, 130:30-37.
180. 2 Ni Supported Catalysts. Int. J. Hydrogen Energy 2006, 31:2193-2199.
181. 3 Catalysts. Appl. Catal. B: Environ. 2008, 81:303-312.
182. Youn M.H., Seo J.G., Jung J.C., Chung J.S., Song I.K. Support Modification of Supported Nickel Catalysts for Hydrogen Production by Auto-thermal Reforming of Ethanol. Catal. Surv. Asia 2010, 14:55-63. and publications by the authors referred therein.
183. Youn M.H., Jung J.C., Lee H., Bang Y., Chung J.S., Song I.K. Hydrogen Production by Auto-Thermal Reforming of Ethanol over Nickel Catalysts Supported on Metal Oxides: Effect of Support Acidity. Appl. Catal. B: Environ. 2010, 98:57-64.
184. 2 Supports on the Properties and Performance of Ni-Rh Bimetallic Catalyst for Oxidative Steam Reforming of Ethanol. J. Catal. 2006, 238:430-440.
185. Fierro V., Akdim O., Mirodatos C. On-Board Hydrogen Production in a Hybrid Electric Vehicle by Bio-Ethanol Oxidative Steam Reforming over Ni and Noble Metal Based Catalysts. Green Chem. 2003, 5:20-24.
186. Klouz V., Fierro V., Denton P., Katz H., Lisse J.P., Bouvot-Mauduit S., Mirodatos C. Ethanol Reforming for Hydrogen Production in a Hybrid Electric Vehicle: Process Optimization. J. Power Sci. 2002, 105:26-34.
187. Fierro V., Akdim O., Provendier H., Mirodatos C. Ethanol Oxidative Reforming over Ni-Based Catalysts. J. Power Sources 2005, 145:659-666.
188. 3 Catalysts for Oxidative Steam Reforming of Ethanol. Appl. Catal. B: Environ. 2011, 105:346-360.
189. 3 in Auto-Thermal Reforming of Ethanol for Hydrogen Production. Catal. Lett. 2009, 130:432-439.
190. 2 Production from Ethanol at Room Temperature. Angew. Chem. Int. Ed. 2011, 50:10193-10197.
191. 2 catalysts: Catalytic behavior and deactivation/regeneration processes. J. Catal. 2008, 257:206-214.
192. 2 for the Oxidative Steam Reforming of Ethanol. Catal. Today 2011, 164:234-239.
193. 2 catalyst deactivation during oxidative steam reforming of ethanol. Catal. Commun. 2010, 11:736-740.
194. Da Silva A.M., Mattos L.V., den Breejen J.P., Bitter J.H., de Jong K.P., Noronha F.B. Oxidative Steam Reforming of Ethanol over Carbon Nanofiber Supported Co Catalysts. Catal. Today 2011, 164:262-267.
195. xZnAl-Mixed Metal Oxide Catalysts Used in the Oxidative Reforming of Bio-Ethanol. Appl. Catal. B: Environ. 2005, 55:287-299.
196. 4.5±δ Catalysts. Appl. Catal. A: Gen. 2011, 393:302-308.
197. Guil-López R., Navarro R.M., Peña M.A., Fierro J.L.G. Hydrogen Production by Oxidative Ethanol Reforming on Co, Ni and Cu Ex-Hydrotalcite Catalysts. Int. J. Hydrogen Energy 2011, 36:1512-1523.
198. 3. Chem. Eng. J. 2010, 160:333-339.
199. Huang L., Zhang F., Wang N., Chen R., Hsu A.T. Nickel-Based Perovskite Catalysts with Iron-Doping via Self-Combustion for Hydrogen Production in Auto-Thermal Reforming of Ethanol. Int. J. Hydrogen Energy 2012, 37:1272-1279.
200. Gallucci F., Basile A. Pd-Ag Membrane Reactor for Steam Reforming Reactions: A Comparison between Different Fuels. Int. J. Hydrogen Energy 2008, 33:1671-1687.
201. Basile A. Hydrogen Production Using Pd-Based Membrane Reactors for Fuel Cells. Top. Catal. 2008, 51:107-122.
202. Mendes D., Tosti S., Borgognoni F., Mendes A., Madeira L.M. Integrated Analysis of a Membrane-Based Process for Hydrogen Production from Ethanol Steam Reforming. Catal. Today 2010, 156:107-117.
203. Tosti S., Bettinali L. Diffusion Bonding of Pd-Ag Membranes. J. Mater. Sci. 2004, 39:3041-3046.
204. Tosti S., Basile A., Bettinali L., Borgognoni F., Chiaravalloti F., Gallucci F. Long-Term Tests of Pd-Ag Thin Wall Permeator Tube. J. Membr. Sci. 2006, 284:393-397.
205. Tong H.D., Gielens F.C., Gardeniers J.G.E., Jansen H.V., van Rijn C.J.M., Elwenspoek M.C., Nijdam W. Microfabricated Palladium-Silver Alloy Membranes and Their Application in Hydrogen Separation. Ind. Eng. Chem. Res. 2004, 43:4182-4187.
206. Burkhanov G.S., Gorina N.B., Kolchugina N.B., Roshan N.R. Palladium-Based Alloy Membranes for Separation of High Purity Hydrogen from Hydrogen-Containing Gas Mixtures. Platin. Met. Rev. 2011, 55:3-12.
207. Tosti S., Basile A., Borgognoni F., Capaldo V., Cordiner S., Di Cave S., Gallucci F., Rizzello C., Santucci A., Traversa E. Low Temperature Ethanol Steam Reforming in a Pd-Ag Membrane Reactor. Part 1: Pt-Based and Ni-Based Catalyst and General Comparison. J. Membr. Sci. 2008, 308:258-263.
208. Montané D., Bolshak E., Abelló S. Thermodynamic Analysis of Fuel Processors Based on Catalytic-Wall Reactors and Membrane Systems for Ethanol Steam Reforming. Chem. Eng. J. 2011, 175:519-533.
209. Gallucci F., Van Sint Annaland M., Kuipers J.A.M. Pure Hydrogen Production via Autothermal Reforming of Ethanol in a Fluidized Bed Membrane Reactor: A Simulation Study. Int. J. Hydrogen Energy 2010, 35:1659-1668.
210. Gao H., Lin Y.S., Li Y., Zhang B. Chemical Stability and Its Improvement of Palladium-Based Metallic Membranes. Ind. Eng. Chem. Res. 2004, 43:6920-6930.
211. Iulianelli A., Basile A. Hydrogen Production from Ethanol via Inorganic Membrane Reactors Technology: A Review. Catal. Sci. Technol. 2011, 1:366-379.
212. Gallucci F., Basile A., Tosti S., Iulianelli A., Drioli E. Methanol and Ethanol Steam Reforming in Membrane Reactors: An Experimental Study. Int. J. Hydrogen Energy 2007, 32:1201-1210.
213. Basile A., Gallucci F., Iulianelli A., Tosti S. CO-Free Hydrogen Production by Ethanol Steam Reforming in a Pd-Ag Membrane Reactor. Fuel Cells 2008, 8:62-68.
214. Tosti S., Basile A., Bettinali L., Borgognoni F., Gallucci F., Rizello C. Design and Process Study of Pd Membrane Reactors. Int. J. Hydrogen Energy 2008, 33:5098-5105.
215. Tosti S., Basile A., Borgognoni F., Capaldo V., Cordiner S., Di Cave S., Gallucci F., Rizzello C., Santucci A., Traversa E. Low Temperature Ethanol Steam Reforming in a Pd-Ag Membrane Reactor. Part 1: Ru-Based Catalyst. J. Membr. Sci. 2008, 308:250-257.
216. Tosti S., Basile A., Borelli R., Borgognoni F., Castelli S., Fabbricino M., Gallucci F., Licusati C. Ethanol Steam Reforming Kinetics of a Pd-Ag Membrane Reactor. Int. J. Hydrogen Energy 2009, 34:4747-4754.
217. Tosti S., Fabbricino M., Moriani A., Agatiello G., Scudieri C., Borgognoni F., Santucci A. Pressure Effect in Ethanol Steam Reforming via Dense Pd-Based Membranes. J. Membr. Sci. 2011, 377:65-74.
218. 3 Catalyst in a Dense Pd-Ag Membrane Reactor to Produce Hydrogen for PEM Fuel Cells. Int. J. Hydrogen Energy 2009, 34:8558-8565.
219. 3 Catalyst in a Pd-Based Membrane Reactor. Int. J. Hydrogen Energy 2011, 36:1503-1511.
220. Iulianelli A., Liguori S., Calabrò V., Pinacci P., Basile A. Partial Oxidation of Ethanol in a Membrane Reactor for High Purity Hydrogen Production. Int. J. Hydrogen Energy 2010, 35:12626-12634.
221. Iulianelli A., Basile A. An Experimental Study on Bio-Ethanol Steam Reforming in a Catalytic Membrane Reactor. Part I: Temperature and Sweep-Gas Flow Configuration Effects. Int. J. Hydrogen Energy 2010, 35:3170-3177.
222. Iulianelli A., Liguori S., Longo T., Tosti S., Pinacci P., Basile A. An Experimental Study on Bio-Ethanol Steam Reforming in a Catalytic Membrane Reactor. Part II: Reaction Pressure, Sweep Factor and WHSV Effects. Int. J. Hydrogen Energy 2010, 35:3159-3164.
223. Basile A., Pinacci P., Iulianelli A., Broglia M., Drago F., Liguori S., Longo T., Calabrò V. Ethanol Steam Reforming Reaction in a Porous Stainless Steel Supported Palladium Membrane Reactor. Int. J. Hydrogen Energy 2011, 36:2029-2037.
224. Seelam P.K., Liguori S., Iulianelli A., Pinacci P., Calabrà V., Huuhtanen M., Keiski R., Piemonte V., Tosti S., de Falco M., Basile A. Hydrogen Production from Bio-Ethanol Steam Reforming in a Pd/PSS Membrane Reactor. Catal. Today 2012, 193:42-48.
225. Lin W.H., Hsiao C.S., Chang H.F. Effect of Oxygen Addition on the Hydrogen Production from Ethanol Steam Reforming in a Pd-Ag Membrane Reactor. J. Membr. Sci. 2008, 322:360-367.
226. Lin W.H., Liu Y.C., Chang H.F. Autothermal Reforming of Ethanol in a Pd-Ag/Ni Composite Membrane Reactor. Int. J. Hydrogen Energy 2010, 35:12961-12969.
227. Papadias D.D., Lee S.H.D., Ferrandon M., Ahmed S. An Analytical and Experimental Investigation of High-Pressure Catalytic Steam Reforming of Ethanol on a Hydrogen Selective Membrane Reactor. Int. J. Hydrogen Energy 2010, 35:2004-2017.
228. Domínguez M., Taboada E., Molins E., Llorca J. Ethanol Steam Reforming at Very Low Temperature over Cobalt Talc in a Membrane Reactor. Catal. Today 2012, 193:101-106.
229. 2 with a Metallic Membrane Reactor. Catal. Today 2012, 193(1):145-150.
230. Yu C.Y., Lee D.W., Park S.J., Lee K.Y., Lee K.H. Ethanol Steam Reforming in a Membrane Reactor with Pt-Impregnated Knudsen Membranes. Appl. Catal. B: Environ. 2009, 86:121-126.
231. Yu C.Y., Lee D.W., Park S.J., Lee K.Y., Lee K.H. Study on a Catalytic Membrane Reactor for Hydrogen Production from Ethanol Steam Reforming. Int. J. Hydrogen Energy 2009, 34:2947-2954.
232. Lim H., Gu Y., Oyama S.T. Reaction of Primary and Secondary Products in a Membrane Reactor: Studies of Ethanol Steam Reforming with a Silica-Alumina Composite Membrane. J. Membr. Sci. 2010, 351:149-159.
233. Lim H., Gu Y., Oyama S.T. Studies of the Effect of Pressure and Hydrogen Permeance on the Ethanol Steam Reforming Reaction with Palladium- and Silica-Based Membranes. J. Membr. Sci. 2012, 396:119-127.
234. Zhu N., Dong X., Liu Z., Zhang G., Jin W., Xu N. Toward High-Effective and Sustainable Hydrogen Production: Bio-Ethanol Oxidative Steam Reforming Coupled with Water Splitting in a Thin Tubular Membrane Reactor. Chem. Comm. 2012, 48:7137-7139.
235. Kolb G. Fuel Processing for Fuel Cells 2008, Wiley-VCH.
236. Ehrfeld W., Hessel V., Löwe H. Microreactors: New Technology for Modern Chemistry 2000, Wiley-VCH.
237. Palo D.R., Dagle R.A., Holladay J.D. Methanol Steam Reforming for Hydrogen Production. Chem. Rev. 2007, 107:3992-4021.
238. Llorca J. Microreactors for the Generation of Hydrogen from Ethanol. Handbook of Sustainable Energy 2010, 693-699. (chapter 22), Nova Science Publishers. W.H. Lee, V.G. Cho (Eds.).
239. Men Y., Kolb G., Zapf R., Hessel V., Löwe H. Ethanol Steam Reforming in a Microchannel Reactor. Process Saf. Environ. Prot. 2007, 85:413-418.
240. Görke O., Pfeifer P., Schubert K. Kinetic Study of Ethanol Reforming in a Microreactor. Appl. Catal. A: Gen. 2009, 360:232-241.
241. Cai W., Wang F., van Veen A., Descorme C., Schuurman Y., Shen W., Mirodatos C. Hydrogen Production from Ethanol Steam Reforming in a Micro-Channel Reactor. Int. J. Hydrogen Energy 2010, 35:1152-1159.
242. Peela N.R., Kunzru D. Steam Reforming of Ethanol in a Microchannel Reactor: Kinetic Study and Reactor Simulation. Ind. Eng. Chem. Res. 2011, 50:12881-12894.
243. Domínguez M., Cristiano G., López E., Llorca J. Ethanol Steam Reforming over Cobalt Talc in a Plate Microreactor. Chem. Eng. J. 2011, 176-177:280-285.
244. 2 Generation by a Catalytic Hollow Fiber Microreactor for Portable Device Applications. Catal. Commun. 2011, 16:128-132.
245. Rahman M.A., García-García F.R., Li K. Development of a Catalytic Hollow Fiber Membrane Microreactor as a Microreformer Unit for Automotive Application. J. Membr. Sci. 2012, 390-391:68-75.
246. Kolb G., Men Y., Schelhaas K.P., Tiemann D., Zapf R., Wilhelm J. Development Work on a Microstructured 50 kW Ethanol Fuel Processor for a Small-Scale Stationary Hydrogen Supply System. Ind. Eng. Chem. Res. 2011, 50:2554-2561.
247. Llorca J., Casanovas A., Trifonov T., Rodriguez A., Alcubilla R. First Use of Macroporous Silicon Loaded with Catalyst Film for a Chemical Reaction: A Microreformer for Producing Hydrogen from Ethanol Steam Reforming. J. Catal. 2008, 255:228-233.
248. López E., Irigoyen A., Trifonov T., Rodríguez A., Llorca J. A Million-Channel Reformer on a Fingertip: Moving Down the Scale in Hydrogen Production. Int. J. Hydrogen Energy 2010, 35:3472-3479.
249. x Microreactor on a Fingertip for Fuel Cell Application. Chem. Eng. J. 2010, 167:597-602.
250. Carneiro J., Berger R., Moulijn J.A., Mul G. An Internally Illuminated Monolith Reactor: Pros and Cons Relative to a Slurry Reactor. Catal. Today 2009, 147S:S324-S329.
251. Du P., Carneiro J.T., Moulijn J.A., Mul G. A Novel Photocatalytic Monolith Reactor for Multiphase Heterogeneous Photocatalysis. Appl. Catal. A: Gen. 2008, 334:119-128.
252. 2 catalysts (M=Pd, Pt or Rh). Appl. Catal. B: Environ. 2006, 67:217-222.
253. Kudo A., Miseki Y. Heterogeneous Photocatalyst Materials for Water Splitting. Chem. Soc. Rev. 2009, 38:253-278.
254. 2 Catalysts. Int. J. Hydrogen Energy 2009, 34:125-129.
255. 2 on Its Performance as a Photocatalyst for Water Cleavage. J. Phys. Chem. 1993, 1993(97):1184-1189.
256. 2 Nanotube Arrays with High Aspect Ratios for Efficient Solar Water Splitting. Nano Lett. 2006, 6:24-28.
257. 2 Photocatalysts for Hydrogen Production and Simultaneous Degradation of Inorganic or Organic Sacrificial Agents in Wastewater. Environ. Sci. Technol. 2010, 44:7200-7205.
258. Dhanalakshmi K.B., Latha S., Anandan S., Maruthamuthu P. Dye Sensitized Hydrogen Evolution from Water. Int. J. Hydrogen Energy 2001, 26:669-674.
259. Fujishima A., Honda K. Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature 1972, 238:37-38.
260. Blount M.C., Buchholz J.A., Falconer J.L. Photocatalytic Decomposition of Aliphatic Alcohols, Acids and Esters. J. Catal. 2001, 197:303-314.
261. Hashimoto K., Kawai T., Sakata T. Photocatalytic Reactions of Hydrocarbons and Fossil Fuels with Water. Hydrogen Production and Oxidation. J. Phys. Chem. 1984, 88:4083-4088.
262. Kondarides D.I., Daskalaki V.M., Patsoura A., Verykios X.E. Hydrogen Production by Photo-Induced Reforming of Biomass Components and Derivatives at Ambient Conditions. Catal. Lett. 2008, 122:26-32.
263. 2. J. Photochem. Photobio. A: Chem. 1995, 89:177-189.
264. Strataki N., Bekiari V., Kondarides D., Lianos P. Hydrogen Production by Photocatalytic Alcohol Reforming Employing Highly Efficient Nanocrystalline Titania Films. Appl. Catal. B: Environ. 2007, 77:184-189.
265. Strataki N., Boukos N., Paloukis F., Neophytides S.G., Lianos P. Effect of the Conditions of Platinum Deposition on Titania Nanocrystalline Films on the Efficiency of Photocatalytic Oxidation of Ethanol and Production of Hydrogen. Photochem. Photobio. Sci. 2009, 8:639-643.
266. 2/Metal Nanocomposites. J. Photochem. Photobio. A: Chem. 2008, 198:126-134.
267. 2 Anatase: Comparing the Micro to Nanoparticle Size Activities of the Support for Hydrogen Production. J. Photochem. Photobio. A: Chem. 2010, 216:250-255.
268. 2. Nat. Chem. 2011, 3:489-492.
269. 2 Catalysts. Investigating the Synergistic Effect of Nanoparticles. Int. J. Nanotechnol. 2012, 9:1/2.
270. 2 by the Sonochemical Methods: Photocatalytic Production of Hydrogen from an Aqueous Solution of Ethanol. Ultrason. Sonochem. 2007, 14:387-392.
271. Casanovas A., Domínguez M., Ledesma C., Lopez E., Llorca J. Catalytic Walls and Micro-Devices for Generating Hydrogen by low Temperature Steam Reforming of Ethanol. Catal. Today 2009, 143:32-37.
272. Peela N.R., Kunzru D. Oxidative Steam Reforming of Ethanol over Rh Based Catalysts in a Micro-Channel Reactor. Int. J. Hydrogen Energy 2011, 36:3384-3396.