Reply to "comment on 'water's structure around hydrophobic solutes and the iceberg model'"

Journal of Physical Chemistry B

Volumn 118, Issue 9, 2014, Pages 2600-2603

  Galamba, N ^a  

^a UNIVERSITY OF LISBON   (Portugal)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84897732048     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp501450n     Document Type: Note

References (39)

1. Frank, H. S.; Evans, M. W. Free Volume and Entropy in Condensed Systems. 3. Entropy in binary liquid mixures-partial molal entropy in dilute solutions-structure and thermodynamics in aqueous electrolytes J. Chem. Phys. 1945, 13, 507-532
2. Chandler, D. Interfaces and the driving force of hydrophobic assembly Nature 2005, 437, 640-647
3. Southall, N. T.; Dill, K. A.; Haymet, A. D. J. A view of the hydrophobic effect J. Phys. Chem. B 2002, 106, 521-533
4. Ashbaugh, H. S.; Pratt, L. R. Colloquium: Scaled particle theory and the length scales of hydrophobicity Rev. Mod. Phys. 2006, 78, 159-178
5. Ashbaugh, H. S.; Truskett, T. M.; Debenedetti, P. G. A simple molecular thermodynamic theory of hydrophobic hydration J. Chem. Phys. 2002, 116, 2907-2921
6. Ben-Amotz, D.; Underwood, R. Unraveling Water's Entropic Mysteries: A Unified View of Nonpolar, Polar, and Ionic Hydration Acc. Chem. Res. 2008, 41, 957-967
7. Gill, S. J.; Dec, S. F.; Olofsson, G.; Wadso, I. Anomalous Heat Capacity of Hydrophobic Solvation J. Phys. Chem. 1985, 89, 3758-3761
8. Graziano, G. On the size dependence of hydrophobic hydration J. Chem. Soc., Faraday Trans. 1998, 94, 3345-3352
9. Graziano, G.; Lee, B. On the intactness of hydrogen bonds around nonpolar solutes dissolved in water J. Phys. Chem. B 2005, 109, 8103-8107
10. Hummer, G.; Garde, S.; Garcia, A. E.; Paulaitis, M. E.; Pratt, L. R. Hydrophobic effects on a molecular scale J. Phys. Chem. B 1998, 102, 10469-10482
11. Hummer, G.; Garde, S.; Garcia, A. E.; Pohorille, A.; Pratt, L. R. An information theory model of hydrophobic interactions Proc. Natl. Acad. Sci. U.S.A. 1996, 93, 8951-8955
12. Hummer, G.; Pratt, L. R.; Garcia, A. E. Free energy of ionic hydration J. Phys. Chem. 1996, 100, 1206-1215
13. Lee, B. The Physical Origin of the Low Solubility of Nonpolar Solutes in Water Biopolymers 1985, 24, 813-823
14. Lee, B. Solvent Reorganization Contribution to the Transfer Thermodynamics of Small Nonpolar Molecules Biopolymers 1991, 31, 993-1008
15. Lee, B.; Graziano, G. A two-state model of hydrophobic hydration that produces compensating enthalpy and entropy changes J. Am. Chem. Soc. 1996, 118, 5163-5168
16. Lucas, M. Size Effect in Transfer of Nonpolar Solutes from Gas or Solvent to Another Solvent with a New View on Hydrophobic Behavior J. Phys. Chem. 1976, 80, 359-362
17. Lum, K.; Chandler, D.; Weeks, J. D. Hydrophobicity at small and large length scales J. Phys. Chem. B 1999, 103, 4570-4577
18. Silverstein, K. A. T.; Haymet, A. D. J.; Dill, K. A. Molecular model of hydrophobic solvation J. Chem. Phys. 1999, 111, 8000-8009
19. Silverstein, K. A. T.; Haymet, A. D. J.; Dill, K. A. The Strength of Hydrogen Bonds in Liquid Water and Around Nonpolar Solutes J. Am. Chem. Soc. 2000, 122, 8037-8041
20. Stillinger, F. H. Structure in Aqueous Solutions of Nonpolar Solutes from the Standpoint of Scaled-Particle Theory J. Solution Chem. 1973, 2, 141-158
21. Ball, P. Water as an active constituent in cell biology Chem. Rev. 2008, 108, 74-108
22. Galamba, N. Water's Structure around Hydrophobic Solutes and the Iceberg Model J. Phys. Chem. B 2013, 117, 2153-2159
23. Graziano, G. Comment on "Water's Structure around Hydrophobic Solutes and the Iceberg Model" J. Phys. Chem. B 2014, 10.1021/jp5008895
24. Chau, P. L.; Hardwick, A. J. A new order parameter for tetrahedral configurations Mol. Phys. 1998, 93, 511-518
25. Errington, J. R.; Debenedetti, P. G. Relationship between structural order and the anomalies of liquid water Nature 2001, 409, 318-321
26. Galamba, N. Water Tetrahedrons, Hydrogen-bond Dynamics and the Orientational Mobility of Water around Hydrophobic Solutes, submitted for publication, 2013.
27. Laage, D.; Stirnemann, G.; Hynes, J. T. Why Water Reorientation Slows without Iceberg Formation around Hydrophobic Solutes J. Phys. Chem. B 2009, 113, 2428-2435
28. Galamba, N. On the Effects of Temperature, Pressure and Dissolved Salts on the Hydrogen-bond Network of Water J. Phys. Chem. B 2013, 117, 589-601
29. Martiniano, H. F. M. C.; Galamba, N. Insights on Hydrogen-bond lifetimes in Liquid and Supercooled Water J. Phys. Chem. B 2013, 117, 16188-16195
30. Xu, H. F.; Berne, B. J. Hydrogen-bond kinetics in the solvation shell of a polypeptide J. Phys. Chem. B 2001, 105, 11929-11932
31. Matysiak, S.; Debenedetti, P. G.; Rossky, P. J. Dissecting the Energetics of Hydrophobic Hydration of Polypetides J. Phys. Chem. B 2011, 115, 14859-14865
32. Song, B.; Molinero, V. Thermodynamic and structural signatures of water-driven methane-methane attraction in coarse-grained mW water J. Chem. Phys. 2013, 139, 054511
33. Davis, J. G.; Gierszal, K. P.; Wang, P.; Ben-Amotz, D. Water structural transformation at molecular hydrophobic interfaces Nature 2012, 491, 582-585
34. Buchanan, P.; Aldiwan, N.; Soper, A. K.; Creek, J. L.; Koh, C. A. Decreased structure on dissolving methane in water Chem. Phys. Lett. 2005, 415, 89-93
35. Ben-Naim, A. Hydrophobic interaction and structural changes in the solvent Biopolymers 1975, 14, 1337-1355
36. Lee, B. Solvent reorganization contribution to the transfer thermodynamics of small nonpolar molecules Biophys. Chem. 1994, 51, 271
37. Yu, H.-A.; Karplus, M. A thermodynamic analysis of solvation J. Chem. Phys. 1988, 89, 2366-2379
38. Qian, H.; Hopfield, J. J. Entropy-enthalpy compensation: Perturbation and relaxation in thermodynamic systems J. Chem. Phys. 1996, 105, 9292-9298
39. Grunwald, E.; Steel, C. Solvent Reorganization and Thermodynamic Enthalpy-Entropy Compensation J. Am. Chem. Soc. 1995, 117, 5687-5692