Hydrogen production by oxidative ethanol reforming on Co, Ni and Cu ex-hydrotalcite catalysts

International Journal of Hydrogen Energy

Volumn 36, Issue 2, 2011, Pages 1512-1523

  Guil Lopez R ^a   Navarro, R M ^a   Pena M A ^a   Fierro, J L G ^a  

^a INSTITUTO DE CATÁLISIS Y PETROLEOQUÍMICA   (Spain)

Author keywords

Co , Ni , Cu catalysts; Ethanol oxidative reforming; ex LDH; Hydrogen; Hydrotalcites

Indexed keywords

ACTIVE METAL OXIDES; ACTIVE METALS; AMORPHOUS MATRICES; AUTO-THERMAL; CHEMICAL TECHNIQUES; CO-, NI-, CU-CATALYSTS; CRYSTALLINITIES; CU OXIDE; ETHANOL CONVERSION; ETHANOL REFORMING; EX-LDH; HYDROTALCITE CATALYSTS; HYDROTALCITES; MOLAR RATIO; OXIDATIVE STEAM REFORMING OF ETHANOLS; OXIDATIVE STEAM REFORMING REACTION; PRODUCTION VALUE; SMALL PARTICLE SIZE; STRONG INTERACTION; TEMPERATURE RANGE; UREA HYDROLYSIS;

ALUMINUM; CALCINATION; CATALYSTS; ETHANOL; HYDROGEN PRODUCTION; METALLIC COMPOUNDS; METALS; NICKEL COMPOUNDS; STEAM ENGINEERING; UREA;

STEAM REFORMING;

EID: 79551504090     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.10.084     Document Type: Article

References (37)

1. 3 catalyst in a dense Pd-Ag membrane reactor to produce hydrogen for PEM fuel cells Int J Hydrogen Energy 34 2009 8558 8565
2. N. Briguglio, L. Andaloro, M. Ferraro, A. Di Blasi, G. Dispenza, and F. Matteucci Renewable energy for hydrogen production and sustainable urban mobility Int J Hydrogen Energy 35 2010 9996 10003
3. R.M. Navarro, M.A. Pena, and J.L.G. Fierro Hydrogen production reactions from carbon feedstocks: fossils fuels and biomass Chem Rev 107 2007 3952 3991
4. D.K. Liguras, K. Goundani, and X.E.X.E. Verykios Production of hydrogen for fuel cells by catalytic partial oxidation of ethanol over structured Ru catalysts Int J Hydrogen Energy 29 2004 419 427
5. 2 Int J Hydrogen Energy 34 2009 2224 2234
6. C. Resini, T. Montanari, L. Barattini, G. Ramis, G. Busca, and S. Presto Hydrogen production by ethanol steam reforming over Ni catalysts derived from hydrotalcite-like precursors: catalyst characterization, catalytic activity and reaction path Appl Catal A Gen 355 2009 83 93
7. y-Pd catalysts Int J Hydrogen Energy 35 2010 11829 11843
8. 3 modified with Ce and La Appl Catal B 55 2005 229 241
9. 2 Ni supported catalysts Int J Hydrogen Energy 31 2006 2193 2199
10. M. Ni, D.Y.C. Leung, and M.K.H. Leung A review on reforming bio-ethanol for hydrogen production Int J Hydrogen Energy 32 2007 3238 3247
11. N. Palmeri, S. Cavallaro, V. Chiodo, S. Freni, F. Frusteri, and J.C.J. Bart Hydrogen production from ethanol on Rh/MgO based catalysts: the influence of rhodium precursor on catalytic performance Int J Hydrogen Energy 32 2007 3335 3342
12. J. Llorca, N. Homs, J. Sales, and P. Ramírez de la Piscina Efficient production of hydrogen over supported cobalt catalysts from ethanol steam reforming J Catal 209 2002 306 317
13. 2 catalyst J Catal 268 2009 268 281
14. A. Chica, and S. Sayas Effective and stable bioethanol steam reforming catalyst based on Ni and Co supported on all-silica delaminated ITQ-2 Catal Today 146 2009 37 43
15. W. Cai, F. Wang, A. van Veen, C. Descorme, Y. Schuurman, and W. Shen Hydrogen production from ethanol steam reforming in a micro-channel reactor Int J Hydrogen Energy 35 2010 1152 1159
16. 3 catalysts: effect of Ni Int J Hydrogen Energy 26 2001 665 668
17. 3 supported catalysts for ethanol steam reforming: formation of hydrotalcite-type compounds as a result of metal-support interaction Appl Catal A Gen 238 2003 41 54
18. G. Busca, U. Costantino, T. Montanari, G. Ramis, C. Resini, and M. Sisani Nickel versus cobalt catalysts for hydrogen production by ethanol steam reforming: Ni-Co-Zn-Al catalysts from hydrotalcite-like precursors Int J Hydrogen Energy 35 2010 5356 5366
19. 3 (M=Ce, La, Zr and Mg) catalysts: influence of support on the hydrogen production Int J Hydrogen Energy 32 2007 1462 1471
20. A.J. Vizcaíno, A. Carrero, and J.A. Calles Ethanol steam reforming on Mg- and Ca-modified Cu-Ni/SBA-15 catalysts Catal Today 146 1-2 2009 63 70
21. F. Cavani, F. Trifiro, and A. Vaccari Hydrotalcite-type anionic clays: preparation, properties and applications Catal Today 11 1991 173 301 [and references therein]
22. W. Feitknecht The formation of double hydroxides between bi- and tri-valent metals Helv Chim Acta 25 1942 555 569
23. M. Li, X. Wang, S. Li, S. Wang, and X. Ma Hydrogen production from ethanol steam reforming over nickel based catalyst derived from Ni/Mg/Al hydrotalcite-like compounds Int J Hydrogen Energy 35 2010 6699 6708
24. S. Miyata Anion-exchange properties of hydrotalcite-like compounds Clay Clay Miner 31 1983 305 311
25. L. Dussault, J.C. Dupin, E. Dumitriu, A. Auroux, and C. Guimon Microcalorimetry, TPR and XPS studies of acid-base properties of NiCuMgAl mixed oxides using LDHs as precursors Thermochim Acta 434 2005 93 99
26. V. Mas, M.L. Dieuzeide, M. Jobbágy, G. Baronetti, N. Amadeo, and M. Laborde Ni(II)-Al(III) layered double hydroxide as catalyst precursor for ethanol steam reforming: activation treatments and kinetic studies Catal Today 133-135 2008 319 323
27. F. Basile, L. Basini, M. D'Amore, G. Fornasari, A. Guarinoni, and D. Matteuzzi Ni/Mg/Al anionic clay derived catalysts for the catalytic partial oxidation of methane: residence time dependence of the reactivity features J Catal 173 1998 247 256
28. S. Liu, D. Chen, K. Zhang, J. Li, and N. Zhao Production of hydrogen by ethanol steam reforming over catalysts from reverse microemulsion-derived nanocompounds Int J Hydrogen Energy 33 2008 3736 3747
29. A. Romero, M. Jobbágy, M. Laborde, G. Baronetti, and N. Amadeo Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: influence of the activation treatments Catal Today 149 2010 407 412
30. 3 catalysts from a hydrotalcite-like LDH precursor J Catal 228 2004 43 55
31. Joint Committee on Powder Diffraction Standard, International Centre for Diffraction Data, Pennsylvania, 1997.
32. 2 from nitrate solution Acta Chim Slov 2 2 2009 14 20
33. V. Rives Characterisation of layered double hydroxides and their decomposition products Mater Chem Phys 75 2002 19 25
34. R.D. Shannon Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Cryst A32 1976 751 767
35. R.L. Frost, A.W. Musumeci, T. Bostrom, M.O. Adebajo, M.L. Weier, and W. Martens Thermal decomposition of hydrotalcite with cromate, molybdate or sulphate in the interlayer Thermochim Acta 429 2005 179 187
36. T. Kameda, T. Yoshioka, K. Watanabe, M. Uchida, and A. Okuwaki Dehydrochlorination behavior of a chloride ion-intercalated hydrotalcite-like compound during thermal decomposition Appl Clay Sci 35 2007 173 179
37. P. Benito, M. Herrero, F.M. Labajos, V. Rives, C. Royo, and N. Latorre Production of carbon nanotubes from methane: use of Co-Zn-Al catalysts prepared by microwave-assisted synthesis Chem Eng J 149 2009 455 462