Oxidative steam reforming of ethanol over Rh based catalysts in a micro-channel reactor

International Journal of Hydrogen Energy

Volumn 36, Issue 5, 2011, Pages 3384-3396

  Peela, Nageswara Rao ^a   Kunzru, Deepak ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY KANPUR   (India)

Author keywords

Ethanol; Hydrogen production; Micro channel reactor; Oxidative steam reforming; Rhodium catalyst

Indexed keywords

ACTIVE METALS; CATALYST LAYERS; DIFFUSIONAL EFFECTS; METALLIC SUBSTRATE; MICRO CHANNEL REACTORS; MICRO-CHANNEL REACTOR; MOLAR RATIO; OPERATING CONDITION; OXIDATIVE STEAM REFORMING; OXIDATIVE STEAM REFORMING OF ETHANOLS; PACKED BED REACTOR; RH-BASED CATALYST; RHODIUM CATALYST; STABILITY TESTS; SUPPORT COMPOSITION; TEMPERATURE RANGE; WASH-COATING;

ALUMINUM; ATMOSPHERIC COMPOSITION; ATMOSPHERIC PRESSURE; CATALYST SUPPORTS; CERIUM COMPOUNDS; CHEMICAL REACTORS; ETHANOL; HYDROGEN PRODUCTION; METALS; OXYGEN; PACKED BEDS; PRESSURE EFFECTS; RHODIUM; STEAM; STEAM ENGINEERING;

STEAM REFORMING;

EID: 79952242785     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.12.091     Document Type: Article

References (49)

1. M. Ni, D.Y.C. Leung, and M.K.H. Leung A review on reforming bio-ethanol for hydrogen production Int J Hydrogen Energy 32 2007 3238 3247 (Pubitemid 47562217)
2. G. Kolb, and V. Hessel Micro-structured reactors for gas phase reactions Chem Eng J 98 2004 1 38 (Pubitemid 38345845)
3. L. Kiwi-Minsker, and A. Renken Microstructured reactors for catalytic reactions Catal Today 110 2005 2 14
4. P.D. Vaidya, and A.E. Rodrigues Insight into steam reforming of ethanol to produce hydrogen for fuel cells Chem Eng J 117 2006 39 49 (Pubitemid 43238292)
5. A. Haryanto, S. Fernando, N. Murali, and S. Adhikari Current status of hydrogen production techniques by steam reforming of ethanol: a review Energy Fuels 19 2005 2098 2106
6. M.K. Moharana, N.R. Peela, S. Khandekar, and D. Kunzru Distributed hydrogen production from ethanol in a microfuel processor: issues and challenges Renew Sust Energy Rev 15 2011 524 533
7. G.A. Deluga, J.R. Salge, L.D. Schmidt, and X.E. Verykios Renewable hydrogen from ethanol by autothermal reforming Science 303 2004 993 997 (Pubitemid 38209699)
8. 2 catalyst Catal Today 138 2008 152 156
9. G. Jacobs, R.A. Keogh, and B.H. Davis Steam reforming of ethanol over Pt/ceria with co-fed hydrogen J Catal 245 2007 326 337 (Pubitemid 46037681)
10. 2 catalyst J Catal 257 2008 356 368
11. J.R. Salge, G.A. Deluga, and L.D. Schmidt Catalytic partial oxidation of ethanol over noble metal catalysts J Catal 235 2005 69 78
12. 2 catalysts: a comparative study of steam reforming, partial oxidation and oxidative steam reforming J Catal 257 2008 96 107
13. J.-L. Bi, Y.-Y. Hong, C.-C. Lee, C.-T. Yeh, and C.-B. Wang Novel zirconia-supported catalysts for low-temperature oxidative steam reforming of ethanol Catal Today 129 2007 322 329 (Pubitemid 350101112)
14. 2 catalyst Catal Commun 8 2007 1588 1594 (Pubitemid 47419461)
15. 2: effect of metal and support on reaction mechanism Top Catal 51 2008 22 38
16. 2-supported Ni-Rh bimetallic catalysts for hydrogen production Catal Lett 101 2005 255 264
17. 3 modified with Ce and La Appl Catal B Environ 55 2005 229 241
18. 2 catalysts: catalytic behavior and deactivation/regeneration processes J Catal 257 2008 206 214
19. N. Laosiripojana, S. Assabumrungrat, and S. Charojrochkul Steam reforming of ethanol with co-fed oxygen and hydrogen over Ni on high surface area ceria support Appl Catal A Gen 327 2007 180 188 (Pubitemid 47031617)
20. 2 catalyst Chem Eng J 136 2008 41 49 (Pubitemid 350257028)
21. 2 Int J Hydrogen Energy 34 2009 2224 2234
22. V. Fierro, O. Akdim, and C. Mirodatos On-board hydrogen production in a hybrid electric vehicle by bio-ethanol oxidative steam reforming over Ni and noble metal based catalysts Green Chem 5 2003 20 24 (Pubitemid 37465258)
23. W.-H. Lin, Y.-C. Liu, and H.-F. Chang Autothermal reforming of ethanol in a Pd-Ag/Ni composite membrane reactor Int J Hydrogen Energy 35 2010 12961 12969
24. 3 catalyst in a dense Pd-Ag membrane reactor to produce hydrogen for PEM fuel cells Int J Hydrogen Energy 34 2009 8558 8565
25. W. Cai, F. Wang, A. van Veen, C. Descorme, Y. Schuurman, and W. Shen Hydrogen production from ethanol steam reforming in a micro-channel reactor Int J Hydrogen Energy 35 2010 1152 1159
26. O. Görke, P. Pfeifer, and K. Schubert Kinetic study of ethanol reforming in a microreactor Appl Catal A Gen 360 2009 232 241
27. A. Casanovas, C. de Leitenburg, A. Trovarelli, and J. Llorca Catalytic monoliths for ethanol steam reforming Catal Today 138 2008 187 192
28. A. Casanovas, M. Domínguez, C. Ledesma, E. López, and J. Llorca Catalytic walls and micro-devices for generating hydrogen by low temperature steam reforming of ethanol Catal Today 143 2009 32 37
29. A. Casanovas, J. Llorca, N. Homs, J.L.G. Fierro, and P. Ramírez de la Piscina Ethanol reforming processes over ZnO-supported palladium catalysts: effect of alloy formation J Mol Catal A Chem 250 2006 44 49
30. A. Casanovas, M. Saint-Gerons, F. Griffon, and J. Llorca Autothermal generation of hydrogen from ethanol in a microreactor Int J Hydrogen Energy 33 2008 1827 1833
31. J. Llorca, A. Casanovas, T. Trifonov, A. Rodríguez, and R. Alcubilla First use of macroporous silicon loaded with catalyst film for a chemical reaction: a microreformer for producing hydrogen from ethanol steam reforming J Catal 255 2008 228 233
32. Y. Men, G. Kolb, R. Zapf, V. Hessel, and H. Löwe Ethanol steam reforming in a microchannel reactor Process Saf Environ Protect 85 2007 413 418 (Pubitemid 47477511)
33. P. Ciambelli, V. Palma, and E. Palo Comparison of ceramic honeycomb monolith and foam as Ni catalyst carrier for methane autothermal reforming Catal Today 155 2010 92 100
34. J.M. Commenge, L. Falk, J.P. Corriou, and M. Matlosz Optimal design for flow uniformity in microchannel reactors AIChE J 48 2002 345 358 (Pubitemid 37442382)
35. N.R. Peela, A. Mubayi, and D. Kunzru Washcoating of γ-alumina on stainless steel microchannels Catal Today 147 2009 S17 S23
36. 3 catalysts in a microchannel reactor. Chem Eng J, in press, doi:10.1016/j.cej.2010.09.081.
37. Y. Li, X. Wang, C. Xie, and C. Song Influence of ceria and nickel addition to alumina-supported Rh catalyst for propane steam reforming at low temperatures Appl Catal A Gen 357 2009 213 222
38. R. Dictor, and S. Roberts Influence of ceria on alumina-supported rhodium: observations of rhodium morphology made using FTIR spectroscopy J Phys Chem 93 1989 5846 5850
39. R. Burch, P.K. Loader, and N.A. Cruise An investigation of the deactivation of Rh/alumina catalysts under strong oxidising conditions Appl Catal A Gen 147 1996 375 394 (Pubitemid 126391680)
40. 2 solid-solutions as highly efficient oxygen exchangers: dependence of the reduction behavior and the oxygen storage capacity on the structural-properties J Catal 151 1995 168 177
41. 2 catalysts Catal Commun 3 2002 565 571 (Pubitemid 41087689)
42. D.K. Liguras, D.I. Kondarides, and X.E. Verykios Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts Appl Catal B Environ 43 2003 345 354 (Pubitemid 36837496)
43. 3 catalyst Appl Catal B Environ 49 2004 135 144 (Pubitemid 38448835)
44. 3 nanocomposites: active and stable catalysts for ethanol steam reforming Appl Catal B Environ 71 2007 125 134 (Pubitemid 46123953)
45. D. Duprez, P. Pereira, A. Miloudi, and R. Maurel Steam dealkylation of aromatic hydrocarbons: II. Role of the support and kinetic pathway of oxygenated species in toluene steam dealkylation over group VIII metal catalysts J Catal 75 1982 151 163
46. 2 structure on the activity of supported Pd catalysts used for methane steam reforming Appl Catal A Gen 230 2002 153 168 (Pubitemid 34284592)
47. 3 catalysts Int J Hydrogen Energy 35 2010 1138 1146
48. E. Vesselli, G. Comelli, R. Rosei, S. Freni, F. Frusteri, and S. Cavallaro Ethanol auto-thermal reforming on rhodium catalysts and initial steps simulation on single crystals under UHV conditions Appl Catal A Gen 281 2005 139 147
49. S. Cavallaro, N. Mondello, and S. Freni Hydrogen produced from ethanol for internal reforming molten carbonate fuel cell J Power Sources 102 2001 198 204 (Pubitemid 34086224)